Boosting photocatalytic degradation of ethyl acetate by Z­scheme Au-TiO2@NH2-UiO-66 heterojunction with ultrafine Au as electron mediator

2021 ◽  
Author(s):  
Hongli Liu ◽  
Xiaoyi Chang ◽  
Xiaoxun Liu ◽  
Guiying Li ◽  
Weiping Zhang ◽  
...  
Keyword(s):  
Visible Light ◽  
Ethyl Acetate ◽  
Charge Separation ◽  
Photocatalytic Oxidation ◽  
Separation Efficiency ◽  
Light Response ◽  
Electron Mediator ◽  
Visible Light Response ◽  
Charge Separation Efficiency ◽  
Photogenerated Charge Separation

TiO2 based photocatalytic oxidation has been regarded as a promising technology for VOCs removal, while it remains challenging by the limited visible light response and low photogenerated charge separation efficiency....

A g-C3N4/nanocarbon/ZnIn2S4nanocomposite: an artificial Z-scheme visible-light photocatalytic system using nanocarbon as the electron mediator

2015 ◽  
Vol 51 (96) ◽  
pp. 17144-17147 ◽  
Author(s):  
Fenfen Shi ◽  
Linlin Chen ◽  
Min Chen ◽  
Deli Jiang
Keyword(s):  
Visible Light ◽  
Charge Separation ◽  
Separation Efficiency ◽  
Electron Mediator ◽  
Photocatalytic System ◽  
Charge Separation Efficiency ◽  
Visible Light Photocatalytic

Nanocarbon could be used as an electron mediator to construct a Z-scheme photocatalytic system with enhanced charge separation efficiency.

An in situ ion exchange grown visible-light-driven Z-scheme AgVO3/AgI graphene microtube for enhanced photocatalytic performance

2020 ◽  
Vol 44 (4) ◽  
pp. 1579-1587
Author(s):  
Yong Liang ◽  
Yuexing Chen ◽  
Li Lin ◽  
Maojun Zhao ◽  
Li Zhang ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Visible Light ◽  
Charge Separation ◽  
Photocatalytic Oxidation ◽  
Photocatalytic Performance ◽  
Separation Efficiency ◽  
Visible Light Driven ◽  
Charge Separation Efficiency ◽  
Hydrothermal Methods

The visible-light-driven Z-scheme AgVO3/AgI graphene microtube is prepared by in situ ion exchange and hydrothermal methods for enhancing charge separation efficiency and photocatalytic oxidation ability.

scholarly journals Self-template synthesis of ATiO3 (A = Ba, Pb and Sr) perovskites for photocatalytic removal of NO

RSC Advances ◽  
2017 ◽  
Vol 7 (44) ◽  
pp. 27397-27404 ◽  
Author(s):  
Shiyi Cai ◽  
Shan Yu ◽  
Wenchao Wan ◽  
Wen Wen ◽  
Ying Zhou
Keyword(s):  
Template Synthesis ◽  
Charge Separation ◽  
Separation Efficiency ◽  
Light Response ◽  
Photocatalytic Removal ◽  
Charge Separation Efficiency

ATiO3 were synthesized from TiO2 nanosheets dominated with {001} facets, PbTiO3 possesses the highest activity as a result of larger light response and higher charge separation efficiency.

scholarly journals Au@CoS-BiVO4 {010} Constructed for Visible-Light-Assisted Peroxymonosulfate Activation

Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1414
Author(s):  
Yekun Ji ◽  
Ye Zhou ◽  
Jinnan Wang ◽  
Aimin Li ◽  
Weilin Bian ◽  
...  
Keyword(s):  
Visible Light ◽  
Charge Separation ◽  
Reaction System ◽  
Light Response ◽  
Pilot Scale ◽  
Sulfate Radical ◽  
Radical Trapping ◽  
Visible Light Response ◽  
Photogenerated Electrons ◽  
Scale Experiment

A visible-light-Fenton-like reaction system was constructed for the selective conversion of peroxymonosulfate to sulfate radical. Au@CoS, when doped on monoclinic BiVO4 {010} facets, promoted spatial charge separation due to the different energy band between the m-BiVO4 {010} and {110} facets. The visible-light response of m-BiVO4 was enhanced, which was attributed to the SPR effect of Au. And the photogenerated electrons were transferred from the m-BiVO4 {010} facet to Au via a Schottky junction. Owing to higher work function, CoS was able to capture these photoelectrons with acceleration of the Co(Ⅱ)/Co(Ⅲ) redox, enhancing peroxymonosulfate conversion to sulfate radical (Co2+ + HSO5−→ Co3+ + •SO4− + OH−). On the other hand, holes accumulated on m-BiVO4 {110} facets also contributed to organics oxidation. Thus, more than 95% of RhB was degraded within 40 min, and, even after five cycles, over 80% of RhB could be removed. The radical trapping experiments and EPR confirmed that both the sulfate radical and photogenerated hole were the main species for organics degradation. UV-vis DRS, photoluminescence (PL) and photoelectrochemical analyses also confirmed the enhancement of the visible-light response and charge separation. In a pilot scale experiment (PMS = 3 mM, initial TOC = 151 mg/L, reaction time = 4 h), CoS-Au-BiVO4 loaded on glass fiber showed a high mineralization rate (>60%) of practical wastewater.

