Structural Diversity of Copper Complexes with 2,2′-Dipyridyldisulfide. From Dimer to Infinite Sheet Structure Both in Solid State and in Solution

1998 ◽  
Vol 27 (10) ◽  
pp. 1067-1068 ◽  
Author(s):  
Sachiko Kubo ◽  
Takanori Nishioka ◽  
Keiichirou Ishikawa ◽  
Isamu Kinoshita ◽  
Kiyoshi Isobe
Keyword(s):  
Solid State ◽  
Copper Complexes ◽  
Structural Diversity ◽  
Sheet Structure

Structural diversity of new solid-state luminophores based on quinoxaline-β-ketoiminate boron difluoride complexes with remarkable fluorescence switching properties

2015 ◽  
Vol 51 (13) ◽  
pp. 2656-2659 ◽  
Author(s):  
Chia-Wei Liao ◽  
Rajeswara Rao M. ◽  
Shih-Sheng Sun
Keyword(s):  
Solid State ◽  
Structural Diversity ◽  
Acid Base ◽  
Fluorescence Switching ◽  
Solid State Fluorescence ◽  
Boron Difluoride

Highly tunable organoboron luminophores with intense solid-state fluorescence showed outstanding photoswitching properties modulated by acid/base vapors.

Thiol end-capped titanium–copper complexes: Synthesis, solid state structure and electrochemical behavior

2008 ◽  
Vol 361 (6) ◽  
pp. 1659-1667 ◽  
Author(s):  
Heinrich Lang ◽  
Katrin Rößler ◽  
Deeb Taher ◽  
Rudolf Holze ◽  
Bernhard Walfort
Keyword(s):  
Solid State ◽  
Electrochemical Behavior ◽  
Copper Complexes ◽  
State Structure ◽  
Solid State Structure

scholarly journals Exploring the Self-Assembled Tacticity in Aurophilic Polymeric Arrangements of Diphosphanegold(I) Fluorothiolates

Molecules ◽  
2019 ◽  
Vol 24 (23) ◽  
pp. 4422 ◽  
Author(s):  
Moreno-Alcántar ◽  
Salazar ◽  
Romo-Islas ◽  
Flores-Álamo ◽  
Torrens
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Structural Diversity ◽  
Supramolecular Structures ◽  
X Ray Diffraction ◽  
Ligand Effects ◽  
Rational Control ◽  
Solid State Structures ◽  
Further Development ◽  
Aurophilic Interactions

Despite the recurrence of aurophilic interactions in the solid-state structures of gold(I) compounds, its rational control, modulation, and application in the generation of functional supramolecular structures is an area that requires further development. The ligand effects over the aurophilic-based supramolecular structures need to be better understood. This paper presents the supramolecular structural diversity of a series of new 1,3-bis(diphenylphosphane)propane (dppp) gold(I) fluorinated thiolates with the general formula [Au2(SRF)2(μ-dppp)] (SRF = SC6F5 (1); SC6HF4-4 (2); SC6H3(CF3)2-3,5 (3); SC6H4CF3-2 (4); SC6H4CF3-4 (5); SC6H3F2-3,4 (6); SC6H3F2-3,5 (7); SC6H4F-2 (8); SC6H4F-3 (9); SC6H4F-4 (10)). These compounds were synthesized and characterized, and six of their solid-state crystalline structures were determined using single-crystal X-ray diffraction. In the crystalline arrangement, they form aurophilic-bridged polymers. In these systems, the changes in the fluorination patterns of the thiolate ligands tune the aurophilic-induced self-assembly of the compounds causing tacticity and chiral differentiation of the monomers. This is an example of the use of ligand effects on the tune of the supramolecular association of gold complexes.

Structural diversity in aroylthiourea copper complexes – formation and biological evaluation of [Cu(i)(μ-S)SCl]2, cis-Cu(ii)S2O2, trans-Cu(ii)S2O2 and Cu(i)S3 cores

2016 ◽  
Vol 40 (6) ◽  
pp. 5401-5413 ◽  
Author(s):  
Nagamani Selvakumaran ◽  
Lakshmanan Sandhiya ◽  
Nattamai S. P. Bhuvanesh ◽  
Kittusamy Senthilkumar ◽  
Ramasamy Karvembu
Keyword(s):  
Copper Complexes ◽  
Structural Diversity ◽  
Biological Evaluation ◽  
Ct Dna

Four different copper complexes containing aroylthiourea ligands displayed good interaction with CT DNA and BSA and cytotoxicity.

Solid state electrical conductivity properties of copper complexes of novel oxime compounds containing oxolane ring

2003 ◽  
Vol 57 (24-25) ◽  
pp. 3755-3760 ◽  
Author(s):  
Y Aydogdu ◽  
F Yakuphanoglu ◽  
A Aydogdu ◽  
E Tas ◽  
A Cukurovali
Keyword(s):  
Electrical Conductivity ◽  
Solid State ◽  
Copper Complexes

scholarly journals Synthesis and structure study of new manganese and indium based phosphate: (Ca,Ba)1.222Mn0.923In1.570(PO4)3

2018 ◽  
Vol 149 ◽  
pp. 01085
Author(s):  
Elhassan Benhsina ◽  
Abderrazzak Assani ◽  
Mohamed Saadi ◽  
Lahcen El Ammari
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Three Dimensional ◽  
Structural Diversity ◽  
Structure Study ◽  
Important Class ◽  
Common Edge ◽  
Monoclinic System ◽  
Metal Phosphates ◽  
Cell Parameters

Phosphates are an important class of materials which are well-known due to their structural diversity and their important potential application in many fields of sciences. A member of this family, represented by transition metal phosphates, is in the forefront of important researchers. A new manganese and indium based phosphate is successfully isolated by means of solid state reaction. Its corresponding crystal structure is isotypic to the alluaudite and crystallizes in the monoclinic system with the space group C2/c and cell parameters a=12.4697(5)Å ; b=12.9365(5)Å ; c=6.5625(3)Å and β=115.603(1)°. The framework of this phosphate is built up on the basis of MnO6, InO6 and PO4 polyhedra. The InO6 octahedra are linked together via common edge, leading to the formation of In2O10 dimers. The In2O10 dimers share edge with MnO6 octahedra, generating chains along the [101] direction. The PO4 tetrahedra connect two chains giving arise to a three-dimensional framework with hexagonal tunnels where the barium and calcium are located.

Supramolecular variations on a molecular theme: the structural diversity of phosphazenes (RNH)6P3N3 in the solid state

2003 ◽  
pp. 1235-1244 ◽  
Author(s):  
Jamie F. Bickley ◽  
Richard Bonar-Law ◽  
Gavin T. Lawson ◽  
Philip I. Richards ◽  
Frederic Rivals ◽  
...  
Keyword(s):  
Solid State ◽  
Structural Diversity

Parallel β-Sheet Structure of Alanine Tetrapeptide in the Solid State As Studied by Solid-State NMR Spectroscopy

2016 ◽  
Vol 120 (34) ◽  
pp. 8932-8941 ◽  
Author(s):  
Tetsuo Asakura ◽  
Kumiko Horiguchi ◽  
Akihiro Aoki ◽  
Yugo Tasei ◽  
Akira Naito
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Solid State Nmr Spectroscopy ◽  
Sheet Structure ◽  
Β Sheet

Six-coordinate copper complexes wlth g

1979 ◽  
Vol 29 (1) ◽  
pp. 67-84 ◽  
Author(s):  
Ivano Bertini ◽  
Dante Gatteschi ◽  
Andrea Scozzafava
Keyword(s):  
Solid State ◽  
Copper Complexes
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