Rational design of self-supported Ni3S2 nanoparticles as a battery type electrode material for high-voltage (1.8 V) symmetric supercapacitor applications

CrystEngComm ◽  
2021 ◽  
Author(s):  
Muhammad Sajjad ◽  
Yaqoob Khan

We developed a high performance SSC device with excellent electrochemical performance in terms of specific capacitance, rate capability, energy density and power density which surpasses most of the reports.

Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1143 ◽  
Author(s):  
Anil Yedluri ◽  
Tarugu Anitha ◽  
Hee-Je Kim

Hierarchical NiMoO4/NiMoO4 nanoflowers were fabricated on highly conductive flexible nickel foam (NF) substrates using a facile hydrothermal method to achieve rapid charge-discharge ability, high energy density, long cycling lifespan, and higher flexibility for high-performance supercapacitor electrode materials. The synthesized composite electrode material, NF/NiMoO4/NiMoO4 with a nanoball-like NF/NiMoO4 structure on a NiMoO4 surface over a NF substrate, formed a three-dimensional interconnected porous network for high-performance electrodes. The novel NF/NiMoO4/NiMoO4 nanoflowers not only enhanced the large surface area and increased the electrochemical activity, but also provided an enhanced rapid ion diffusion path and reduced the charge transfer resistance of the entire electrode effectively. The NF/NiMoO4/NiMoO4 composite exhibited significantly improved supercapacitor performance in terms of a sustained cycling life, high specific capacitance, rapid charge-discharge capability, high energy density, and good rate capability. Electrochemical analysis of the NF/NiMoO4/NiMoO4 nanoflowers fabricated on the NF substrate revealed ultra-high electrochemical performance with a high specific capacitance of 2121 F g−1 at 12 mA g−1 in a 3 M KOH electrolyte and 98.7% capacitance retention after 3000 cycles at 14 mA g−1. This performance was superior to the NF/NiMoO4 nanoball electrode (1672 F g−1 at 12 mA g−1 and capacitance retention 93.4% cycles). Most importantly, the SC (NF/NiMoO4/NiMoO4) device displayed a maximum energy density of 47.13 W h kg−1, which was significantly higher than that of NF/NiMoO4 (37.1 W h kg−1). Overall, the NF/NiMoO4/NiMoO4 composite is a suitable material for supercapacitor applications.


2020 ◽  
Vol 44 (25) ◽  
pp. 10359-10366
Author(s):  
Dengke Xiong ◽  
Shi-Cheng Wang ◽  
Chen Chen ◽  
Minli Gu ◽  
Fei-Yan Yi

Multiple Prussian-blue analogues/NF composites were successfully fabricated through a one-pot chemical etching and growing process. The target materials NiCoxFe1−x-PBA/NF exhibited excellent electrochemical performance.


2019 ◽  
Vol 48 (28) ◽  
pp. 10652-10660 ◽  
Author(s):  
Tarugu Anitha ◽  
Araveeti Eswar Reddy ◽  
Yedluri Anil Kumar ◽  
Young-Rae Cho ◽  
Hee-Je Kim

A bunch of PbMoO4/CdMoO4 nanocube-like structures exhibit superior specific capacitance and cycling stability to PbMoO4 and CdMoO4 electrodes.


2017 ◽  
Vol 5 (19) ◽  
pp. 9169-9176 ◽  
Author(s):  
Sainan Liu ◽  
Zhenyang Cai ◽  
Jiang Zhou ◽  
Mengnan Zhu ◽  
Anqiang Pan ◽  
...  

Herein, we report the rational design of a simple hydrothermal reaction for the first time to prepare interlaced Sb2O3nanosheets and Sb2S3micro-nanospheres, grown on carbon fiber cloth, for application as flexible electrodes in sodium-ion batteries and sodium-ion capacitors with excellent electrochemical performance.


2020 ◽  
Vol 49 (3) ◽  
pp. 941-941
Author(s):  
Tarugu Anitha ◽  
Araveeti Eswar Reddy ◽  
Yedluri Anil Kumar ◽  
Young-Rae Cho ◽  
Hee-Je Kim

Correction for ‘One-step synthesis and electrochemical performance of a PbMoO4/CdMoO4 composite as an electrode material for high-performance supercapacitor applications’ by Tarugu Anitha et al., Dalton Trans., 2019, 48, 10652–10660.


