Metal–ligand cooperation behaviour of Fe and Co complexes bearing a tetradentate phenanthroline-based PNNP ligand

2021 ◽  
Author(s):  
Yumiko Nakajima ◽  
Tomohiro Takeshita ◽  
Nai-Yuan Jheng
Keyword(s):  
Long Range ◽  
Cobalt Complexes ◽  
Metal Ligand

A metal–ligand cooperation (MLC) behavior was investigated using Iron and cobalt complexes bearing a phenanthroline-based meridional PNNP ligand, demonstrating a unique long-range MLC, where the phenanthroline backbone behaves as a H2 reservoir.

Exploring ligand non-innocence of coordinatively-versatile diamidodipyrrinato cobalt complexes

2019 ◽  
Vol 55 (12) ◽  
pp. 1825-1828 ◽  
Author(s):  
Simran S. Saund ◽  
Samantha L. Goldschmid ◽  
Karina Ng ◽  
Veronica Stewart ◽  
Maxime A. Siegler ◽  
...  
Keyword(s):  
Cobalt Complexes ◽  
Redox Activity ◽  
Coordination Modes ◽  
New Strategy ◽  
Metal Ligand

A new strategy is reported for modifying the redox activity of diamidodipyrrins through coordination modes in the same metal–ligand platform.

“Long-Range” Metal−Ligand Cooperation in H2Activation and Ammonia-Promoted Hydride Transfer with a Ruthenium−Acridine Pincer Complex

2010 ◽  
Vol 132 (42) ◽  
pp. 14763-14765 ◽  
Author(s):  
Chidambaram Gunanathan ◽  
Boopathy Gnanaprakasam ◽  
Mark A. Iron ◽  
Linda J. W. Shimon ◽  
David Milstein
Keyword(s):  
Long Range ◽  
Hydride Transfer ◽  
Pincer Complex ◽  
Metal Ligand

scholarly journals Cyaphide–alkynyl complexes: metal–ligand conjugation and the influence of remote substituents

2019 ◽  
Vol 48 (23) ◽  
pp. 8131-8143 ◽  
Author(s):  
Samantha K. Furfari ◽  
Matthew C. Leech ◽  
Nicola Trathen ◽  
Madeleine C. Levis ◽  
Ian R. Crossley
Keyword(s):  
Long Range ◽  
Long Range Communication ◽  
Metal Ligand

A series of cyaphide–alkynyl complexes exhibits significant cooperativity between the electron accepting “–CP” ligand and remote alkynyl substituents, indicative of long-range communication.

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