Single crystal-to-single crystal transformation – from two distinct to three distinct spin crossover centers in 2D coordination polymer [Fe(bbtr)3](CF3SO3)2

2021 ◽  
Author(s):  
Robert Bronisz ◽  
Maria Książek ◽  
Joachim Kusz ◽  
Marek Damian Weselski
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Crystal Lattice ◽  
Spin Crossover ◽  
Triazole Ring ◽  
Two Dimensional ◽  
Crystal Transformation

1,4-di(1,2,3-triazol-1-yl)butane (bbtr) forms two-dimensional (2D) coordination polymer (1) in the reaction with iron(II) triflate. In the crystal lattice there are two crystallographically unique iron(II) ions surrounded octahedrally by 1,2,3-triazole ring...

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

A spin-crossover phenomenon in a 2D heterometallic coordination polymer with [Pd(SCN)4]2− building blocks

2021 ◽  
Vol 50 (12) ◽  
pp. 4152-4158
Author(s):  
Kai-Ping Xie ◽  
Si-Guo Wu ◽  
Long-Fei Wang ◽  
Guo-Zhang Huang ◽  
Zhao-Ping Ni ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Spin Crossover ◽  
Building Blocks ◽  
Two Dimensional ◽  
Heterometallic Coordination Polymer

The first spin-crossover example of a two-dimensional coordination polymer containing [Pd(SCN)4]2− building blocks was explored.

Water molecule induced reversible single-crystal-to-single-crystal transformation between two trinuclear Fe(ii) complexes with different spin crossover behaviour

2018 ◽  
Vol 47 (12) ◽  
pp. 4307-4314 ◽  
Author(s):  
Wen-Bin Chen ◽  
Yan-Cong Chen ◽  
Meng Yang ◽  
Ming-Liang Tong ◽  
Wen Dong
Keyword(s):  
Water Molecule ◽  
Single Crystal ◽  
Spin Crossover ◽  
Crystal Transformation

Water molecule induced reversible single-crystal-to-single-crystal transformation between two trinuclear Fe(ii) complexes with different spin crossover behaviour.

Two-Step Spin-Crossover with Three Inequivalent FeII Sites in a Two-Dimensional Hofmann-Type Coordination Polymer

2017 ◽  
Vol 23 (42) ◽  
pp. 10034-10037 ◽  
Author(s):  
Yan Meng ◽  
Qing-Qing Sheng ◽  
Md. Najbul Hoque ◽  
Yan-Cong Chen ◽  
Si-Guo Wu ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Spin Crossover ◽  
Two Dimensional

Synthesis, Structure and Properties of Two-Dimensional Coordination Polymer Based on 3,5-di(benzimidazol-1-yl)pyridine

2020 ◽  
Vol 42 (2) ◽  
pp. 249-249
Author(s):  
Guo Jun Wu Guo Jun Wu
Keyword(s):  
Infrared Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Photocatalytic Degradation ◽  
Elemental Analysis ◽  
Solvothermal Reaction ◽  
Two Dimensional ◽  
Structure And Properties ◽  
X Ray Diffraction ◽  
X Ray

[Cu(L)(AIP)·1.5H2O]n (1) [L= 3,5-di(benzimidazol-1-yl)pyridine, H2AIP= 5-aminoisophthalic acid] was prepared by the solvothermal reaction, which was characterized by single-crystal X–ray diffraction, infrared spectroscopy, and elemental analysis. 1 exhibits an infinite two dimensional [Cu(AIP)]n sheet parallel to (0 1 1) crystal plane. Furthermore, complex 1 displays good photocatalytic degradation of methyl blue (MB).

Single Crystal Growth of Two-Dimensional Cyano-Bridged Coordination Polymer of Co(H2O)2Ni(CN)4·4H2O Using Trisodium Citrate Dihydrate

2019 ◽  
Vol 92 (7) ◽  
pp. 1263-1267 ◽  
Author(s):  
Alowasheeir Azhar ◽  
Mohamed Barakat Zakaria ◽  
Jeonghun Kim ◽  
Jongbeom Na ◽  
Yusuf Valentino Kaneti ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Trisodium Citrate ◽  
Single Crystal Growth ◽  
Two Dimensional ◽  
Trisodium Citrate Dihydrate

Single-crystal to single-crystal transformation from a 1-D chain-like structure to a 2-D coordination polymer on heating

CrystEngComm ◽  
2013 ◽  
Vol 15 (28) ◽  
pp. 5606 ◽  
Author(s):  
Xu-Jia Hong ◽  
Ming-Fang Wang ◽  
Hong-Guang Jin ◽  
Qing-Guang Zhan ◽  
Yi-Ting Liu ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Crystal Transformation
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