Rational design of light induced self healed Fe based oxygen vacancy rich CeO2 (CeO2NS–FeOOH/Fe2O3) nanostructure materials for photocatalytic water oxidation and Cr(vi) reduction

2018 ◽  
Vol 6 (24) ◽  
pp. 11377-11389 ◽  
Author(s):  
S. Sultana ◽  
S. Mansingh ◽  
K. M. Parida
Keyword(s):  
Oxygen Vacancy ◽  
Visible Light ◽  
Water Oxidation ◽  
Charge Separation ◽  
Rational Design ◽  
Separation Efficiency ◽  
Nanostructure Materials ◽  
Charge Separation Efficiency ◽  
Uv Visible

Self regenerating oxygen vacancy rich CeO2NS–FeOOH/Fe2O3 hybrids are optimized and show superior charge separation efficiency both in visible and UV-visible light.

Spatially separated cocatalysts for efficient charge separation: a hollow Pt/CdS/N–ZnO/CoOx graphene microtubule with high stability for photocatalytic reactions and sustainable recycling

2019 ◽  
Vol 9 (24) ◽  
pp. 6899-6908 ◽  
Author(s):  
Yong Liang ◽  
Yuexing Chen ◽  
Maojun Zhao ◽  
Li Lin ◽  
Rongtao Duan ◽  
...  
Keyword(s):  
Hydrothermal Method ◽  
Charge Separation ◽  
High Stability ◽  
Photocatalytic Oxidation ◽  
Separation Efficiency ◽  
Capillary Action ◽  
Efficient Charge ◽  
Charge Separation Efficiency ◽  
Photocatalytic Reactions

The spatially separated Pt/CdS/N–ZnO/CoOx graphene microtubule (PCNZCo-GM) with double cocatalysts is prepared by a capillary action assisted hydrothermal method for enhancing charge separation efficiency and photocatalytic oxidation ability.

Efficient band structure tuning, charge separation, and visible-light response in ZrS2-based van der Waals heterostructures

2016 ◽  
Vol 9 (3) ◽  
pp. 841-849 ◽  
Author(s):  
Xirui Zhang ◽  
Zhaoshun Meng ◽  
Dewei Rao ◽  
Yunhui Wang ◽  
Qi Shi ◽  
...  
Keyword(s):  
Band Structure ◽  
Visible Light ◽  
Water Splitting ◽  
Charge Separation ◽  
Van Der Waals ◽  
Light Response ◽  
Van Der Waals Heterostructures ◽  
Visible Light Response

Bilayer ZrS2-based vdW heterostructures are proposed as efficient photocatalysts for water splitting under visible light.

Efficient charge separation and visible-light response of two-dimensional Janus group-III monochalcogenide multilayers

2021 ◽  
Author(s):  
Yujie Bai ◽  
Rongfeng Guan ◽  
Haiyang Zhang ◽  
Qinfang Zhang ◽  
Ning Xu
Keyword(s):  
Visible Light ◽  
Charge Separation ◽  
Light Response ◽  
Two Dimensional ◽  
Excellent Performance ◽  
Electron Hole ◽  
Group Iii ◽  
Efficient Separation ◽  
Visible Light Response ◽  
Efficient Charge

The Janus group-III monochalcogenide multilayers with enhanced built-in electric field exhibit excellent performance in harvesting sunlight and efficient separation of electron–hole pairs.

scholarly journals The Ternary Heterostructures of BiOBr/Ultrathin g-C3N4/Black Phosphorous Quantum Dot Composites for Photodegradation of Tetracycline

Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1118 ◽  
Author(s):  
Tianhao Jiang ◽  
Chaoqun Shang ◽  
Qingguo Meng ◽  
Mingliang Jin ◽  
Hua Liao ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Visible Light ◽  
Photocatalytic Degradation ◽  
Efficient Method ◽  
Charge Separation ◽  
Separation Efficiency ◽  
Photodegradation Efficiency ◽  
Charge Separation Efficiency ◽  
Black Phosphorous ◽  
Water Bath Heating

Herein, we synthesized BiOBr/ultrathin g-C3N4/ternary heterostructures modified with black phosphorous quantum dots using a simple water bath heating and sonication method. The ternary heterostructure was then used for the photocatalytic degradation of tetracycline in visible light, with an efficiency as high as 92% after 3 h of irradiation. Thus, the photodegradation efficiency is greatly improved compared to that of ultrathin g-C3N4, BiOBr, and black phosphorous quantum dots alone. The synthesized ternary heterostructure improves the charge separation efficiency, thus increasing the photodegradation efficiency. This work provides a new and efficient method for the degradation of antibiotics in the environment.

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