scholarly journals Quasilinear 3d-metal(i) complexes [KM(N(Dipp)SiR3)2] (M = Cr–Co) – structural diversity, solution state behaviour and reactivity

2021 ◽  
Vol 50 (14) ◽  
pp. 4890-4903
Author(s):  
Ruth Weller ◽  
Igor Müller ◽  
Carine Duhayon ◽  
Sylviane Sabo-Etienne ◽  
Sébastien Bontemps ◽  
...  
Keyword(s):  
Solid State ◽  
Structural Diversity ◽  
Solution State ◽  
State Behaviour

The synthesis of quasilinear metal(i) silylamides [KM(N(Dipp)SiR3)2] of chromium to cobalt, their diverse speciation in solid state and solution as well as their reactivity towards alkynes are reported.

scholarly journals Solid-state structure, solution-state behaviour and catalytic activity of electronically divergent C,N-chelating palladium–N-heterocyclic carbene complexes

2015 ◽  
Vol 44 (36) ◽  
pp. 15938-15948 ◽  
Author(s):  
Michael R. Chapman ◽  
Benjamin R. M. Lake ◽  
Christopher M. Pask ◽  
Bao N. Nguyen ◽  
Charlotte E. Willans
Keyword(s):  
Catalytic Activity ◽  
Solid State ◽  
Cross Coupling ◽  
State Structure ◽  
Carbene Complexes ◽  
Solid State Structure ◽  
Solution State ◽  
Structure Solution ◽  
State Behaviour

Electronically diverse pyridyl-substituted Pd(ii)-NHC complexes have been employed in Suzuki–Miyaura cross-coupling to yield a sterically congested tetra-ortho-substituted biaryl product.

Structural diversity of new solid-state luminophores based on quinoxaline-β-ketoiminate boron difluoride complexes with remarkable fluorescence switching properties

2015 ◽  
Vol 51 (13) ◽  
pp. 2656-2659 ◽  
Author(s):  
Chia-Wei Liao ◽  
Rajeswara Rao M. ◽  
Shih-Sheng Sun
Keyword(s):  
Solid State ◽  
Structural Diversity ◽  
Acid Base ◽  
Fluorescence Switching ◽  
Solid State Fluorescence ◽  
Boron Difluoride

Highly tunable organoboron luminophores with intense solid-state fluorescence showed outstanding photoswitching properties modulated by acid/base vapors.

Proton-Detected NMR Spectroscopy of Nanodisc-Embedded Membrane Proteins: MAS Solid-State vs Solution-State Methods

2017 ◽  
Vol 121 (32) ◽  
pp. 7671-7680 ◽  
Author(s):  
Nils-Alexander Lakomek ◽  
Lukas Frey ◽  
Stefan Bibow ◽  
Anja Böckmann ◽  
Roland Riek ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Membrane Proteins ◽  
Solution State

Solid State Behaviour of "Dynamic Compounds": A 13C CO/MAS NMR Spectroscopy Study

Heterocycles ◽  
1987 ◽  
Vol 26 (2) ◽  
pp. 333 ◽  
Author(s):  
Jos� Elguero ◽  
Robert Faure ◽  
Emile-Jean Vincent ◽  
Andr� Rousseau
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Mas Nmr ◽  
Spectroscopy Study ◽  
State Behaviour

scholarly journals Exploring the Self-Assembled Tacticity in Aurophilic Polymeric Arrangements of Diphosphanegold(I) Fluorothiolates

Molecules ◽  
2019 ◽  
Vol 24 (23) ◽  
pp. 4422 ◽  
Author(s):  
Moreno-Alcántar ◽  
Salazar ◽  
Romo-Islas ◽  
Flores-Álamo ◽  
Torrens
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Structural Diversity ◽  
Supramolecular Structures ◽  
X Ray Diffraction ◽  
Ligand Effects ◽  
Rational Control ◽  
Solid State Structures ◽  
Further Development ◽  
Aurophilic Interactions

Despite the recurrence of aurophilic interactions in the solid-state structures of gold(I) compounds, its rational control, modulation, and application in the generation of functional supramolecular structures is an area that requires further development. The ligand effects over the aurophilic-based supramolecular structures need to be better understood. This paper presents the supramolecular structural diversity of a series of new 1,3-bis(diphenylphosphane)propane (dppp) gold(I) fluorinated thiolates with the general formula [Au2(SRF)2(μ-dppp)] (SRF = SC6F5 (1); SC6HF4-4 (2); SC6H3(CF3)2-3,5 (3); SC6H4CF3-2 (4); SC6H4CF3-4 (5); SC6H3F2-3,4 (6); SC6H3F2-3,5 (7); SC6H4F-2 (8); SC6H4F-3 (9); SC6H4F-4 (10)). These compounds were synthesized and characterized, and six of their solid-state crystalline structures were determined using single-crystal X-ray diffraction. In the crystalline arrangement, they form aurophilic-bridged polymers. In these systems, the changes in the fluorination patterns of the thiolate ligands tune the aurophilic-induced self-assembly of the compounds causing tacticity and chiral differentiation of the monomers. This is an example of the use of ligand effects on the tune of the supramolecular association of gold complexes.

Determination of extent of reaction in poly(mono- and dimethacrylates) using n.m.r. Comparison of solid-state and solution-state methods

Polymer ◽  
1997 ◽  
Vol 38 (9) ◽  
pp. 2041-2045 ◽  
Author(s):  
Frank Heatley ◽  
Majid Ali ◽  
John Godward ◽  
Karl Stonebank ◽  
David C. Watts ◽  
...  
Keyword(s):  
Solid State ◽  
Solution State

Structural Diversity of Copper Complexes with 2,2′-Dipyridyldisulfide. From Dimer to Infinite Sheet Structure Both in Solid State and in Solution

1998 ◽  
Vol 27 (10) ◽  
pp. 1067-1068 ◽  
Author(s):  
Sachiko Kubo ◽  
Takanori Nishioka ◽  
Keiichirou Ishikawa ◽  
Isamu Kinoshita ◽  
Kiyoshi Isobe
Keyword(s):  
Solid State ◽  
Copper Complexes ◽  
Structural Diversity ◽  
Sheet Structure

Ordered Solid‐State Microstructures of Conjugated Polymers Arising from Solution‐State Aggregation

2020 ◽  
Vol 132 (40) ◽  
pp. 17620-17624
Author(s):  
Ze‐Fan Yao ◽  
Zi‐Yuan Wang ◽  
Hao‐Tian Wu ◽  
Yang Lu ◽  
Qi‐Yi Li ◽  
...  
Keyword(s):  
Solid State ◽  
Conjugated Polymers ◽  
Solution State ◽  
State Aggregation

Solution- and solid-state photophysical and stimuli-responsive behavior in conjugated monoalkoxynaphthalene–naphthalimide donor–acceptor dyads

2015 ◽  
Vol 3 (46) ◽  
pp. 12156-12163 ◽  
Author(s):  
Cameron Peebles ◽  
Christopher D. Wight ◽  
Brent L. Iverson
Keyword(s):  
Solid State ◽  
Stimuli Responsive ◽  
Solution State ◽  
Donor Acceptor ◽  
Responsive Behavior

The solution-state, solid-state and exceptional stimuli-responsive properties of a series of aromatic conjugated monoalkoxynaphthalene–naphthalimide donor–acceptor dyads is reported.

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