scholarly journals Spin-spin interactions and spin delocalisation in a doped organic semiconductor probed by EPR spectroscopy

Author(s):  
Claudia E. Tait ◽  
Anna Reckwitz ◽  
Malavika Arvind ◽  
Dieter Neher ◽  
Robert Bittl ◽  
...  

The enhancement and control of the electrical conductivity of organic semiconductors is fundamental for their use in optoelectronic applications and can be achieved by molecular doping, which introduces additional charge...

Author(s):  
Nathan J Yutronkie ◽  
Benjamin King ◽  
Owen Alfred Melville ◽  
Benoit Hugo Lessard ◽  
Jaclyn L Brusso

The perfluorinated analogue of silicon phthalocyanine (F2-F16SiPc) has been synthesized as a novel air-stable n-type organic semiconductor. The design of F2-F16SiPc facilitates strong electron conduction through peripheral fluorination that deepens...


2020 ◽  
Vol 12 (50) ◽  
pp. 56222-56230
Author(s):  
Marten Koopmans ◽  
Miina A. T. Leiviskä ◽  
Jian Liu ◽  
Jingjin Dong ◽  
Li Qiu ◽  
...  

2009 ◽  
Vol 21 (20) ◽  
pp. NA-NA
Author(s):  
Sarah A. Burke ◽  
Jeffrey M. LeDue ◽  
Jessica M. Topple ◽  
Shawn Fostner ◽  
Peter Grütter

2021 ◽  
Author(s):  
Yuze Zhang ◽  
Alina Chen ◽  
Min-Woo Kim ◽  
Aida Alaei ◽  
Stephanie S. Lee

This tutorial review highlights the role of nanoconfinement in selecting for orientations and polymorphs of organic semiconductor crystals that are optimized for optoelectronic processes, including charge transport and light emission.


2019 ◽  
Vol 43 (20) ◽  
pp. 7790-7796 ◽  
Author(s):  
Lei Yang ◽  
Jie Mao ◽  
Cheng-Zhu Yin ◽  
Mohamad Akbar Ali ◽  
Xiang-Ping Wu ◽  
...  

The lower charge mobility of organic semiconductors relative to that of inorganic semiconductors is a thorny problem that still has not been resolved.


Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1727 ◽  
Author(s):  
Ji-Hyun Lee ◽  
Armand Perrot ◽  
Masahiro Hiramoto ◽  
Seiichiro Izawa

Clarifying critical differences in free charge generation and recombination processes between inorganic and organic semiconductors is important for developing efficient organic photoconversion devices such as solar cells (SCs) and photodetector. In this study, we analyzed the dependence of doping concentration on the photoconversion process at the organic pn-homojunction interface in a single organic semiconductor using the temperature dependence of J–V characteristics and energy structure measurements. Even though the organic pn-homojunction SC devices were fabricated using a single host material and the doping technique resembling an inorganic pn-homojunction, the charge generation and recombination mechanisms are similar to that of conventional donor/acceptor (D/A) type organic SCs; that is, the charge separation happens from localized exciton and charge transfer (CT) state being separated by the energy offset between adjacent molecules, and the recombination happens from localized charge carrier at two adjacent molecules. The determining factor for photoconversion processes is the localized nature of charges in organic semiconductors. The results demonstrated that controlling the delocalization of the charges is important to realize efficient organic photoconversion devices.


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