A facile route to well-dispersed Ru nanoparticles embedded in self-templated mesoporous carbons for high-performance supercapacitors

2019 ◽  
Vol 7 (35) ◽  
pp. 20208-20222 ◽  
Author(s):  
M. Aftabuzzaman ◽  
Chang Ki Kim ◽  
Tomasz Kowalewski ◽  
Krzysztof Matyjaszewski ◽  
Hwan Kyu Kim
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Rate Capability ◽  
Mesoporous Carbons ◽  
Ru Nanoparticles ◽  
Excellent Electrochemical Performance ◽  
Very High ◽  
Good Rate Capability ◽  
Facile Route

Ru-NPs-embedded self-templated mesoporous carbons were successfully prepared by a facile route. They show excellent electrochemical performance with very high specific gravimetric capacitance, good rate capability, and excellent long-term cycling stability.

Preparation of urchin-like NiCo2O4 material and studies of its electrochemical performance for supercapacitors

2019 ◽  
Vol 12 (03) ◽  
pp. 1950026 ◽  
Author(s):  
Lili Wang ◽  
Yanxia Huang ◽  
Xiaoshan Li ◽  
Hang Ma ◽  
Chenghang You ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Hydrothermal Process ◽  
Rate Capability ◽  
Cycling Stability ◽  
A Value ◽  
Excellent Electrochemical Performance ◽  
Good Cycling Stability ◽  
Good Rate Capability

The paper reports a kind of NiCo2O4 material with urchin-like morphology. This material was prepared using a facile strategy of hydrothermal process followed by calcinations, and exhibits an excellent electrochemical performance. For example, it delivers a specific capacitance high up to 1167[Formula: see text]Fg[Formula: see text] at 1[Formula: see text]Ag[Formula: see text] and still retains a value of 1095[Formula: see text]Fg[Formula: see text] at 10[Formula: see text]Ag[Formula: see text], showing a good rate capability; after suffering from 3000 cycles at 10[Formula: see text]A[Formula: see text]g[Formula: see text], the specific capacitance has only a decay of 12%, presenting a good cycling stability.

scholarly journals The Evolution in Electrochemical Performance of Honeycomb-Like Ni(OH)2 Derived from MOF Template with Morphology as a High-Performance Electrode Material for Supercapacitors

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4870
Author(s):  
Xiao Li ◽  
Jun Li ◽  
Ying Zhang ◽  
Peng Zhao ◽  
Ruyan Lei ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Electrode Material ◽  
High Performance ◽  
Rate Capability ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Specific Surface Area ◽  
High Energy Density ◽  
Initial Value ◽  
Very High

Ni(OH)2 derived from an MOF template was synthesized as an electrode material for supercapacitors. The electrochemical performance of the electrode was adjusted by effectively regulating the morphology of Ni(OH)2. The evolution of electrochemical performance of the electrode with morphology of Ni(OH)2 was highlighted in detail, based on which honeycomb-like Ni(OH)2 was successfully synthesized, and endowed the electrode with outstanding electrochemical performance. For the three-electrode testing system, honeycomb-like Ni(OH)2 exhibited a very high specific capacitance (1865 F·g−1 at 1 A·g−1, 1550 F·g−1 at 5 mV·s−1). Moreover, it also presented an excellent rate capability and cycling stability, due to 59.46 % of the initial value (1 A·g−1) being retained at 10 A·g−1, and 172% of initial value (first circle at 50 mV·s−1) being retained after 20,000 cycles. With respect to the assembled hybrid supercapacitor, honeycomb-like Ni(OH)2 also displayed superior electrochemical performance, with a high energy density (83.9 Wh·kg−1 at a power density of 374.8 W·kg−1). The outstanding electrochemical performance of Ni(OH)2 should be attributed to its unique honeycomb-like structure, with a very high specific surface area, which greatly accelerates the transformation and diffusion of active ions.

