scholarly journals Site-Selective Synthesis of Janus-type Metal-Organic Framework Composites

2014 ◽  
Vol 53 (15) ◽  
pp. 4001-4005 ◽  
Author(s):  
Sudarat Yadnum ◽  
Jérome Roche ◽  
Eric Lebraud ◽  
Philippe Négrier ◽  
Patrick Garrigue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Selective Synthesis ◽  
Metal Organic ◽  
Site Selective ◽  
Organic Framework

scholarly journals Innenrücktitelbild: Site-Selective Synthesis of Janus-type Metal-Organic Framework Composites (Angew. Chem. 15/2014)

2014 ◽  
Vol 126 (15) ◽  
pp. 4087-4087
Author(s):  
Sudarat Yadnum ◽  
Jérome Roche ◽  
Eric Lebraud ◽  
Philippe Négrier ◽  
Patrick Garrigue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Selective Synthesis ◽  
Metal Organic ◽  
Site Selective ◽  
Organic Framework

scholarly journals Site-Selective Synthesis of Janus-type Metal-Organic Framework Composites

2014 ◽  
Vol 126 (15) ◽  
pp. 4082-4086 ◽  
Author(s):  
Sudarat Yadnum ◽  
Jérome Roche ◽  
Eric Lebraud ◽  
Philippe Négrier ◽  
Patrick Garrigue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Selective Synthesis ◽  
Metal Organic ◽  
Site Selective ◽  
Organic Framework

scholarly journals Inside Back Cover: Site-Selective Synthesis of Janus-type Metal-Organic Framework Composites (Angew. Chem. Int. Ed. 15/2014)

2014 ◽  
Vol 53 (15) ◽  
pp. 4007-4007
Author(s):  
Sudarat Yadnum ◽  
Jérome Roche ◽  
Eric Lebraud ◽  
Philippe Négrier ◽  
Patrick Garrigue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Selective Synthesis ◽  
Back Cover ◽  
Metal Organic ◽  
Site Selective ◽  
Organic Framework

scholarly journals Ternary MOF-on-MOF heterostructures with controllable architectural and compositional complexity via multiple selective assembly

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Chao Liu ◽  
Qiang Sun ◽  
Lina Lin ◽  
Jing Wang ◽  
Chaoqi Zhang ◽  
...  
Keyword(s):  
Rational Design ◽  
Materials Science ◽  
Metal Organic Framework ◽  
Building Blocks ◽  
Selective Assembly ◽  
Assembly Strategy ◽  
Metal Organic ◽  
Site Selective ◽  
Organic Framework ◽  
The Way

Abstract Assembly of different metal-organic framework (MOF) building blocks into hybrid MOF-on-MOF heterostructures is promising in chemistry and materials science, however the development of ternary MOF-on-MOF heterostructures with controllable architectural and compositional complexity is challenging. Here we report the synthesis of three types of ternary MOF-on-MOF heterostructures via a multiple selective assembly strategy. This strategy relies on the choice of one host MOF with more than one facet that can arrange the growth of a guest MOF, where the arrangement is site-selective without homogenous growth of guest MOF or homogenous coating of guest on host MOF. The growth of guest MOF on a selected site of host MOF in each step provides the opportunity to further vary the combinations of arrangements in multiple steps, leading to ternary MOF-on-MOF heterostructures with tunable complexity. The developed strategy paves the way towards the rational design of intricate and unprecedented MOF-based superstructures for various applications.

Site-selective cyclometalation of a metal–organic framework

2013 ◽  
Vol 4 (2) ◽  
pp. 601-605 ◽  
Author(s):  
Phuong V. Dau ◽  
Min Kim ◽  
Seth M. Cohen
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic ◽  
Site Selective ◽  
Organic Framework

Motorized Janus metal organic framework crystals

2014 ◽  
Vol 50 (96) ◽  
pp. 15175-15178 ◽  
Author(s):  
Tristan T. Y. Tan ◽  
Jerald T. M. Cham ◽  
Michael R. Reithofer ◽  
T. S. Andy Hor ◽  
Jia Min Chin
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic ◽  
Site Selective ◽  
Organic Framework

A Janus MOF crystal showing site-selective bubble ejection from the ZIF-67 covered surface.

scholarly journals Visible-Light-Mediated Photocatalytic Selective N-Methylation of Amines using CO2 under mild reaction condition via NH2-MIL-125 (Ti) MOF catalyst

2021 ◽  
Author(s):  
Jianguo liu ◽  
Xiuzhi Wei ◽  
Longlong Ma
Keyword(s):  
Visible Light ◽  
Metal Organic Framework ◽  
Synthesis Method ◽  
Selective Synthesis ◽  
Facile Synthesis ◽  
Reaction Conditions ◽  
Reaction Condition ◽  
Photocatalytic System ◽  
Metal Organic ◽  
Organic Framework

We herein describe a facile synthesis method of novel NH2-MIL-125 (Ti) metal organic framework as a photocatalyst, and the photochemical system was firstly developed for the direct N-methylation of amines under very mild reaction conditions of one bar CO2 and NaBH4. According to the optimization of reaction conditions, the selective synthesis of methylamines is achieved in good to excellent conversion and selectivity using visible light mediated photocatalytic system.

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