Gas Phase Detection of the NH–P Hydrogen Bond and Importance of Secondary Interactions

2015 ◽  
Vol 119 (44) ◽  
pp. 10988-10998 ◽  
Author(s):  
Kristian H. Møller ◽  
Anne S. Hansen ◽  
Henrik G. Kjaergaard
Keyword(s):  
Hydrogen Bond ◽  
Gas Phase ◽  
Phase Detection ◽  
Secondary Interactions

11H-Pyrido[2,1-b]quinazolin-11-one - A reversible Turn-on/off Fluorescent Probe for Solution and Gas-phase Detection of Acids or Basic Amines

2021 ◽  
pp. 109536
Author(s):  
João Victor L. Silva Néto ◽  
Rodolfo I. Teixeira ◽  
Ramon B. da Silva ◽  
Nanci C. de Lucas ◽  
Simon J. Garden
Keyword(s):  
Gas Phase ◽  
Fluorescent Probe ◽  
Phase Detection ◽  
Turn On

First gas-phase detection of dimethylgermylene and time-resolved study of some of its reactions

1996 ◽  
Vol 250 (1) ◽  
pp. 111-119 ◽  
Author(s):  
R. Becerra ◽  
S.E. Boganov ◽  
M.P. Egorov ◽  
V.Ya. Lee ◽  
O.M. Nefedov ◽  
...  
Keyword(s):  
Gas Phase ◽  
Phase Detection ◽  
Time Resolved

Development of a Latching Valve for Micro-Chem-Lab™

1999 ◽  
Author(s):  
C. Channy Wong ◽  
Douglas R. Adkins ◽  
Ronald P. Manginell ◽  
Gregory C. Frye-Mason ◽  
Peter J. Hesketh ◽  
...  
Keyword(s):  
Power Consumption ◽  
Gas Phase ◽  
Flow Rate ◽  
Integrated System ◽  
Dead Volume ◽  
Design Parameters ◽  
Working Fluid ◽  
Driving Voltage ◽  
Magnetic Actuation ◽  
Phase Detection

Abstract An integrated microsystem to detect traces of chemical agents (μChemLab™) is being developed at Sandia for counter-terrorism and nonproliferation applications. This microsystem has two modes of operation: liquid and gas phase detection. For the gas phase detection, we are integrating these critical components: a preconcentrator for sample collection, a gas chromatographic (GC) separator, a chemically selective flexural plate wave (FPW) array mass detector, and a latching valve onto a single chip. By fabricating these components onto a single integrated system (μChemLab™ on a chip), the advantages of reduced dead volume, lower power consumption, and smaller physical size can be realized. In this paper, the development of a latching valve will be presented. The key design parameters for this latching valve are: a volumetric flow rate of 1 mL/min, a maximum hold-off pressure of 40 kPa (6 psi), a relatively low power, and a fast response time. These requirements have led to the design of a magnetically actuated latching relay diaphragm valve. Magnetic actuation is chosen because it can achieve sufficient force to effectively seal against back pressure and its power consumption is relatively low. The actuation time is rapid, and valve can latch in either an open or closed state. A corrugated parylene membrane is used to separate the working fluid from internal components of the valve. Corrugations in the parylene ensure that the diaphragm presents minimum resistance to the actuator for a relativley large deflection. Two different designs and their performance of the magnetic actuation have been evaluated. The first uses a linear magnetic drive mechanism, and the second uses a relay mechanism. Preliminary results of the valve performance indicates that the required driving voltage is about 10 volts, the measured flow rate is about 50 mL/min, and it can hold off pressure of about 5 psi (34 kPa). Latest modifications of the design show excellent performance improvements.

Gas-phase detection of the FCO2 radical by millimeter wave and high resolution infrared spectroscopy assisted by ab initio calculations

2003 ◽  
Vol 118 (3) ◽  
pp. 1214-1220 ◽  
Author(s):  
Zdeněk Zelinger ◽  
Pascal Dréan ◽  
Adam Walters ◽  
Juan Ramon Avilès Moreno ◽  
Marcel Bogey ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
High Resolution ◽  
Ab Initio Calculations ◽  
Ab Initio ◽  
Gas Phase ◽  
Millimeter Wave ◽  
Phase Detection

Enhancement of Thermodynamic Gas-Phase Acidity and Basicity of Water by Means of Secondary Interactions

ChemPhysChem ◽  
2018 ◽  
Vol 19 (19) ◽  
pp. 2486-2491 ◽  
Author(s):  
M. Merced Montero-Campillo ◽  
Ibon Alkorta ◽  
José Elguero
Keyword(s):  
Gas Phase ◽  
Gas Phase Acidity ◽  
Secondary Interactions ◽  
Acidity And Basicity
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