Dynamic Vapochromic Behaviors of Organic Crystals Based on the Open-Close Motions of S-Shaped Donor-Acceptor Folding Units

2010 ◽  
Vol 16 (16) ◽  
pp. 4793-4802 ◽  
Author(s):  
Eiji Takahashi ◽  
Hikaru Takaya ◽  
Takeshi Naota
1989 ◽  
Vol 173 ◽  
Author(s):  
Malcolm R. McLean ◽  
Mamoun Badr ◽  
Larry R. Dalton ◽  
Robert L. S. Devine ◽  
William H. Steier

ABSTRACTA series of fused three-ring compounds have been synthesized and characterized for their possible use as organic crystals for second-harmonic generation. Polymer films doped with these compounds were aligned via corona poling and their second order non-linear optical properties compared with layers doped with stilbene like molecules. Values of ¼β0 have been obtained and the effects of different heteroatoms and substituents on λ max and on ¼β0 were examined. An X-ray diffraction crystal structure on one member of the series, 1,2,4-Trichloro-8-nitro-phenoxazin-3-one (Compound 1), revealed a centrosymmetric crystal habit in a P21/n space group, with a = 9.829(3), b = 8.300(2) and c = 15.542(4) Å. Final R(F) = 0.0939 for 754 reflections where I σ; 3σ(I).


CrystEngComm ◽  
2021 ◽  
Author(s):  
Suguru Ito ◽  
Sayaka Nagai ◽  
Takashi Ubukata ◽  
Takashi Tachikawa

The past decade has witnessed rapid advances in the development of organic crystals that exhibit mechanochromic luminescence (MCL), i.e., the reversible color change of photoluminescence induced by mechanical force. However,...


Author(s):  
E. Knapek ◽  
H. Formanek ◽  
G. Lefranc ◽  
I. Dietrich

A few years ago results on cryoprotection of L-valine were reported, where the values of the critical fluence De i.e, the electron exposure which decreases the intensity of the diffraction reflections by a factor e, amounted to the order of 2000 + 1000 e/nm2. In the meantime a discrepancy arose, since several groups published De values between 100 e/nm2 and 1200 e/nm2 /1 - 4/. This disagreement and particularly the wide spread of the results induced us to investigate more thoroughly the behaviour of organic crystals at very low temperatures during electron irradiation.For this purpose large L-valine crystals with homogenuous thickness were deposited on holey carbon films, thin carbon films or Au-coated holey carbon films. These specimens were cooled down to nearly liquid helium temperature in an electron microscope with a superconducting lens system and irradiated with 200 keU-electrons. The progress of radiation damage under different preparation conditions has been observed with series of electron diffraction patterns and direct images of extinction contours.


1980 ◽  
Vol 41 (7) ◽  
pp. 707-712 ◽  
Author(s):  
A. Poure ◽  
G. Aguero ◽  
G. Masse ◽  
J.P. Aicardi

2008 ◽  
Author(s):  
Derck Schlettwein ◽  
Robin Knecht ◽  
Dominik Klaus ◽  
Christopher Keil ◽  
Günter Schnurpfeil

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