Origin of Asynchronicity in Diels-Alder Reactions

Physical Chemistry Chemical Physics ◽

10.1039/d1cp02456f ◽

2021 ◽

Author(s):

Pascal Vermeeren ◽

Trevor A. Hamlin ◽

F. Matthias Bickelhaupt

Keyword(s):

Crucial Role ◽

Diels Alder ◽

Orbital Interaction ◽

Reaction Barrier

Asynchronicity in Diels-Alder reactions plays a crucial role in determining the height of the reaction barrier. Currently, the origin of asynchronicity is ascribed to the stronger orbital interaction between the...

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ChemInform Abstract: Solvent Effect as the Result of Frontier Molecular-Orbital Interaction. Part 3. Hetero Diels-Alder Reaction with Inverse Electron Demand Between 4-Arylidenepyrazol-5-ones and Isobutyl Vinyl Ether.

ChemInform ◽

10.1002/chin.198946075 ◽

1989 ◽

Vol 20 (46) ◽

Author(s):

M. BURDISSO ◽

G. DESIMONI ◽

G. FAITA ◽

P. RIGHETTI ◽

G. TACCONI

Keyword(s):

Solvent Effect ◽

Vinyl Ether ◽

Molecular Orbital ◽

Alder Reaction ◽

Diels Alder ◽

Frontier Molecular Orbital ◽

Orbital Interaction ◽

Inverse Electron Demand ◽

Diels Alder Reaction ◽

Electron Demand

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Solvent effect as the result of frontier molecular orbital interaction. VII. The retro-diels-alder reaction.

Tetrahedron ◽

10.1016/s0040-4020(01)88725-1 ◽

1992 ◽

Vol 48 (9) ◽

pp. 1667-1674 ◽

Cited By ~ 21

Author(s):

G. Desimoni ◽

G. Faita ◽

D. Pasini ◽

P.P. Righetti

Keyword(s):

Solvent Effect ◽

Molecular Orbital ◽

Alder Reaction ◽

Diels Alder ◽

Frontier Molecular Orbital ◽

Orbital Interaction ◽

Diels Alder Reaction

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ChemInform Abstract: Solvent Effect as the Result of Frontier Molecular Orbital Interaction. Part 7. The Retro-Diels-Alder Reaction.

ChemInform ◽

10.1002/chin.199225057 ◽

2010 ◽

Vol 23 (25) ◽

pp. no-no

Author(s):

G. DESIMONI ◽

G. FAITA ◽

D. PASINI ◽

P. P. RIGHETTI

Keyword(s):

Solvent Effect ◽

Molecular Orbital ◽

Alder Reaction ◽

Diels Alder ◽

Frontier Molecular Orbital ◽

Orbital Interaction ◽

Diels Alder Reaction

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Solvent effect as the result of frontier molecular-orbital interaction. Part 3. Hetero Diels–Alder reaction with inverse electron demand between 4-arylidenepyrazol-5-ones and isobutyl vinyl ether

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29890000845 ◽

1989 ◽

pp. 845-850 ◽

Cited By ~ 8

Author(s):

Marina Burdisso ◽

Giovanni Desimoni ◽

Giuseppe Faita ◽

Pierpaolo Righetti ◽

Gianfranco Tacconi

Keyword(s):

Solvent Effect ◽

Vinyl Ether ◽

Molecular Orbital ◽

Alder Reaction ◽

Diels Alder ◽

Frontier Molecular Orbital ◽

Orbital Interaction ◽

Inverse Electron Demand ◽

Diels Alder Reaction ◽

Electron Demand

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ChemInform Abstract: A Three-Center Orbital Interaction in the Diels-Alder Reactions Catalyzed by Lewis Acids.

ChemInform ◽

10.1002/chin.200025051 ◽

2010 ◽

Vol 31 (25) ◽

pp. no-no

Author(s):

Shinichi Yamabe ◽

Tsutomu Minato

Keyword(s):

Lewis Acids ◽

Diels Alder ◽

Orbital Interaction

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Solvent effect as the result of frontier molecular orbital interaction. V. Diels-Alder with heterodienophiles: a unified approach to the solvent effect of the Diels-Alder reactions

Tetrahedron ◽

10.1016/s0040-4020(01)90093-6 ◽

1990 ◽

Vol 46 (23) ◽

pp. 7951-7970 ◽

Cited By ~ 45

Author(s):

G. Desimoni ◽

G. Faita ◽

P.P. Righetti ◽

L. Toma

Keyword(s):

Solvent Effect ◽

Molecular Orbital ◽

Diels Alder ◽

Frontier Molecular Orbital ◽

Orbital Interaction ◽

Unified Approach

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ChemInform Abstract: Solvent Effect as the Result of Frontier Molecular Orbital Interaction. Part 4. A Parallel Between Solvent Effect and Acid Catalysis in the Intramolecular Hetero-Diels-Alder Reaction.

ChemInform ◽

10.1002/chin.198926074 ◽

1989 ◽

Vol 20 (26) ◽

Author(s):

A. CORSICO CODA ◽

G. DESIMONI ◽

G. FAITA ◽

P. RIGHETTI ◽

G. TACCONI

Keyword(s):

Solvent Effect ◽

Molecular Orbital ◽

Acid Catalysis ◽

Alder Reaction ◽

Diels Alder ◽

Frontier Molecular Orbital ◽

Orbital Interaction ◽

Diels Alder Reaction

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ChemInform Abstract: Solvent Effect as the Result of Frontier Molecular Orbital Interaction. Part 6. The Diels-Alder Reactions of an N-Acyl-o-quinone Monoimide Behaving as Diene or Dienophile.

ChemInform ◽

10.1002/chin.199143070 ◽

2010 ◽

Vol 22 (43) ◽

pp. no-no

Author(s):

G. DESIMONI ◽

G. FAITA ◽

P. P. RIGHETTI

Keyword(s):

Solvent Effect ◽

Molecular Orbital ◽

Diels Alder ◽

Frontier Molecular Orbital ◽

Orbital Interaction

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A Three-Center Orbital Interaction in the Diels−Alder Reactions Catalyzed by Lewis Acids

The Journal of Organic Chemistry ◽

10.1021/jo9919310 ◽

2000 ◽

Vol 65 (6) ◽

pp. 1830-1841 ◽

Cited By ~ 29

Author(s):

Shinichi Yamabe ◽

Tsutomu Minato

Keyword(s):

Lewis Acids ◽

Diels Alder ◽

Orbital Interaction

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ChemInform Abstract: Solvent Effect as the Result of Frontier Molecular Orbital Interaction. Part 5. Diels-Alder with Heterodienophiles: A Unified Approach to the Solvent Effect of the Diels-Alder Reactions.

ChemInform ◽

10.1002/chin.199109067 ◽

2010 ◽

Vol 22 (9) ◽

pp. no-no

Author(s):

G. DESIMONI ◽

G. FAITA ◽

P. P. RIGHETTI ◽

L. TOMA

Keyword(s):

Solvent Effect ◽

Molecular Orbital ◽

Diels Alder ◽

Frontier Molecular Orbital ◽

Orbital Interaction ◽

Unified Approach

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