scholarly journals Two-dimensional Cahn-Hilliard simulations for coarsening kinetics of spinodal decomposition in binary mixtures

Author(s):  
Björn König ◽  
Olivier Ronsin ◽  
Jens Harting

The evolution of the microstructure due to spinodal decomposition in phase separated mixtures has a strong impact on the final material properties. In the late stage of coarsening, the system...

1998 ◽  
Vol 09 (08) ◽  
pp. 1373-1382 ◽  
Author(s):  
Alexander J. Wagner ◽  
J. M. Yeomans

We use lattice-Boltzmann simulations to examine late stage spinodal decomposition in binary fluids, showing that the scaling hypothesis for phase ordering does not hold in all cases. We also examine the effects of an applied shear on the coarsening of the spinodal pattern.


2003 ◽  
Vol 90 (1) ◽  
Author(s):  
V. M. Kaganer ◽  
W. Braun ◽  
B. Jenichen ◽  
L. Däweritz ◽  
K. H. Ploog

2003 ◽  
Vol 68 (8) ◽  
pp. 1407-1419 ◽  
Author(s):  
Claudio Fontanesi ◽  
Roberto Andreoli ◽  
Luca Benedetti ◽  
Roberto Giovanardi ◽  
Paolo Ferrarini

The kinetics of the liquid-like → solid-like 2D phase transition of adenine adsorbed at the Hg/aqueous solution interface is studied. Attention is focused on the effect of temperature on the rate of phase change; an increase in temperature is found to cause a decrease of transition rate.


2021 ◽  
pp. 174425912198938
Author(s):  
Michael Gutland ◽  
Scott Bucking ◽  
Mario Santana Quintero

Hygrothermal models are important tools for assessing the risk of moisture-related decay mechanisms which can compromise structural integrity, loss of architectural features and material. There are several sources of uncertainty when modelling masonry, related to material properties, boundary conditions, quality of construction and two-dimensional interactions between mortar and unit. This paper examines the uncertainty at the mortar-unit interface with imperfections such as hairline cracks or imperfect contact conditions. These imperfections will alter the rate of liquid transport into and out of the wall and impede the liquid transport between mortar and masonry unit. This means that the effective liquid transport of the wall system will be different then if only properties of the bulk material were modelled. A detailed methodology for modelling this interface as a fracture is presented including definition of material properties for the fracture. The modelling methodology considers the combined effect of both the interface resistance across the mortar-unit interface and increase liquid transport in parallel to the interface, and is generalisable to various combinations of materials, geometries and fracture apertures. Two-dimensional DELPHIN models of a clay brick/cement-mortar masonry wall were created to simulate this interaction. The models were exposed to different boundary conditions to simulate wetting, drying and natural cyclic weather conditions. The results of these simulations were compared to a baseline model where the fracture model was not included. The presence of fractures increased the rate of absorption in the wetting phase and an increased rate of desorption in the drying phase. Under cyclic conditions, the result was higher peak moisture contents after rain events compared to baseline and lower moisture contents after long periods of drying. This demonstrated that detailed modelling of imperfections at the mortar-unit interface can have a definitive influence on results and conclusions from hygrothermal simulations.


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