Interface-engineered hematite nanocones as binder-free electrodes for high-performance lithium-ion batteries

2018 ◽  
Vol 6 (28) ◽  
pp. 13968-13974 ◽  
Author(s):  
Lei Wang ◽  
Kun Liang ◽  
Guanzhi Wang ◽  
Yang Yang
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Specific Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
High Specific Capacity ◽  
One Dimensional ◽  
Binder Free ◽  
Enhanced Electrochemical Performance ◽  
Good Rate Capability

One-dimensional α-Fe2O3 nanocone arrays exhibited an enhanced electrochemical performance with high specific capacity, good rate capability, and excellent cyclability.

Rational design of self-supported Ni3S2 nanoparticles as a battery type electrode material for high-voltage (1.8 V) symmetric supercapacitor applications

CrystEngComm ◽  
2021 ◽  
Author(s):  
Muhammad Sajjad ◽  
Yaqoob Khan
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
High Voltage ◽  
Electrode Material ◽  
High Performance ◽  
Rational Design ◽  
Rate Capability ◽  
Excellent Electrochemical Performance ◽  
Symmetric Supercapacitor ◽  
Supercapacitor Applications

We developed a high performance SSC device with excellent electrochemical performance in terms of specific capacitance, rate capability, energy density and power density which surpasses most of the reports.

scholarly journals Hierarchical Porous RGO/PEDOT/PANI Hybrid for Planar/Linear Supercapacitor with Outstanding Flexibility and Stability

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Fuwei Liu ◽  
Luoyuan Xie ◽  
Li Wang ◽  
Wei Chen ◽  
Wei Wei ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Energy Density ◽  
Structural Design ◽  
High Performance ◽  
Rate Capability ◽  
Cotton Yarn ◽  
Reduced Graphene ◽  
Hierarchical Porous ◽  
Good Rate Capability ◽  
Electrodes For Supercapacitors

AbstractMany hybrid electrodes for supercapacitors (SCs) are a reckless combination without proper structural design that keeps them from fulfilling their potential. Herein, we design a reduced graphene oxide/poly(3,4-ethylenedioxythiophene)/polyaniline (RGO/PEDOT/PANI) hybrid with hierarchical and porous structure for high-performance SCs, where components fully harness their advantages, forming an interconnected and conductive framework with substantial reactive sites.Thus, this hybrid achieves a high capacitance of 535 F g−1 along with good rate capability and cyclability. The planar SC based on this hybrid deliver an energy density of 26.89 Wh kg−1 at a power density of 800 W kg−1. The linear SC developed via modifying a cotton yarn with the hybrid exhibits good flexibility and structural stability, which operates normally after arbitrary deformations. This work provides a beneficial reference for developing SCs.

scholarly journals Sb nanosheet modified separator for Li–S batteries with excellent electrochemical performance

RSC Advances ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 6798-6803
Author(s):  
Linchao Zeng ◽  
Jianhui Zhu ◽  
Minsu Liu ◽  
Peixin Zhang
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Excellent Electrochemical Performance ◽  
First Time ◽  
Modified Separator

Antimony nanosheet modified separator is prepared for high performance Li–S batteries for the first time.

Self-assembly synthesis of nitrogen-doped mesoporous carbons used as high-performance electrode materials in lithium-ion batteries and supercapacitors

2017 ◽  
Vol 41 (21) ◽  
pp. 12901-12909 ◽  
Author(s):  
Chunfeng Shao ◽  
Ziqiang Wang ◽  
Errui Wang ◽  
Shujun Qiu ◽  
Hailiang Chu ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Self Assembly ◽  
High Performance ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Mesoporous Carbons ◽  
Nitrogen Doped ◽  
First Time ◽  
Enhanced Electrochemical Performance

Guanine was, for the first time, used as a nitrogen source during the synthesis of nitrogen-doped porous carbons (NMCs) with enhanced electrochemical performance.

