Mechanistic Insights into CoOx–Ag/CeO2 Catalysts for the Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid

2021 ◽  
Author(s):  
Chun Shen ◽  
Mengchen Fu ◽  
Weiyao Yang ◽  
Chenyu Yang ◽  
Yiwen Zhang
Keyword(s):  
Aerobic Oxidation ◽  
Furandicarboxylic Acid ◽  
Ag Catalysts

Although Ag catalysts harbors potential for 5-hydroxymethylfurfural (HMF) oxidation to 5-hydroxymethyl-2-furancarboxylic acid (HMFCA), further oxidation into 2,5-furandicarboxylic acid (FDCA) remains a severe challenge. Herein, we propose a strategy to synthesize...

Aerobic Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid over Holey 2 D Mn 2 O 3 Nanoflakes from a Mn‐based MOF

ChemSusChem ◽  
2019 ◽  
Vol 13 (3) ◽  
pp. 548-555 ◽  
Author(s):  
Liwei Bao ◽  
Fang‐Zhou Sun ◽  
Guo‐Ying Zhang ◽  
Tong‐Liang Hu
Keyword(s):  
Aerobic Oxidation ◽  
Furandicarboxylic Acid

Fe–Zr–O catalyzed base-free aerobic oxidation of 5-HMF to 2,5-FDCA as a bio-based polyester monomer

2018 ◽  
Vol 8 (1) ◽  
pp. 164-175 ◽  
Author(s):  
Dongxia Yan ◽  
Jiayu Xin ◽  
Qiu Zhao ◽  
Kai Gao ◽  
Xingmei Lu ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Aerobic Oxidation ◽  
Reaction System ◽  
Environment Friendly ◽  
Furandicarboxylic Acid

An environment-friendly and economical route for 5-hydroxymethylfurfural (HMF) aerobic oxidation to 2,5-furandicarboxylic acid (FDCA) in an ionic liquid (IL)-promoted base-free reaction system was reported using Fe–Zr–O as a catalyst.

Selective aerobic oxidation of the biomass-derived precursor 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under mild conditions over a magnetic palladium nanocatalyst

2015 ◽  
Vol 17 (2) ◽  
pp. 1308-1317 ◽  
Author(s):  
Zehui Zhang ◽  
Judun Zhen ◽  
Bing Liu ◽  
Kangle Lv ◽  
Kejian Deng
Keyword(s):  
Aerobic Oxidation ◽  
High Yield ◽  
Mild Conditions ◽  
Furandicarboxylic Acid ◽  
Selective Aerobic Oxidation

High yield of 2,5-furandicarboxylic acid was achieved from the aerobic oxidation of 5-hydroxymethylfurfural over a magnetic palladium nanocatalyst.

Selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over MnOx–CeO2 composite catalysts

2017 ◽  
Vol 19 (4) ◽  
pp. 996-1004 ◽  
Author(s):  
Xuewang Han ◽  
Chaoqun Li ◽  
Xiaohui Liu ◽  
Qineng Xia ◽  
Yanqin Wang
Keyword(s):  
Selective Oxidation ◽  
Noble Metal ◽  
Mixed Oxides ◽  
Aerobic Oxidation ◽  
Metal Catalysts ◽  
Precipitation Method ◽  
Composite Catalysts ◽  
Noble Metal Catalysts ◽  
Furandicarboxylic Acid ◽  
Co Precipitation

Non-noble metal catalysts, MnOx–CeO2 mixed oxides, were prepared by a co-precipitation method and used in the direct aerobic oxidation of HMF to FDCA, showing excellent catalystic activity and stability.

Back Cover: Heterogeneously-Catalyzed Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid with MnO2 (ChemSusChem 4/2017)

ChemSusChem ◽  
2017 ◽  
Vol 10 (4) ◽  
pp. 815-815
Author(s):  
Eri Hayashi ◽  
Tasuku Komanoya ◽  
Keigo Kamata ◽  
Michikazu Hara
Keyword(s):  
Aerobic Oxidation ◽  
Back Cover ◽  
Furandicarboxylic Acid

Tunable mixed oxides based on CeO2 for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to FDCA in water

2018 ◽  
Vol 20 (17) ◽  
pp. 3921-3926 ◽  
Author(s):  
Maria Ventura ◽  
Francesco Nocito ◽  
Elvira de Giglio ◽  
Stefania Cometa ◽  
Angela Altomare ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Mixed Oxides ◽  
Aerobic Oxidation ◽  
Hydroxymethyl Furfural ◽  
Furandicarboxylic Acid ◽  
Selective Aerobic Oxidation

The selective oxidation of 5-HMF towards 2,5-furandicarboxylic acid (FDCA) has been achieved with 99% yield in water, using oxygen as the oxidant over CuO·MnO2·CeO2 mixed oxides.

A novel magnetic palladium catalyst for the mild aerobic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid in water

2015 ◽  
Vol 5 (6) ◽  
pp. 3194-3202 ◽  
Author(s):  
Nan Mei ◽  
Bing Liu ◽  
Judun Zheng ◽  
Kangle Lv ◽  
Dingguo Tang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Palladium Catalyst ◽  
Palladium Nanoparticles ◽  
Aerobic Oxidation ◽  
High Catalytic Activity ◽  
Supported Palladium ◽  
Magnetically Separable ◽  
Furandicarboxylic Acid

Magnetically separable, graphene oxide-supported palladium nanoparticles showed high catalytic activity for the aerobic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.

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