Novel zwitterionic Polymer Binder with Enhanced Ionic Conductivity for Water-processable LiFePO4 Cathodes

2021 ◽  
Author(s):  
Shu Huang ◽  
Xiaoting Huang ◽  
Xiaokai Li ◽  
Youyuan Huang ◽  
Xueqin He ◽  
...  

Current olivine structure LiFePO4 possesses poor conductivity, which makes it unsuitable for unparalleled battery applications. This issue can be solved by improved design concepts of binder systems. Herein, an original...

Author(s):  
A. J. Scalzo ◽  
G. S. Howard ◽  
P. C. Holden

The field test of the current production W501D combustion turbine shows the engine to be an outstanding success. The engine meets power and exceeds efficiency expectations. Metal temperatures are at or below expected levels throughout the engine. In particular the test data demonstrates low temperatures provided by improved design concepts for the combustion chamber and first stage turbine vane, which are critical components because of their severe environment. Other design improvements for performance and reliability were also verified during the test.


Author(s):  
Rajan Babu V. ◽  
V. Balasubramaniyan ◽  
Raghupathy Sundararajan ◽  
P. Puthiyavinayagam ◽  
Chellapandi Perumal

Prototype Fast Breeder Reactor (PFBR), a 500 MWe, (U-Pu)O2 fuelled, sodium cooled, pool type fast reactor, is in advanced stage of construction at Kalpakkam, India. Based on the experience gained during the design, manufacture and erection of various reactor components of PFBR, it is planned to construct Sodium cooled Fast Reactors (SFR) by adopting twin unit (2×500 MWe reactors) concept. The future Fast Breeder Reactor (FBR) – 1 & 2 have three main heat transport circuits, namely primary sodium, secondary sodium and steam-water systems. All the reactor internals including core and primary heat transport circuit systems are contained in a single vessel called main vessel and it is closed with top shield. Reactor assembly forms the heart of the Nuclear Steam Supply System. A detailed and exhaustive design / optimisation exercise was initiated towards improving the economic competitiveness and enhancing the safety of future FBRs. It is observed that the overall dimensions of the reactor assembly contribute immensely to the capital cost. In this context, detailed studies were carried out towards optimizing the overall dimensions of the reactor assembly. Further, the reactor assembly design in particular has been engineered to favour manufacture of integrated assembly and erection of the same, as a single unit, in reactor vault to reduce construction time. Various activities undertaken towards technology development of critical components have enhanced the confidence level in the improved design concepts and reducing time for manufacture and erection. In addition to the reactor assembly, specific improvements have been made in decay heat removal systems and sodium purification system. The layout incorporates a twin unit concept in which the ex-vessel fuel handling system and fuel storage building are shared. This paper discusses the basis for undertaking the review exercise and experience gained during construction of PFBR and highlights the design studies and technology development carried out for future SFR.


2015 ◽  
Vol 137 (8) ◽  
Author(s):  
Bradley Camburn ◽  
Brock Dunlap ◽  
Tanmay Gurjar ◽  
Christopher Hamon ◽  
Matthew Green ◽  
...  

Scientific evaluation of prototyping practices is an emerging field in design research. Prototyping is critical to the success of product development efforts, and yet its implementation in practice is often guided by ad hoc experience. To address this need, we seek to advance the study and development of prototyping principles, techniques, and tools. A method to repeatedly enhance the outcome of prototyping efforts is reported in this paper. The research methodology to develop this method is as follows: (1) systematically identify practices that improve prototyping; (2) synthesize these practices to form a guiding method for designers; and (3) validate that the proposed method encourages best practices and improves performance. Prototyping practices are represented as six key heuristics to guide a designer in planning: how many iterations to pursue, how many unique design concepts to explore in parallel, as well as the use of scaled prototypes, isolated subsystem prototypes, relaxed requirements, and virtual prototypes. The method is correlated, through experimental investigation, with increased application of these best practices and improved design performance outcomes. These observations hold across various design problems studied. This method is novel in providing a systematic approach to prototyping.


1989 ◽  
Vol 44 (9) ◽  
pp. 1047-1049 ◽  
Author(s):  
Heinz Dieter Lutz ◽  
Arno Pfitzner

In the system LiI — ZnI2, the hitherto unknown peritectically melting Li2ZnI4 has been established. It crystallizes in the olivine structure (a = 1480.3(9), b = 856.0(2), and c = 701.2(1) pm) and exhibits high ionic conductivity. Thermoanalytical and Raman spectroscopic data are included.


2018 ◽  
Vol 78 (4) ◽  
pp. 968-981 ◽  
Author(s):  
Md Khalekuzzaman ◽  
Mehedi Hasan ◽  
Rezaul Haque ◽  
Muhammed Alamgir

Abstract Hydrodynamic performance of a biological reactor is an important design concern since it directly affects the treatment efficiency. In this research, a hybrid anaerobic baffled reactor (HABR) was proposed with improved design concepts and principles. The HABR consisted of a front sedimentation chamber, four regular baffled chambers followed by two floated filter media chambers. The effects of operating variables 5–20 hr hydraulic retention time (HRT) and 10–40 °C of influent temperature, as well as their interactive effects, on the hydrodynamic behaviour were investigated by residence time distributions study and response surface methodology. The study suggests that the hydrodynamic performance is greatly influenced by the number of chambers in the reactor rather than HRT and influent temperature. The influence of HRT and feed temperature were mainly observed on the front chambers (1–4) rather than rear chambers (5–7). The optimum reactor performance – low dead space (<10%), excellent hydraulic efficiency (>0.75), and intermediate mixing pattern (Peclet number > 10) – were achieved using the proposed HABR with more than five chambers.


Author(s):  
W.K. Lo ◽  
J.C.H. Spence

An improved design for a combination Scanning Tunnelling Microscope/TEM specimen holder is presented. It is based on earlier versions which have been used to test the usefulness of such a device. As with the earlier versions, this holder is meant to replace the standard double-tilt specimen holder of an unmodified Philips 400T TEM. It allows the sample to be imaged simultaneously by both the STM and the TEM when the TEM is operated in the reflection mode (see figure 1).The resolution of a STM is determined by its tip radii as well as its stability. This places strict limitations on the mechanical stability of the tip with respect to the sample. In this STM the piezoelectric tube scanner is rigidly mounted inside the endcap of the STM holder. The tip coarse approach to the sample (z-direction) is provided by an Inchworm which is located outside the TEM vacuum.


Author(s):  
Arthur V. Jones

With the introduction of field-emission sources and “immersion-type” objective lenses, the resolution obtainable with modern scanning electron microscopes is approaching that obtainable in STEM and TEM-but only with specific types of specimens. Bulk specimens still suffer from the restrictions imposed by internal scattering and the need to be conducting. Advances in coating techniques have largely overcome these problems but for a sizeable body of specimens, the restrictions imposed by coating are unacceptable.For such specimens, low voltage operation, with its low beam penetration and freedom from charging artifacts, is the method of choice.Unfortunately the technical dificulties in producing an electron beam sufficiently small and of sufficient intensity are considerably greater at low beam energies — so much so that a radical reevaluation of convential design concepts is needed.The probe diameter is usually given by


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