scholarly journals Optical Chemosensors for Gas Phase Detection of Aldehydes: Mechanism, Material Design and Application

2021 ◽  
Author(s):  
Chenglong Liao ◽  
Jiangfan Shi ◽  
Miao Zhang ◽  
Rana Dalapati ◽  
Qingyun Tian ◽  
...  
Keyword(s):  
Research And Development ◽  
Gas Phase ◽  
Chemical Sensors ◽  
Material Design ◽  
Phase Detection ◽  
Optical Chemosensors ◽  
High Hazard ◽  
Design And Application

Because of their high hazard and presence in various common scenarios (e.g., workplace, residence or bio-conversion systems), aldehydes have attracted enormous attention in research and development of chemical sensors and...

11H-Pyrido[2,1-b]quinazolin-11-one - A reversible Turn-on/off Fluorescent Probe for Solution and Gas-phase Detection of Acids or Basic Amines

2021 ◽  
pp. 109536
Author(s):  
João Victor L. Silva Néto ◽  
Rodolfo I. Teixeira ◽  
Ramon B. da Silva ◽  
Nanci C. de Lucas ◽  
Simon J. Garden
Keyword(s):  
Gas Phase ◽  
Fluorescent Probe ◽  
Phase Detection ◽  
Turn On

scholarly journals Perylene Imide-Based Optical Chemosensors for Vapor Detection

Chemosensors ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 1
Author(s):  
Miao Zhang ◽  
Jiangfan Shi ◽  
Chenglong Liao ◽  
Qingyun Tian ◽  
Chuanyi Wang ◽  
...  
Keyword(s):  
Molecular Design ◽  
Phase Detection ◽  
Time Reversibility ◽  
Strong Electron ◽  
Vapor Detection ◽  
Multiple Sensors ◽  
Optical Chemosensors ◽  
Potential Applications ◽  
High Fluorescence ◽  
Organic Amines

Perylene imide (PI) molecules and materials have been extensively studied for optical chemical sensors, particularly those based on fluorescence and colorimetric mode, taking advantage of the unique features of PIs such as structure tunability, good thermal, optical and chemical stability, strong electron affinity, strong visible light absorption and high fluorescence quantum yield. PI-based optical chemosensors have now found broad applications in gas phase detection of chemicals, including explosives, biomarkers of some food and diseases (such as organic amines (alkylamines and aromatic amines)), benzene homologs, organic peroxides, phenols and nitroaromatics, etc. In this review, the recent research on PI-based fluorometric and colorimetric sensors, as well as array technology incorporating multiple sensors, is reviewed along with the discussion of potential applications in environment, health and public safety areas. Specifically, we discuss the molecular design and aggregate architecture of PIs in correlation with the corresponding sensor performances (including sensitivity, selectivity, response time, recovery time, reversibility, etc.). We also provide a perspective summary highlighting the great potential for future development of PIs optical chemosensors, especially in the sensor array format that will largely enhance the detection specificity in complexed environments.

First gas-phase detection of dimethylgermylene and time-resolved study of some of its reactions

1996 ◽  
Vol 250 (1) ◽  
pp. 111-119 ◽  
Author(s):  
R. Becerra ◽  
S.E. Boganov ◽  
M.P. Egorov ◽  
V.Ya. Lee ◽  
O.M. Nefedov ◽  
...  
Keyword(s):  
Gas Phase ◽  
Phase Detection ◽  
Time Resolved

Gas Phase Detection of the NH–P Hydrogen Bond and Importance of Secondary Interactions

2015 ◽  
Vol 119 (44) ◽  
pp. 10988-10998 ◽  
Author(s):  
Kristian H. Møller ◽  
Anne S. Hansen ◽  
Henrik G. Kjaergaard
Keyword(s):  
Hydrogen Bond ◽  
Gas Phase ◽  
Phase Detection ◽  
Secondary Interactions

