Elucidating metal ions-regulated flavour formation mechanism in the aging process of Chinese distilled spirits (Baijiu) by electrochemistry, ICP-MS/OES, and UPLC-Q-Orbitrap-MS/MS

2021 ◽  
Author(s):  
Qing Zheng ◽  
Yaru Hu ◽  
Ayuan Xiong ◽  
Ying Su ◽  
Zihao Wang ◽  
...  

Elucidating the organometallic interactions in Baijiu will promote a deeper understanding of the flavour formation mechanism during Baijiu aging. However, the organometallic interactions during aging is difficult to explore because...

1998 ◽  
Vol 47 (4) ◽  
pp. 239-247 ◽  
Author(s):  
Naoko NONOSE ◽  
Akiharu HIOKI ◽  
Masayasu KURAHASHI ◽  
Masaaki KUBOTA

2019 ◽  
Vol 34 (3) ◽  
pp. 598-606 ◽  
Author(s):  
Peipei Zhou ◽  
Rongjie Zheng ◽  
Wei Zhang ◽  
Wei Liu ◽  
Yanyan Li ◽  
...  

A novel magnetic NiFe2O4-based effervescent tablet-assisted dispersive solid-phase microextraction (MNET-DSPM) was developed for extraction of metal ions prior to ICP-MS.


2013 ◽  
Vol 845 ◽  
pp. 462-466 ◽  
Author(s):  
H. Mas-Ayu ◽  
S. Izman ◽  
Mohammed Rafiq Abdul Kadir ◽  
Rosdi Daud ◽  
A. Shah ◽  
...  

The releases of harmful ions from cobalt based alloy to host tissues have raised significant health concerns. Carbon contents in this alloy may influence ions release but has yet investigated. It is hypothesized that carbon contents in this alloy will help the formation of oxide layer during thermal oxidation process and hence reducing the release of Co/Cr ions after implantation. In this study, Co-Cr-Mo alloy with carbon concentrations of 0.03% and 0.24% were oxidized at 1050°C for 3 hours under atmospheric condition. The oxidized substrates were characterized under FESEM and subjected to circulating immersion test in simulated body fluid (SBF) for 21 days. Metal ions release was measured using inductively coupled plasma-mass spectrometry (ICP-MS) at day 0, 7, 14 and 21. Oxidized high carbon samples show denser and a more uniform oxide layer than samples with low carbon contents. It is found that compact oxide structure promotes less metal ions release during immersion.


2021 ◽  
Author(s):  
Ao Su ◽  
et al.

Figure S1: Correlations of vein density vs. TOC, calcite, and dolomite contents of host shales; Figure S2: The box plots of calcite contents in shale samples with and without beef veins; Table S1: LA-MC-ICP-MS carbonate U-Pb dating data.


2022 ◽  
Author(s):  
Fakhri Arjmand ◽  
Zahra Mohamadnia

Recognition of metal ions using different methods such as HPLC, ICP-MS, ICP-AES, etc. has many limitations including expensiveness, time-consuming, and the need for advanced equipment. These limitations were extensively solved...


2018 ◽  
Vol 8 (11) ◽  
pp. 2050 ◽  
Author(s):  
Marek Kieliszek ◽  
Stanisław Błażejak

Selenium plays a key role in the proper metabolism of living organisms. The search for new selenium compounds opens up new possibilities for understanding selenometabolome in yeast cells. This study was aimed at the identification of compounds containing selenium in the feed yeasts Candida utilis ATCC 9950. Yeast biomass was kept in aqueous solutions enriched with inorganic selenium (20 mg·L−1) for 24 h. Speciation analysis of the element was performed using the HPLC-ICP-MS and UHPLC-ESI-Orbitrap MS techniques. The obtained selenium value in the yeast was 629 μg·g−1, while the selenomethionine value was 31.57 μg·g−1. The UHPLC-ESI-Orbitrap MS analysis conducted allowed for the identification of six selenium compounds: dehydro-selenomethionine-oxide, selenomethionine, selenomethionine-NH3, a Se-S conjugate of selenoglutathione-cysteine, methylthioselenoglutathione, and 2,3-DHP-selenocysteine-cysteine. In order to explain the structure of selenium compounds, the selected ions were subjected to fragmentation. The selenium compounds obtained with a low mass play a significant role in the metabolism of the compound. However, the bioavailability of such components and their properties have not been fully understood. The number of signals indicating the presence of selenium compounds obtained using the UHPLC-ESI-Orbitrap MS method was characterized by higher sensitivity than when using the HPLC-ICP-MS method. The obtained results will expand upon knowledge about the biotransformation of selenium in eukaryotic yeast cells. Future research should focus on understanding the entire selenium metabolism in cells and on the search for new transformation pathways for this element. This opens up new possibilities for obtaining functional food, rich in easily absorbable selenium sources, and constituting an alternative to dietary supplements based on this compound found primarily in inorganic form.


Sign in / Sign up

Export Citation Format

Share Document