Highly Efficient Bifunctional Electrocatalyst (ORR/OER) Derived from GO Functionalized with Carbonyl, Hydroxyl and Epoxy Groups for Rechargeable Zinc-Air Batteries

2021 ◽  
Author(s):  
Lei Gu ◽  
Xuan-Long Sun ◽  
Jiao Zhao ◽  
Bing-Quan Gong ◽  
Zheng-Lv Bao ◽  
...  

Electrocatalysts play an important role in fuel cells, metal-air battery and water-splitting devices. The development of low cost, high activity and high performance bifunctional electrocatalysts for ORR and OER is...

Nanoscale ◽  
2020 ◽  
Vol 12 (45) ◽  
pp. 23125-23133
Author(s):  
Yifan Tian ◽  
Xinying Xue ◽  
Yu Gu ◽  
Zhaoxi Yang ◽  
Guo Hong ◽  
...  

Electrochemically splitting water into hydrogen and oxygen plays a significant role in the commercialization of hydrogen energy as well as fuel cells, but it remains a challenge to design and fabricate low-cost and high-efficiency electrocatalysts.


Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 458
Author(s):  
Tse-Wei Chen ◽  
Ganesan Anushya ◽  
Shen-Ming Chen ◽  
Palraj Kalimuthu ◽  
Vinitha Mariyappan ◽  
...  

Metal-air batteries and fuel cells are considered the most promising highly efficient energy storage systems because they possess long life cycles, high carbon monoxide (CO) tolerance, and low fuel crossover ability. The use of energy storage technology in the transport segment holds great promise for producing green and clean energy with lesser greenhouse gas (GHG) emissions. In recent years, nanoscale based electrocatalysts have shown remarkable electrocatalytic performance towards the construction of sustainable energy-related devices/applications, including fuel cells, metal-air battery and water-splitting processes. This review summarises the recent advancement in the development of nanoscale-based electrocatalysts and their energy-related electrocatalytic applications. Further, we focus on different synthetic approaches employed to fabricate the nanomaterial catalysts and also their size, shape and morphological related electrocatalytic performances. Following this, we discuss the catalytic reaction mechanism of the electrochemical energy generation process, which provides close insight to develop a more efficient catalyst. Moreover, we outline the future perspectives and challenges pertaining to the development of highly efficient nanoscale-based electrocatalysts for green energy storage technology.


Nanoscale ◽  
2019 ◽  
Vol 11 (48) ◽  
pp. 23318-23329 ◽  
Author(s):  
Lina Jia ◽  
Chen Li ◽  
Yaru Zhao ◽  
Bitao Liu ◽  
Shixiu Cao ◽  
...  

Non-precious metal-based electrocatalysts with high activity and stability for efficient hydrogen evolution reactions are of critical importance for low-cost and large-scale water splitting.


2020 ◽  
Vol 4 (2) ◽  
pp. 582-588 ◽  
Author(s):  
Yu-Yang Sun ◽  
Mei-Yan Jiang ◽  
Lian-Kui Wu ◽  
Guang-Ya Hou ◽  
Yi-Ping Tang ◽  
...  

Developing a bifunctional electrocatalyst with a facile method, low cost, excellent performance and good stability for overall water splitting is essential for the wide application of hydrogen production.


Hydrogen ◽  
2020 ◽  
Vol 2 (1) ◽  
pp. 1-17
Author(s):  
William J. F. Gannon ◽  
Charles W. Dunnill

Low-cost, high-performance coatings for hydrogen production via electrolytic water-splitting are of great importance for de-carbonising energy. In this study the Raney2.0 coating was analysed using various electrochemical techniques to assess its absolute performance, and it was confirmed to have an extremely low overpotential for hydrogen evolution of just 28 mV at 10 mA/cm2. It was also confirmed to be an acceptable catalyst for oxygen evolution, making it the highest performing simple bifunctional electrocatalyst known. The coating exhibits an extremely high capacitance of up to 1.7 F/cm2, as well as being able to store 0.61 J/cm2 in the form of temporary hydride deposits. A new technique is presented that performs a best-fit of a transient simulation of an equivalent circuit containing a constant phase element to cyclic voltammetry measurements. From this the roughness factor of the coating was calculated to be approximately 40,000, which is the highest figure ever reported for this type of material. The coating is therefore an extremely useful improved bifunctional coating for the continued roll-out of alkaline electrolysis for large-scale renewable energy capture via hydrogen production.


RSC Advances ◽  
2016 ◽  
Vol 6 (93) ◽  
pp. 90069-90075 ◽  
Author(s):  
Kai-Yuan Zhou ◽  
Guang-Yi Chen ◽  
Jia-Ang Liu ◽  
Zhi-Peng Zhang ◽  
Peng Sun ◽  
...  

Air-cathodes with properties of efficiency, durability and low cost are essential for high performance metal–air batteries and fuel cells for practical applications.


2016 ◽  
Vol 4 (20) ◽  
pp. 7762-7771 ◽  
Author(s):  
Xin Wang ◽  
Xiangye Liu ◽  
Chuan-Jia Tong ◽  
Xiaotao Yuan ◽  
Wujie Dong ◽  
...  

Efficient catalysts for oxygen evolution reactions (OERs) are a key renewable energy technology for fuel cells, metal–air batteries and water splitting, but few non-precious oxygen electrode catalysts with high activity have been discovered.


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