Development of a Latching Valve for Micro-Chem-Lab™

1999 ◽  
Author(s):  
C. Channy Wong ◽  
Douglas R. Adkins ◽  
Ronald P. Manginell ◽  
Gregory C. Frye-Mason ◽  
Peter J. Hesketh ◽  
...  
Keyword(s):  
Power Consumption ◽  
Gas Phase ◽  
Flow Rate ◽  
Integrated System ◽  
Dead Volume ◽  
Design Parameters ◽  
Working Fluid ◽  
Driving Voltage ◽  
Magnetic Actuation ◽  
Phase Detection

Abstract An integrated microsystem to detect traces of chemical agents (μChemLab™) is being developed at Sandia for counter-terrorism and nonproliferation applications. This microsystem has two modes of operation: liquid and gas phase detection. For the gas phase detection, we are integrating these critical components: a preconcentrator for sample collection, a gas chromatographic (GC) separator, a chemically selective flexural plate wave (FPW) array mass detector, and a latching valve onto a single chip. By fabricating these components onto a single integrated system (μChemLab™ on a chip), the advantages of reduced dead volume, lower power consumption, and smaller physical size can be realized. In this paper, the development of a latching valve will be presented. The key design parameters for this latching valve are: a volumetric flow rate of 1 mL/min, a maximum hold-off pressure of 40 kPa (6 psi), a relatively low power, and a fast response time. These requirements have led to the design of a magnetically actuated latching relay diaphragm valve. Magnetic actuation is chosen because it can achieve sufficient force to effectively seal against back pressure and its power consumption is relatively low. The actuation time is rapid, and valve can latch in either an open or closed state. A corrugated parylene membrane is used to separate the working fluid from internal components of the valve. Corrugations in the parylene ensure that the diaphragm presents minimum resistance to the actuator for a relativley large deflection. Two different designs and their performance of the magnetic actuation have been evaluated. The first uses a linear magnetic drive mechanism, and the second uses a relay mechanism. Preliminary results of the valve performance indicates that the required driving voltage is about 10 volts, the measured flow rate is about 50 mL/min, and it can hold off pressure of about 5 psi (34 kPa). Latest modifications of the design show excellent performance improvements.

Gas-phase detection of the FCO2 radical by millimeter wave and high resolution infrared spectroscopy assisted by ab initio calculations

2003 ◽  
Vol 118 (3) ◽  
pp. 1214-1220 ◽  
Author(s):  
Zdeněk Zelinger ◽  
Pascal Dréan ◽  
Adam Walters ◽  
Juan Ramon Avilès Moreno ◽  
Marcel Bogey ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
High Resolution ◽  
Ab Initio Calculations ◽  
Ab Initio ◽  
Gas Phase ◽  
Millimeter Wave ◽  
Phase Detection

scholarly journals The periodic table – an experimenter’s guide to transactinide chemistry

2019 ◽  
Vol 107 (9-11) ◽  
pp. 865-877 ◽  
Author(s):  
Robert Eichler
Keyword(s):  
Research And Development ◽  
Gas Phase ◽  
Periodic Table ◽  
Chemical Properties ◽  
Superheavy Elements ◽  
Experimental Results ◽  
Chemical Studies ◽  
Phase Chemical

Abstract The fundamental principles of the periodic table guide the research and development of the challenging experiments with transactinide elements. This guidance is elucidated together with experimental results from gas phase chemical studies of the transactinide elements with the atomic numbers 104–108 and 112–114. Some deduced chemical properties of these superheavy elements are presented here in conjunction with trends established by the periodic table. Finally, prospects are presented for further chemical investigations of transactinides based on trends in the periodic table.

scholarly journals Gas phase detection of tributyltin chloride arising from aqueous and solid matrices

2002 ◽  
Vol 17 (11) ◽  
pp. 1506-1510 ◽  
Author(s):  
Chrystelle Bancon-Montigny ◽  
Paulette Maxwell ◽  
Lu Yang ◽  
Zoltán Mester ◽  
Ralph E. Sturgeon ◽  
...  
Keyword(s):  
Gas Phase ◽  
Phase Detection ◽  
Tributyltin Chloride ◽  
Solid Matrices
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