scholarly journals Sonochemical Preparation of Polymer-Metal Nanocomposites with Catalytic and Plasmonic Properties

2021 ◽  
Author(s):  
Jing Wan ◽  
Bo Fan ◽  
San Thang
Keyword(s):  
Reducing Agents ◽  
Wide Range ◽  
Polymer Metal ◽  
Metal Nanocomposites

Polymer-metal nanocomposites are of increasing interest for a wide range of applications; however, the preparation of these nanocomposites often requires the addition of external initiation and reducing agents for the...

Conducting Polymer - Metal Nanocomposites Synthesis and Their Sensory Applications

2013 ◽  
Vol 17 (20) ◽  
pp. 2256-2267 ◽  
Author(s):  
Zhen Liu ◽  
Lin Zhang ◽  
Selcuk Poyraz ◽  
Xinyu Zhang
Keyword(s):  
Conducting Polymer ◽  
Polymer Metal ◽  
Metal Nanocomposites

scholarly journals A Mixed Numerical-Experimental Method to Characterize Metal-Polymer Interfaces for Crash Applications

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 818
Author(s):  
Jonas Richter ◽  
Moritz Kuhtz ◽  
Andreas Hornig ◽  
Mohamed Harhash ◽  
Heinz Palkowski ◽  
...  
Keyword(s):  
Experimental Parameter ◽  
Dissimilar Materials ◽  
Calibration Method ◽  
Parameter Determination ◽  
Failure Behavior ◽  
Cohesive Elements ◽  
Interface Failure ◽  
Wide Range ◽  
Polymer Metal ◽  
Metal Polymer

Metallic (M) and polymer (P) materials as layered hybrid metal-polymer-metal (MPM) sandwiches offer a wide range of applications by combining the advantages of both material classes. The interfaces between the materials have a considerable impact on the resulting mechanical properties of the composite and its structural performance. Besides the fact that the experimental methods to determine the properties of the single constituents are well established, the characterization of interface failure behavior between dissimilar materials is very challenging. In this study, a mixed numerical–experimental approach for the determination of the mode I energy release rate is investigated. Using the example of an interface between a steel (St) and a thermoplastic polyolefin (PP/PE), the process of specimen development, experimental parameter determination, and numerical calibration is presented. A modified design of the Double Cantilever Beam (DCB) is utilized to characterize the interlaminar properties and a tailored experimental setup is presented. For this, an inverse calibration method is used by employing numerical studies using cohesive elements and the explicit solver of LS-DYNA based on the force-displacement and crack propagation results.

Fabrication of Ionic Polymer Metal Composite Actuator with Palladium Electrodes and Evaluation of its Bending Response

2009 ◽  
Vol 1190 ◽  
Author(s):  
Takuma Kobayashi ◽  
Takeshi Kuribayashi ◽  
Masaki Omiya
Keyword(s):  
Electric Field ◽  
Sample Length ◽  
Metal Composite ◽  
Ionic Polymer Metal Composite ◽  
Ionic Polymer ◽  
Palladium Electrode ◽  
Wide Range ◽  
Polymer Metal ◽  
Bending Response ◽  
Tip Displacement

AbstractWe built up the way of fabricating IPMC actuator with palladium electrodes and we found that it showed large bending response than Au-plated IPMC actuator. An ionic polymer-metal composite (IPMC) consisting of a thin perfuorinated ionomer membrane, electrodes plated on both faces, undergoes large bending motion when a small electric field is applied across its thickness in a hydrated state. The characteristics of IPMC are ease of miniaturization, low density, and mechanical flexibility. Therefore, it is considered to have a wide range of applications from MEMS sensor to artificial muscle. However, there are problems on IPMC. First, its mechanical and electric characteristics have not been clarified because of the complex mechanism of the deformation. Second, it is high-priced because most of IPMC actuators use gold or platinum as electrodes. In order for IPMC actuator to be widely put to practical use, we should solve these problems. Hence, this research focuses on fabrication of IPMC actuator with palladium electrode, which is cheaper than gold or platinum, and evaluation of its mechanical properties such as its tip displacement. We fabricated IPMC consisting of a thin Nafion® membrane, which is the film with fluorocarbon back-bones and mobile cations, sandwiched between two thin palladium plates. The surface resistivity was 2.88±0.18Ω/sq., so it could be said to be enough small. Then, we observed its cross section by using FE-SEM. As a result, palladium plates were evenly coated and its thickness was about 30μm. Also, we carried out an actuation test for two kinds of IPMCs: one was fabricated by using Nafion®117 (thickness 183μm), the other was by Nafion®115 (thickness 127μm). In this test, the relationship between voltage (0˜4V) across its thickness and tip displacement for the cantilevered strip of the IPMC was measured. Then we found that IPMCs showed large bending motion under a low electric field. When Nafion®117 sample was subjected to voltage of 1.5V, the ratio of the tip displacement to the sample length was 0.35, which was lager bending than Au-plated IPMC actuator, whose ratio of the tip displacement to the sample length was 0.12 [1]. When Nafion®115 sample was applied to 1.5V, the ratio of the tip displacement to the sample length was 0.22. Then, we found that Nafion®117 bended in a larger way than Nafion®115. Reference [1]Sia Nemat-Nesser and Yongxian Wu,”Comparative experimental study of ionic polymer-metal composites with different backbone ionomers and in various cation forms”, Journal of Applied Physics,93,5255 (2003)

4. Polymer–metal nanocomposites with antimicrobial activity

2019 ◽  
pp. 83-106
Author(s):  
Narendra Pal Singh Chauhan ◽  
Abolfazl Yazdanpanah ◽  
Masoud Mozafari
Keyword(s):  
Antimicrobial Activity ◽  
Polymer Metal ◽  
Metal Nanocomposites

Modified Nernst-Plank-Poisson Model for IPMC With Back-Relaxation Effects

2019 ◽  
Author(s):  
Aiman Al-Allaq ◽  
Nebojsa Jaksic ◽  
Bahaa Ansaf ◽  
Jude DePalma ◽  
Trung Duong
Keyword(s):  
Controller Design ◽  
Real Life ◽  
Poisson Model ◽  
Great Accuracy ◽  
Metal Composite ◽  
New Model ◽  
Relaxation Effects ◽  
Wide Range ◽  
Polymer Metal ◽  
Robotic Applications

Abstract The ionic polymer–metal composite (IPMC) is a new practical engineering material that, it has a wide range of capabilities in both dry and liquid environments. IPMC is a new candidate for diaphragms in micropump devices, micro and Nano robotic applications. IPMCs are regarded as a capable actuator for transportable applications, however, the unique combination of electrochemical and mechanical properties that they possess, such as back-relaxation, restraint their use in real-life applications. There have a lot of attempts to understand and model the IPMCs properties and build a whole prototype that can be used, with certainty, in different robotic, control, and medical applications, yet, till now, it seems that the dehydration and back-relaxation are still not modeled properly. The Nernst-Plank-Poisson was chosen to be the base model for the IPMC behavior, we were able to create a new model that truly represent the back-relaxation effects that occur in IPMCs, we’ve called the new model as modified NPP model. The modification used captured data from our experimental work Our modified analytical NPP (Nernst-Plank-Poisson) model was the verified using MATLAB & Simulink, which showed that the model, and the controller design for it was able to first compensate the loss of position of the IPMC due to back-relaxation, and then track the desired position input signals with great accuracy. The model and designed controller can be utilized in verity of robotic applications.

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