Coordination–driven discrete metallo–supramolecular assembly for rapid and selective photochemical CO2 reduction in aqueous solution

2021 ◽  
Author(s):  
Yanan Wang ◽  
Longxin Chen ◽  
Ting Liu ◽  
Duobin Chao

A discrete metallo–supramolecular assembly composed of six iron(II) cations and twelve redox–active terpyridine fragments has been developed for highly efficient visible–light–driven reduction of CO2 to CO with a TON of...

2016 ◽  
Vol 18 (1) ◽  
pp. 139-143 ◽  
Author(s):  
Akinobu Nakada ◽  
Kazuhide Koike ◽  
Kazuhiko Maeda ◽  
Osamu Ishitani

Even in an aqueous solution, a Ru(ii)–Re(i) supramolecular photocatalyst worked well for CO2 reduction. A water-soluble reductant BI(CO2−)H should be useful for evaluation of the real abilities of various photocatalytic systems.


2020 ◽  
Vol 59 (23) ◽  
pp. 17464-17472
Author(s):  
Liyan Zhang ◽  
Shiwei Li ◽  
Huiping Liu ◽  
Yuan-Sheng Cheng ◽  
Xian-Wen Wei ◽  
...  

2021 ◽  
Vol 282 ◽  
pp. 119600
Author(s):  
Puttaswamy Madhusudan ◽  
Run Shi ◽  
Shengling Xiang ◽  
Mengtian Jin ◽  
Bananakere Nanjegowda Chandrashekar ◽  
...  

2016 ◽  
Vol 7 (11) ◽  
pp. 6728-6739 ◽  
Author(s):  
Jana Rohacova ◽  
Osamu Ishitani

Trinuclear Re(i)-rings were applied as redox photosensitizers in visible light-driven CO2 reduction in tandem with various catalysts, i.e., Re(i)-, Ru(ii)- and Mn(i)-diimine metal complex. The quantum yields for the Ru(ii) and Mn(i) catalysts were the among highest reported.


2016 ◽  
Vol 4 (7) ◽  
pp. 2657-2662 ◽  
Author(s):  
Dashu Chen ◽  
Hongzhu Xing ◽  
Chungang Wang ◽  
Zhongmin Su

A new anthracene-based Zr-MOF for highly efficient visible-light-driven CO2 reduction to produce formate via dual catalytic routes.


2016 ◽  
Vol 7 (7) ◽  
pp. 4364-4371 ◽  
Author(s):  
Akinobu Nakada ◽  
Takuya Nakashima ◽  
Keita Sekizawa ◽  
Kazuhiko Maeda ◽  
Osamu Ishitani

A hybrid photocatalytic system consisting of a Ru(ii) binuclear complex and Ag-loaded TaON can reduce CO2 to HCOOH by visible light irradiation even in aqueous solution (TONHCOOH = 750, ΦHCOOH = 0.48%).


2014 ◽  
Vol 13 (4) ◽  
pp. 691-702 ◽  
Author(s):  
Naoya Ikuta ◽  
Shin-ya Takizawa ◽  
Shigeru Murata

We report a novel system of visible-light-driven CO2 reduction to CO in an aqueous solution, in which DPPC vesicles dispersed in the solution act as a photocatalyst using ascorbate (HAsc−) as an electron source.


2018 ◽  
Vol 24 (17) ◽  
pp. 4273-4278 ◽  
Author(s):  
Zi-Cheng Fu ◽  
Rong-Chen Xu ◽  
Joshua T. Moore ◽  
Fei Liang ◽  
Xiao-Cun Nie ◽  
...  

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