scholarly journals Simultaneous improvement of kinetics and thermodynamics based on SrF2 and SrF2@Gr additives on hydrogen sorption in MgH2

2021 ◽  
Author(s):  
Vivek Shukla ◽  
Ashish Bhatnagar ◽  
Satish K Verma ◽  
Anant Pandey ◽  
Alok Vishwakarma ◽  
...  

Herein we describe and discuss the effect of significant advantages of alkaline earth fluoride additive SrF2 on the improvement of kinetics, thermodynamics, and cyclability of the frontier hydrogen storage material...

2021 ◽  
Vol 765 ◽  
pp. 138277
Author(s):  
Pingping Liu ◽  
Yafei Zhang ◽  
Xiangjun Xu ◽  
Fangming Liu ◽  
Jibiao Li

2012 ◽  
Vol 512-515 ◽  
pp. 1438-1441 ◽  
Author(s):  
Hong Min Kan ◽  
Ning Zhang ◽  
Xiao Yang Wang ◽  
Hong Sun

An overview of recent advances in hydrogen storage is presented in this review. The main focus is on metal hydrides, liquid-phase hydrogen storage material, alkaline earth metal NC/polymer composites and lithium borohydride ammoniate. Boron-nitrogen-based liquid-phase hydrogen storage material is a liquid under ambient conditions, air- and moisture-stable, recyclable and releases H2controllably and cleanly. It is not a solid material. It is easy storage and transport. The development of a liquid-phase hydrogen storage material has the potential to take advantage of the existing liquid-based distribution infrastructure. An air-stable composite material that consists of metallic Mg nanocrystals (NCs) in a gas-barrier polymer matrix that enables both the storage of a high density of hydrogen and rapid kinetics (loading in <30 min at 200°C). Moreover, nanostructuring of Mg provides rapid storage kinetics without using expensive heavy-metal catalysts. The Co-catalyzed lithium borohydride ammoniate, Li(NH3)4/3BH4 releases 17.8 wt% of hydrogen in the temperature range of 135 to 250 °C in a closed vessel. This is the maximum amount of dehydrogenation in all reports. These will reduce economy cost of the global transition from fossil fuels to hydrogen energy.


ChemInform ◽  
2009 ◽  
Vol 40 (36) ◽  
Author(s):  
Thomas Huegle ◽  
Moritz F. Kuehnel ◽  
Dieter Lentz

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