Exploring ligand non-innocence of coordinatively-versatile diamidodipyrrinato cobalt complexes

2019 ◽  
Vol 55 (12) ◽  
pp. 1825-1828 ◽  
Author(s):  
Simran S. Saund ◽  
Samantha L. Goldschmid ◽  
Karina Ng ◽  
Veronica Stewart ◽  
Maxime A. Siegler ◽  
...  
Keyword(s):  
Cobalt Complexes ◽  
Redox Activity ◽  
Coordination Modes ◽  
New Strategy ◽  
Metal Ligand

A new strategy is reported for modifying the redox activity of diamidodipyrrins through coordination modes in the same metal–ligand platform.

Influence of Multisite Metal–Ligand Cooperativity on the Redox Activity of Noninnocent N2S2 Ligands

2020 ◽  
Vol 59 (15) ◽  
pp. 10845-10853 ◽  
Author(s):  
Kyle D. Spielvogel ◽  
Javier A. Luna ◽  
Sydney M. Loria ◽  
Leah P. Weisburn ◽  
Nathan C. Stumme ◽  
...  
Keyword(s):  
Redox Activity ◽  
Metal Ligand

ESR STUDY OF COPPER(II) COMPLEXES OF α-AMINO ACIDS. COORDINATION MODES AND METAL-LIGAND BONDS IN FROZEN AQUEOUS SOLUTIONS

1988 ◽  
Vol 17 (1) ◽  
pp. 69-83 ◽  
Author(s):  
Terézia Szabó-Plánka ◽  
Antal Rockenbauer ◽  
Miklós Györ ◽  
Ferenc Gaizer
Keyword(s):  
Amino Acids ◽  
Aqueous Solutions ◽  
Coordination Modes ◽  
Metal Ligand

Redox Activity, Ligand Protonation, and Variable Coordination Modes of Diimino-Pyrrole Complexes of Palladium

2018 ◽  
Vol 57 (12) ◽  
pp. 7044-7050 ◽  
Author(s):  
Andrew J. McNeece ◽  
Mu-Chieh Chang ◽  
Alexander S. Filatov ◽  
John S. Anderson
Keyword(s):  
Redox Activity ◽  
Coordination Modes ◽  
Variable Coordination

Two 2D sliver complexes with a symmetric and noncentrosymmetric architecture controlled by the metal–ligand ratio

CrystEngComm ◽  
2014 ◽  
Vol 16 (25) ◽  
pp. 5627-5632 ◽  
Author(s):  
Lin-Fei Wu ◽  
Zhao-Xi Wang ◽  
Chao-Chao Xue ◽  
Hong-Ping Xiao ◽  
Ming-Xing Li
Keyword(s):  
Phosphorus Atom ◽  
Coordination Modes ◽  
Ligand Ratio ◽  
Metal Ligand

By controlling the metal–ligand ratio, we obtained two 2D sliver complexes from a symmetric to noncentrosymmetric architecture based on 2,2′-phosphinico-dibenzoic acid (H3L). The four groups around the phosphorus atom of the L3− ligand connect the Ag(i) ions through different coordination modes to form a noncentrosymmetric complex 2.

Metal–ligand cooperation behaviour of Fe and Co complexes bearing a tetradentate phenanthroline-based PNNP ligand

2021 ◽  
Author(s):  
Yumiko Nakajima ◽  
Tomohiro Takeshita ◽  
Nai-Yuan Jheng
Keyword(s):  
Long Range ◽  
Cobalt Complexes ◽  
Metal Ligand

A metal–ligand cooperation (MLC) behavior was investigated using Iron and cobalt complexes bearing a phenanthroline-based meridional PNNP ligand, demonstrating a unique long-range MLC, where the phenanthroline backbone behaves as a H2 reservoir.

Redox Activity and Two-Step Valence Tautomerism in a Family of Dinuclear Cobalt Complexes with a Spiroconjugated Bis(dioxolene) Ligand

2013 ◽  
Vol 135 (22) ◽  
pp. 8304-8323 ◽  
Author(s):  
Kerwyn G. Alley ◽  
Giordano Poneti ◽  
Peter S. D. Robinson ◽  
Ayman Nafady ◽  
Boujemaa Moubaraki ◽  
...  
Keyword(s):  
Cobalt Complexes ◽  
Redox Activity ◽  
Valence Tautomerism

A New Strategy for Neurochemical Photodelivery:  Metal−Ligand Heterolytic Cleavage

2003 ◽  
Vol 125 (4) ◽  
pp. 882-883 ◽  
Author(s):  
Leonardo Zayat ◽  
Cecilia Calero ◽  
Pablo Alborés ◽  
Luis Baraldo ◽  
Roberto Etchenique
Keyword(s):  
Heterolytic Cleavage ◽  
New Strategy ◽  
Metal Ligand

scholarly journals Rich Redox-Activity and Solvatochromism in a Family of Heteroleptic Cobalt Complexes

2021 ◽  
Author(s):  
Vincent L. Nadurata ◽  
Moya Hay ◽  
Jett Tao Janetzki ◽  
Gemma Kate Gransbury ◽  
Colette Boskovic
Keyword(s):  
Charge Transfer ◽  
Cobalt Complexes ◽  
Redox Activity ◽  
Redox Active Ligands ◽  
Valence Tautomerism ◽  
Redox Active ◽  
Active Metal ◽  
Metal Redox ◽  
Redox Active Metal

The combination of redox-active metals with redox-active ligands can lead to interesting charge transfer behaviours, including valence tautomerism and solvatochromism. With the aim of investigating a relatively underexplored redox-active metal/redox-active...

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