Exploring the effect of acid modulators on MIL-101 (Cr) metal-organic framework catalysed olefin-aldehyde condensation; A sustainable approach for the selective synthesis of nopol

2021 ◽  
Author(s):  
Bhavana B Kulkarni ◽  
Kempanna S Kanakikodi ◽  
Dheer A Rambhia ◽  
Suresh Babu Kalidindi ◽  
Sanjeev P Maradur
Keyword(s):  
Metal Organic Framework ◽  
Selective Synthesis ◽  
Pine Tree ◽  
Metal Organic ◽  
Petroleum Reserves ◽  
Organic Framework

The development of efficient and sustainable strategies that evades the utilization of petroleum reserves is highly challenging yet inevitable today. In this regard, the conversion of pine tree-derived β-pinene to...

scholarly journals Site-Selective Synthesis of Janus-type Metal-Organic Framework Composites

2014 ◽  
Vol 53 (15) ◽  
pp. 4001-4005 ◽  
Author(s):  
Sudarat Yadnum ◽  
Jérome Roche ◽  
Eric Lebraud ◽  
Philippe Négrier ◽  
Patrick Garrigue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Selective Synthesis ◽  
Metal Organic ◽  
Site Selective ◽  
Organic Framework

scholarly journals Visible-Light-Mediated Photocatalytic Selective N-Methylation of Amines using CO2 under mild reaction condition via NH2-MIL-125 (Ti) MOF catalyst

2021 ◽  
Author(s):  
Jianguo liu ◽  
Xiuzhi Wei ◽  
Longlong Ma
Keyword(s):  
Visible Light ◽  
Metal Organic Framework ◽  
Synthesis Method ◽  
Selective Synthesis ◽  
Facile Synthesis ◽  
Reaction Conditions ◽  
Reaction Condition ◽  
Photocatalytic System ◽  
Metal Organic ◽  
Organic Framework

We herein describe a facile synthesis method of novel NH2-MIL-125 (Ti) metal organic framework as a photocatalyst, and the photochemical system was firstly developed for the direct N-methylation of amines under very mild reaction conditions of one bar CO2 and NaBH4. According to the optimization of reaction conditions, the selective synthesis of methylamines is achieved in good to excellent conversion and selectivity using visible light mediated photocatalytic system.

scholarly journals Innenrücktitelbild: Site-Selective Synthesis of Janus-type Metal-Organic Framework Composites (Angew. Chem. 15/2014)

2014 ◽  
Vol 126 (15) ◽  
pp. 4087-4087
Author(s):  
Sudarat Yadnum ◽  
Jérome Roche ◽  
Eric Lebraud ◽  
Philippe Négrier ◽  
Patrick Garrigue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Selective Synthesis ◽  
Metal Organic ◽  
Site Selective ◽  
Organic Framework

scholarly journals Site-Selective Synthesis of Janus-type Metal-Organic Framework Composites

2014 ◽  
Vol 126 (15) ◽  
pp. 4082-4086 ◽  
Author(s):  
Sudarat Yadnum ◽  
Jérome Roche ◽  
Eric Lebraud ◽  
Philippe Négrier ◽  
Patrick Garrigue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Selective Synthesis ◽  
Metal Organic ◽  
Site Selective ◽  
Organic Framework

scholarly journals Inside Back Cover: Site-Selective Synthesis of Janus-type Metal-Organic Framework Composites (Angew. Chem. Int. Ed. 15/2014)

2014 ◽  
Vol 53 (15) ◽  
pp. 4007-4007
Author(s):  
Sudarat Yadnum ◽  
Jérome Roche ◽  
Eric Lebraud ◽  
Philippe Négrier ◽  
Patrick Garrigue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Selective Synthesis ◽  
Back Cover ◽  
Metal Organic ◽  
Site Selective ◽  
Organic Framework

Multifunctional metal–organic framework heterostructures for enhanced cancer therapy

2021 ◽  
Author(s):  
Jintong Liu ◽  
Jing Huang ◽  
Lei Zhang ◽  
Jianping Lei
Keyword(s):  
Cancer Therapy ◽  
General Principle ◽  
Biomedical Applications ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Functional Modulation ◽  
Organic Framework

We review the general principle of the design and functional modulation of nanoscaled MOF heterostructures, and biomedical applications in enhanced therapy.

Magnetic Ordering via Itinerant Ferromagnetism in a Metal-Organic Framework

2020 ◽  
Author(s):  
Jesse Park ◽  
Brianna Collins ◽  
Lucy Darago ◽  
Tomce Runcevski ◽  
Michael Aubrey ◽  
...  
Keyword(s):  
Charge Transport ◽  
Magnetic Order ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Magnetic Ordering ◽  
Double Exchange ◽  
Itinerant Ferromagnetism ◽  
Organic Solids ◽  
Metal Organic ◽  
Organic Framework

<b>Materials that combine magnetic order with other desirable physical attributes offer to revolutionize our energy landscape. Indeed, such materials could find transformative applications in spintronics, quantum sensing, low-density magnets, and gas separations. As a result, efforts to design multifunctional magnetic materials have recently moved beyond traditional solid-state materials to metal–organic solids. Among these, metal–organic frameworks in particular bear structures that offer intrinsic porosity, vast chemical and structural programmability, and tunability of electronic properties. Nevertheless, magnetic order within metal–organic frameworks has generally been limited to low temperatures, owing largely to challenges in creating strong magnetic exchange in extended metal–organic solids. Here, we employ the phenomenon of itinerant ferromagnetism to realize magnetic ordering at <i>T</i><sub>C</sub> = 225 K in a mixed-valence chromium(II/III) triazolate compound, representing the highest ferromagnetic ordering temperature yet observed in a metal–organic framework. The itinerant ferromagnetism is shown to proceed via a double-exchange mechanism, the first such observation in any metal–organic material. Critically, this mechanism results in variable-temperature conductivity with barrierless charge transport below <i>T</i><sub>C</sub> and a large negative magnetoresistance of 23% at 5 K. These observations suggest applications for double-exchange-based coordination solids in the emergent fields of magnetoelectrics and spintronics. Taken together, the insights gleaned from these results are expected to provide a blueprint for the design and synthesis of porous materials with synergistic high-temperature magnetic and charge transport properties. </b>

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

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