Theoretical Investigation of CH-Bond Activation by photocatalytic excited SO2 and Effects of (C-, N-, S-, Se-) doped TiO2

Physical Chemistry Chemical Physics ◽

10.1039/d1cp04335h ◽

2021 ◽

Author(s):

Luca Gerhards ◽

Thorsten Klüner

Keyword(s):

Theoretical Investigation ◽

Lower Energy ◽

Bond Activation ◽

Sulfonic Acids ◽

Doped Tio2 ◽

Ch Bond Activation

The photocatalytic sulfoxidation on TiO2 found by Parrino et al. represents a new interesting and lower energy route for the synthesis of sulfonic acids. Sulfonic acids are an important precursor...

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[Cp2TiCH2CHMe(SiMe3)]+, an Alkyl–Titanium Complex Which (a) Exists in Equilibrium between a β-Agostic and a Lower Energy γ-Agostic Isomer and (b) Undergoes Hydrogen Atom Exchange between α-, β-, and γ-Sites via a Combination of Conventional β-Hydrogen Elimination–Reinsertion and a Nonconventional CH Bond Activation Process Which Involves Proton Tunnelling

Journal of the American Chemical Society ◽

10.1021/ja4092775 ◽

2013 ◽

Vol 135 (46) ◽

pp. 17514-17527 ◽

Cited By ~ 17

Author(s):

Alexandre F. Dunlop-Brière ◽

Michael C. Baird ◽

Peter H. M. Budzelaar

Keyword(s):

Hydrogen Atom ◽

Lower Energy ◽

Bond Activation ◽

Activation Process ◽

Titanium Complex ◽

Hydrogen Elimination ◽

Ch Bond Activation

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CH Bond Activation as a Powerful Tool in the Construction of Biologically Active Nitrogen-Containing Heterocycles

Studies in Natural Products Chemistry ◽

10.1016/b978-0-444-63749-9.00009-8 ◽

2016 ◽

pp. 299-340 ◽

Cited By ~ 1

Author(s):

Qitao Tan ◽

Bin Xu

Keyword(s):

Bond Activation ◽

Biologically Active ◽

Active Nitrogen ◽

Ch Bond Activation

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Cobalt induced CH bond activation and C8-arylation of caffeine with aryl bromides

Inorganic Chemistry Communications ◽

10.1016/j.inoche.2013.01.025 ◽

2013 ◽

Vol 30 ◽

pp. 139-142 ◽

Cited By ~ 9

Author(s):

Tingting Zheng ◽

Hongjian Sun ◽

Faguan Lu ◽

Klaus Harms ◽

Xiaoyan Li

Keyword(s):

Bond Activation ◽

Aryl Bromides ◽

Ch Bond Activation

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Theoretical investigation of the reactivity in the C–F bond activation of CH3F by Lu+ in the gas phase

Chemical Physics Letters ◽

10.1016/j.cplett.2006.09.056 ◽

2006 ◽

Vol 431 (4-6) ◽

pp. 223-226 ◽

Cited By ~ 11

Author(s):

Ze-Yu Liu ◽

Yong-Cheng Wang ◽

Zhi-Yuan Geng ◽

Xiao-Yan Yang ◽

Han-Qing Wang

Keyword(s):

Gas Phase ◽

Theoretical Investigation ◽

Bond Activation

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CH bond activation in the presence or absence of oxygen or nitrous oxide

Reaction Kinetics and Catalysis Letters ◽

10.1023/b:reac.0000034853.52513.86 ◽

2004 ◽

Vol 82 (2) ◽

pp. 401-409 ◽

Cited By ~ 3

Author(s):

Abdelhakim Kaddouri

Keyword(s):

Nitrous Oxide ◽

Bond Activation ◽

Ch Bond Activation

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CH Bond Activation of Methane by a Transient η2-Cyclopropene/Metallabicyclobutane Complex of Niobium

Journal of the American Chemical Society ◽

10.1021/jacs.5b07859 ◽

2015 ◽

Vol 137 (39) ◽

pp. 12450-12453 ◽

Cited By ~ 19

Author(s):

Chen Li ◽

Chiara Dinoi ◽

Yannick Coppel ◽

Michel Etienne

Keyword(s):

Bond Activation ◽

Ch Bond Activation

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Alumina-supported vanadyl complexes as catalysts for the CH bond activation of cyclohexene with tert-butylhydroperoxide

Journal of Molecular Catalysis A Chemical ◽

10.1016/j.molcata.2004.07.007 ◽

2004 ◽

Vol 221 (1-2) ◽

pp. 169-175 ◽

Cited By ~ 48

Author(s):

M. Salavati-Niasari ◽

M.R. Elzami ◽

M.R. Mansournia ◽

S. Hydarzadeh

Keyword(s):

Bond Activation ◽

Vanadyl Complexes ◽

Tert Butylhydroperoxide ◽

Ch Bond Activation

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α-CH Bond Activation of Coordinated Et2O via Reaction of PR3(R = Ph, Cy) with the Cationic Complex [C5Me5W(CO)3(OEt2)]+

Organometallics ◽

10.1021/om950790z ◽

1996 ◽

Vol 15 (1) ◽

pp. 2-4 ◽

Cited By ~ 7

Author(s):

Chae S. Yi ◽

Dariusz Wódka ◽

Arnold L. Rheingold ◽

Glenn P. A. Yap

Keyword(s):

Bond Activation ◽

Cationic Complex ◽

Ch Bond Activation

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Lewis Bases Trigger Intramolecular CH-Bond Activation: (tBu3SiO)2W=NtBu [rlhar2] (tBu3SiO)(κO,κC-tBu2SiOCMe2CH2)HW=NtBu

European Journal of Inorganic Chemistry ◽

10.1002/ejic.201300234 ◽

2013 ◽

Vol 2013 (22-23) ◽

pp. 4056-4067 ◽

Cited By ~ 6

Author(s):

Michael P. Marshak ◽

Devon C. Rosenfeld ◽

Wesley D. Morris ◽

Peter T. Wolczanski ◽

Emil B. Lobkovsky ◽

...

Keyword(s):

Bond Activation ◽

Lewis Bases ◽

Ch Bond Activation

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CH Bond Activation of Unsaturated Hydrocarbons by a Niobium Methyl Cyclopropyl Precursor. Cyclopropyl Ring Opening and Alkyne Coupling Reaction

Organometallics ◽

10.1021/acs.organomet.6b00506 ◽

2016 ◽

Vol 36 (1) ◽

pp. 53-63 ◽

Cited By ~ 9

Author(s):

Pascal Oulié ◽

Chiara Dinoi ◽

Chen Li ◽

Alix Sournia-Saquet ◽

Kane Jacob ◽

...

Keyword(s):

Ring Opening ◽

Bond Activation ◽

Coupling Reaction ◽

Unsaturated Hydrocarbons ◽

Ch Bond Activation ◽

Alkyne Coupling

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