scholarly journals Multi-color mechanochromic luminescence of three polymorphic crystals of a donor–acceptor-type benzothiadiazole derivative

CrystEngComm ◽  
2021 ◽  
Author(s):  
Suguru Ito ◽  
Sayaka Nagai ◽  
Takashi Ubukata ◽  
Takashi Tachikawa

The past decade has witnessed rapid advances in the development of organic crystals that exhibit mechanochromic luminescence (MCL), i.e., the reversible color change of photoluminescence induced by mechanical force. However,...

CrystEngComm ◽  
2022 ◽  
Author(s):  
Suguru Ito

Mechanoresponsive luminescent organic crystals have recently attracted increasing interest owing to their potential applications in advanced optoelectronic devices, mechanosensors, security technologies, etc. In the past few years, an increasing number...


2019 ◽  
Vol 7 (10) ◽  
pp. 3100-3104 ◽  
Author(s):  
Ning-Ning Zhang ◽  
Rong-Jian Sa ◽  
Shan-Shan Sun ◽  
Ming-De Li ◽  
Ming-Sheng Wang ◽  
...  

An unprecedented series of triazole-based donor–acceptor molecules were found to form highly air/heat-stable triplet diradicals in the solid state accompanied by a color change after photoinduced intramolecular charge separation.


2020 ◽  
Vol 56 (72) ◽  
pp. 10394-10408
Author(s):  
Chaowei Zhao ◽  
Fan Yang ◽  
Dongdong Xia ◽  
Zhou Zhang ◽  
Yuefeng Zhang ◽  
...  

Thieno[3,4-c]pyrrole-4,6-dione (TPD) based conjugated polymers as an electron donor, acceptor and single-component for application in organic solar cells in the past ten years have been intensively reviewed in this Feature Article.


2019 ◽  
Vol 7 (32) ◽  
pp. 9808-9812 ◽  
Author(s):  
Bin Huang ◽  
Dawei Jiang ◽  
Yan Feng ◽  
Wen-Cheng Chen ◽  
Ying Zhang ◽  
...  

A novel donor–acceptor emitter exhibiting mechanochromic luminescence was used in light-emitting devices with tunable colors triggered by heat treatment.


2015 ◽  
Vol 3 (13) ◽  
pp. 3049-3054 ◽  
Author(s):  
Yujian Zhang ◽  
Qingbao Song ◽  
Kai Wang ◽  
Wengang Mao ◽  
Feng Cao ◽  
...  

The organic crystals BCrys, SCrys and YCrys with the blue, sky-blue, and yellow fluorescence, respectively exhibit the responsive fluorescence switching under grinding, heating and solvent vapour stimulation.


Author(s):  
Jing-Ju Huang ◽  
Hsing-An Lin ◽  
Chi Chen ◽  
Po-Wen Tang ◽  
Shyh-Chyang Luo

π−Conjugated polymers have received increasing attention in electrochromic material research because their color change can be altered over a wide range by introducing electron-donor (D) and electron-acceptor (A) moieties. In...


2015 ◽  
Vol 3 (3) ◽  
pp. 499-505 ◽  
Author(s):  
Lu Wang ◽  
Zhenyu Zhang ◽  
Xiao Cheng ◽  
Kaiqi Ye ◽  
Feng Li ◽  
...  

The present study not only provides a rare example of organic crystals with highly efficient red fluorescence but also indicates the possible application of four-coordinate boron materials in organic solid-state lasers.


Chemosensors ◽  
2019 ◽  
Vol 7 (3) ◽  
pp. 38 ◽  
Author(s):  
Pramod D. Jawale Patil ◽  
Rajita D. Ingle ◽  
Sopan M. Wagalgave ◽  
Rajesh S. Bhosale ◽  
Sidhanath V. Bhosale ◽  
...  

Although chemical structural modification of naphthalimides is widely employed for the purpose of sensing explosives, the effects of such modification have been little explored. Herein, we report the design and synthesis of a new naphthalimide-benzothiazole conjugate (1) and its ability to sense various nitrophenols by means of its colorimetric and fluorescent characteristics. Under long-range UV light (365 nm), 1 displayed a color change of its solution from bluish to colorless only upon addition of 2,4,6-trinitrophenol (TNP). Photoluminescence spectroscopy showed quantitative fluorescence quenching by TNP of the emission peaks of 1 at 398 nm and 418 nm due to donor–acceptor electron transfer. The interaction of 1 with TNP was via a cooperative, non-covalent hydrogen-bonding interaction. Receptor 1 exhibited high sensitivity and selectivity towards TNP over various aromatic nitro analytes. The binding constant (K) and Stern–Volmer constant (Ksv) between 1 and TNP were found to be 5.332 × 10−5 M and 2.271 × 106 M−1, respectively. Furthermore, the limit of detection was calculated and found to be as low as 1.613 × 10−10 M.


2020 ◽  
Vol 56 (92) ◽  
pp. 14435-14438
Author(s):  
Cai-Xin Yan ◽  
Qian-Qian Lin ◽  
Sha Li ◽  
Cheng-Juan Wu ◽  
Yan-An Li ◽  
...  

Donor–acceptor fulvene-containing boron complexes exhibit aggregation-induced emission (AIE), bioimaging properties, and mechanochromic luminescence.


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