Development of encapsulation strategies towards the commercialization of perovskite solar cells

Author(s):  
Sai Ma ◽  
Gui-Zhou Yuan ◽  
Ying Zhang ◽  
Ning Yang ◽  
Yujing Li ◽  
...  

After a decade of research and development on the perovskite solar cells (PSCs), the achievements targeting the device stability have fallen far behind the progress made in the photoelectric conversion...

Nanomaterials ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 720 ◽  
Author(s):  
Hang Dong ◽  
Shangzheng Pang ◽  
Yi Zhang ◽  
Dazheng Chen ◽  
Weidong Zhu ◽  
...  

Due to the low temperature fabrication process and reduced hysteresis effect, inverted p-i-n structured perovskite solar cells (PSCs) with the PEDOT:PSS as the hole transporting layer and PCBM as the electron transporting layer have attracted considerable attention. However, the energy barrier at the interface between the PCBM layer and the metal electrode, which is due to an energy level mismatch, limits the electron extraction ability. In this work, an inorganic aluminum-doped zinc oxide (AZO) interlayer is inserted between the PCBM layer and the metal electrode so that electrons can be collected efficiently by the electrode. It is shown that with the help of the PCBM/AZO bilayer, the power conversion efficiency of PSCs is significantly improved, with negligible hysteresis and improved device stability. The UPS measurement shows that the AZO interlayer can effectively decrease the energy offset between PCBM and the metal electrode. The steady state photoluminescence, time-resolved photoluminescence, transient photocurrent, and transient photovoltage measurements show that the PSCs with the AZO interlayer have a longer radiative carrier recombination lifetime and more efficient charge extraction efficiency. Moreover, the introduction of the AZO interlayer could protect the underlying perovskite, and thus, greatly improve device stability.


Coatings ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 978
Author(s):  
Chaoqun Lu ◽  
Weijia Zhang ◽  
Zhaoyi Jiang ◽  
Yulong Zhang ◽  
Cong Ni

The hole transport layer (HTL) is one of the main factors affecting the efficiency and stability of perovskite solar cells (PSCs). However, obtaining HTLs with the desired properties through current preparation techniques remains a challenge. In the present study, we propose a new method which can be used to achieve a double-layer HTL, by inserting a CuI layer between the perovskite layer and Spiro-OMeTAD layer via a solution spin coating process. The CuI layer deposited on the surface of the perovskite film directly covers the rough perovskite surface, covering the surface defects of the perovskite, while a layer of CuI film avoids the defects caused by Spiro-OMetad pinholes. The double-layer HTLs improve roughness and reduce charge recombination of the Spiro-OMeTAD layer, thereby resulting in superior hole extraction capabilities and faster hole mobility. The CuI/Spiro-OMeTAD double-layer HTLs-based devices were prepared in N2 gloveboxes and obtained an optimized PCE (photoelectric conversion efficiency) of 17.44%. Furthermore, their stability was improved due to the barrier effect of the inorganic CuI layer on the entry of air and moisture into the perovskite layer. The results demonstrate that another deposited CuI film is a promising method for realizing high-performance and air-stable PSCs.


2019 ◽  
Vol 7 (27) ◽  
pp. 8344-8349 ◽  
Author(s):  
Xianglan Tang ◽  
Shuqin Xiao ◽  
Qingxia Fu ◽  
Yiwang Chen ◽  
Ting Hu

A PCBM:ITIC mixture interlayer was formed on perovskite to improve charge mobility and device stability.


RSC Advances ◽  
2020 ◽  
Vol 10 (25) ◽  
pp. 14679-14688
Author(s):  
Liping Peng ◽  
Wei Xie

Perovskite solar cells based on the lead free hybrid organic–inorganic CH3NH3SnI3 (MASnI3) and CH4N2SnI3 (FASnI3) perovskites were fabricated, and the photoelectric conversion efficiency (PCE) was assessed.


2017 ◽  
Vol 5 (23) ◽  
pp. 11462-11482 ◽  
Author(s):  
Shida Yang ◽  
Weifei Fu ◽  
Zhongqiang Zhang ◽  
Hongzheng Chen ◽  
Chang-Zhi Li

In this review, we first highlighted recent progress in high-performance perovskite solar cells (PVSCs) with a discussion of the fabrication methods and PVSCs-based tandem solar cells. Furthermore, the stability issue of PVSCs and strategies to improve material and device stability have been discussed, and finally, a summary of the recent progress in lead-free perovskites has been presented.


2019 ◽  
Vol 6 (1) ◽  
pp. 1970004
Author(s):  
Chuanjiang Qin ◽  
Toshinori Matsushima ◽  
Dino Klotz ◽  
Takashi Fujihara ◽  
Chihaya Adachi

Solar RRL ◽  
2017 ◽  
Vol 1 (9) ◽  
pp. 1700097 ◽  
Author(s):  
Yuanhang Cheng ◽  
Xiuwen Xu ◽  
Yuemin Xie ◽  
Ho-Wa Li ◽  
Jian Qing ◽  
...  

2017 ◽  
Vol 26 (1) ◽  
pp. 018401 ◽  
Author(s):  
Chao Xia ◽  
Wei-Dong Song ◽  
Chong-Zhen Zhang ◽  
Song-Yang Yuan ◽  
Wen-Xiao Hu ◽  
...  

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