Author(s):  
Shiying Lin ◽  
Lanlan Mo ◽  
Tao Lyu ◽  
Feijun Wang

Abstract Heteroatom doping is an effective modification to improve electrochemical performance of carbon materials as electrodes in storage devices and multi-doping works better because of synergistic effect. In this report, a N/O/S multi-doped carbon nanospheres (SLS/PANI-700) are prepared from crosslinking hydrogel beads of polyaniline and sodium lignosulfonate. The addition of sodium lignosulfonate significantly improve the electrochemical performance of PANI-based carbon by changing micromorphology, building interconnected network and offering diverse doping. SLS/PANI-700 has ultrahigh specific surface area of 2861 m2 g−1, well-developed hierarchically porous structure, interconnected conducting carbon network and high N and O concentration. Take these advantages, it delivers very high capacitance of 487.7 F g−1 at 1 A g−1, a superior rate retention with capacitance of 373.6 F g−1 at a high current density of 20 A g−1 as electrode material. The assembled symmetric supercapacitor device exhibits a very high energy density of 43.68 Wh kg−1 at 488.98 W kg−1 and keeps 21.18 Wh kg−1 under a high power density of 8664.54 W kg−1. Based on these properties, SLS/PANI-700 possesses a great promising potential as electrode material for advanced supercapacitor.


Author(s):  
Gun Ho Lee ◽  
Byung Jun Park ◽  
Tae Won Nam ◽  
Ye Ji Kim ◽  
Gyu Rac Lee ◽  
...  

Despite the high power density of ultracapacitors, increasing the energy density to level that of conventional battery systems remains a critical challenge. Here, we report excellent electrochemical performance of three-dimensionally...


RSC Advances ◽  
2018 ◽  
Vol 8 (52) ◽  
pp. 29488-29494 ◽  
Author(s):  
Xiaobo Chen ◽  
Jingguo Ding ◽  
Jing Jiang ◽  
Guoce Zhuang ◽  
Zhihai Zhang ◽  
...  

The effect of carbon supports on the electrochemical performance of MoS2 nanosheets for supercapacitor applications was investigated.


2019 ◽  
Vol 7 (35) ◽  
pp. 20208-20222 ◽  
Author(s):  
M. Aftabuzzaman ◽  
Chang Ki Kim ◽  
Tomasz Kowalewski ◽  
Krzysztof Matyjaszewski ◽  
Hwan Kyu Kim

Ru-NPs-embedded self-templated mesoporous carbons were successfully prepared by a facile route. They show excellent electrochemical performance with very high specific gravimetric capacitance, good rate capability, and excellent long-term cycling stability.


Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4870
Author(s):  
Xiao Li ◽  
Jun Li ◽  
Ying Zhang ◽  
Peng Zhao ◽  
Ruyan Lei ◽  
...  

Ni(OH)2 derived from an MOF template was synthesized as an electrode material for supercapacitors. The electrochemical performance of the electrode was adjusted by effectively regulating the morphology of Ni(OH)2. The evolution of electrochemical performance of the electrode with morphology of Ni(OH)2 was highlighted in detail, based on which honeycomb-like Ni(OH)2 was successfully synthesized, and endowed the electrode with outstanding electrochemical performance. For the three-electrode testing system, honeycomb-like Ni(OH)2 exhibited a very high specific capacitance (1865 F·g−1 at 1 A·g−1, 1550 F·g−1 at 5 mV·s−1). Moreover, it also presented an excellent rate capability and cycling stability, due to 59.46 % of the initial value (1 A·g−1) being retained at 10 A·g−1, and 172% of initial value (first circle at 50 mV·s−1) being retained after 20,000 cycles. With respect to the assembled hybrid supercapacitor, honeycomb-like Ni(OH)2 also displayed superior electrochemical performance, with a high energy density (83.9 Wh·kg−1 at a power density of 374.8 W·kg−1). The outstanding electrochemical performance of Ni(OH)2 should be attributed to its unique honeycomb-like structure, with a very high specific surface area, which greatly accelerates the transformation and diffusion of active ions.


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