Highly ordered nanoscale phosphomolybdate-grafted polyaniline/metal hybrid layered structures prepared via secondary sputtering phenomenon as high-performance pseudocapacitor electrodes

2021 ◽  
Author(s):  
Eun Seop Yoon ◽  
Bong Gill Choi ◽  
Hwan-Jin Jeon
Keyword(s):  
Electron Transfer ◽  
Aspect Ratio ◽  
Electrochemical Performance ◽  
High Aspect Ratio ◽  
High Performance ◽  
Electrode Materials ◽  
Rate Capability ◽  
High Specific Capacitance ◽  
High Rate ◽  
Large Area

Abstract The development of energy storage electrode materials is important for enhancing the electrochemical performance of supercapacitors. Despite extensive research on improving electrochemical performance with polymer-based materials, electrode materials with micro/nanostructures are needed for fast and efficient ion and electron transfer. In this work, highly ordered phosphomolybdate (PMoO)-grafted polyaniline (PMoO-PAI) deposited onto Au hole-cylinder nanopillar arrays is developed for high-performance pseudocapacitors. The three-dimensional nanostructured arrays are easily fabricated by secondary sputtering lithography, which has recently gained attention and features a high resolution of 10 nm, a high aspect ratio greater than 20, excellent uniformity/accuracy/precision, and compatibility with large area substrates. These 10nm scale Au nanostructures with a high aspect ratio of ~30 on Au substrates facilitate efficient ion and electron transfer. The resultant PMoO-PAI electrode exhibits outstanding electrochemical performance, including a high specific capacitance of 114 mF/cm2, a high-rate capability of 88%, and excellent long-term stability.

Hierarchical coral-like MnCo2O4.5@Co-Ni LDH composites on Ni foam as promising electrodes for high-performance supercapacitor

2021 ◽  
Author(s):  
yajun JI ◽  
Fei Chen ◽  
Shufen Tan ◽  
Fuyong Ren
Keyword(s):  
Electrochemical Performance ◽  
Metal Oxides ◽  
High Performance ◽  
High Capacity ◽  
Rate Capability ◽  
Negative Electrode ◽  
High Energy ◽  
Hybrid Nanostructures ◽  
High Energy Density ◽  
Ni Foam

Abstract Transition metal oxides are generally designed as hybrid nanostructures with high performance for supercapacitors by enjoying the advantages of various electroactive materials. In this paper, a convenient and efficient route had been proposed to prepare hierarchical coral-like MnCo2O4.5@Co-Ni LDH composites on Ni foam, in which MnCo2O4.5 nanowires were enlaced with ultrathin Co-Ni layered double hydroxides nanosheets to achieve high capacity electrodes for supercapacitors. Due to the synergistic effect of shell Co-Ni LDH and core MnCo2O4.5, the outstanding electrochemical performance in three-electrode configuration was triggered (high area capacitance of 5.08 F/cm2 at 3 mA/cm2 and excellent rate capability of maintaining 61.69 % at 20 mA/cm2), which is superior to those of MnCo2O4.5, Co-Ni LDH and other metal oxides based composites reported. Meanwhile, the as-prepared hierarchical MnCo2O4.5@Co-Ni LDH electrode delivered improved electrical conductivity than that of pristine MnCo2O4.5. Furthermore, the as-constructed asymmetric supercapacitor using MnCo2O4.5@Co-Ni LDH as positive and activated carbon as negative electrode presented a rather high energy density of 220 μWh/cm2 at 2400 μW/cm2 and extraordinary cycling durability with the 100.0 % capacitance retention over 8000 cycles at 20 mA/cm2, demonstrating the best electrochemical performance compared to other asymmetric supercapacitors using metal oxides based composites as positive electrode material. It can be expected that the obtained MnCo2O4.5@Co-Ni LDH could be used as the high performance and cost-effective electrode in supercapacitors.

A high performance ceria-based solid oxide fuel cell operating on underground coal gasification gas

RSC Advances ◽  
2015 ◽  
Vol 5 (106) ◽  
pp. 87477-87483 ◽  
Author(s):  
Jie Xiong ◽  
Chengran Jiao ◽  
Minfang Han ◽  
Wentao Yi ◽  
Jie Ma ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Electrochemical Performance ◽  
Solid Oxide Fuel Cell ◽  
High Performance ◽  
Coal Gasification ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Underground Coal Gasification ◽  
Long Term Stability

A NiO-GDC‖GDC‖Ba0.9Co0.7Fe0.2Nb0.1O3−δ cell fed with UCG gas demonstrated exceptional electrochemical performance and desirable long term stability.

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