Preyssler-type polyoxometalate-based crystalline materials for the electrochemical detection of H2O2

CrystEngComm ◽  
2021 ◽  
Author(s):  
HaoTian Zhu ◽  
WenSi Tang ◽  
YuanYuan Ma ◽  
YongHui Wang ◽  
HuaQiao Tan ◽  
...  

Four Preyssler-type polyoxometalate-based organic–inorganic hybrid materials were synthesized as non-enzymatic H2O2 electrochemical sensors, with high sensitivity and low detection limit.

2013 ◽  
Vol 823 ◽  
pp. 291-295 ◽  
Author(s):  
Shou Chen Chai ◽  
Peng Yang ◽  
Cheng Jia Yang ◽  
Chun Li Cai ◽  
Na Yu

In the space restricted airtight environment that people lives in, detecting harmful gas by miniature gas chromatography is the practical requirement at present, however, PIDs performance is key factor that restrict the application of miniature gas chromatography, the redesign of the detectors gas route in this paper aiming at improve detectors stability observably, and schemed out miniature PID with high sensitivity, low detection limit and fast response. The result of the experiment shows that the detection limit is 0.04ppm, the sensitivity is 101mv/ppm,the stability is 0.04×10-6/24h,meeting the project requirement. Keywords: photoionization detector; ionization chamber; sensitivity; detection limit;


Toxins ◽  
2019 ◽  
Vol 12 (1) ◽  
pp. 1 ◽  
Author(s):  
Wei Ye ◽  
Taomei Liu ◽  
Weimin Zhang ◽  
Muzi Zhu ◽  
Zhaoming Liu ◽  
...  

Marine toxins cause great harm to human health through seafood, therefore, it is urgent to exploit new marine toxins detection methods with the merits of high sensitivity and specificity, low detection limit, convenience, and high efficiency. Aptasensors have emerged to replace classical detection methods for marine toxins detection. The rapid development of molecular biological approaches, sequencing technology, material science, electronics and chemical science boost the preparation and application of aptasensors. Taken together, the aptamer-based biosensors would be the best candidate for detection of the marine toxins with the merits of high sensitivity and specificity, convenience, time-saving, relatively low cost, extremely low detection limit, and high throughput, which have reduced the detection limit of marine toxins from nM to fM. This article reviews the detection of marine toxins by aptamer-based biosensors, as well as the selection approach for the systematic evolution of ligands by exponential enrichment (SELEX), the aptamer sequences. Moreover, the newest aptasensors and the future prospective are also discussed, which would provide thereotical basis for the future development of marine toxins detection by aptasensors.


Materials ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2577 ◽  
Author(s):  
Yuanying Liang ◽  
Ting Guo ◽  
Lei Zhou ◽  
Andreas Offenhäusser ◽  
Dirk Mayer

The detection of chemical messenger molecules, such as neurotransmitters in nervous systems, demands high sensitivity to measure small variations, selectivity to eliminate interferences from analogues, and compliant devices to be minimally invasive to soft tissue. Here, an organic electrochemical transistor (OECT) embedded in a flexible polyimide substrate is utilized as transducer to realize a highly sensitive dopamine aptasensor. A split aptamer is tethered to a gold gate electrode and the analyte binding can be detected optionally either via an amperometric or a potentiometric transducer principle. The amperometric sensor can detect dopamine with a limit of detection of 1 μM, while the novel flexible OECT-based biosensor exhibits an ultralow detection limit down to the concentration of 0.5 fM, which is lower than all previously reported electrochemical sensors for dopamine detection. The low detection limit can be attributed to the intrinsic amplification properties of OECTs. Furthermore, a significant response to dopamine inputs among interfering analogues hallmarks the selective detection capabilities of this sensor. The high sensitivity and selectivity, as well as the flexible properties of the OECT-based aptasensor, are promising features for their integration in neuronal probes for the in vitro or in vivo detection of neurochemical signals.


RSC Advances ◽  
2017 ◽  
Vol 7 (22) ◽  
pp. 13438-13443 ◽  
Author(s):  
Jiao Liu ◽  
Hong-Wei Li ◽  
Yuqing Wu

The ultrabright AuNCs@AMP are used as fluorescence probe to detect lactate dehydrogenase (LDH) with high sensitivity and selectivity, showing an extremely low detection limit of 0.2 nM (26 pg μL−1, 0.8 U L−1).


2021 ◽  
Author(s):  
Siddesh Umapathi ◽  
Harish Singh ◽  
Jahangir Masud ◽  
Manashi Nath

CuSe nanostructures exhibit high-efficiency for glucose detection with high sensitivity (19.419 mA mM−1 cm−2) and selectivity at low applied potential (0.15 V vs. Ag|AgCl), low detection limit (0.196 μM) and linear detection range (100 nM to 40 μM).


MRS Bulletin ◽  
2010 ◽  
Vol 35 (2) ◽  
pp. 116-121 ◽  
Author(s):  
Nico A.J.M. Sommerdijk ◽  
Helmut Cölfen

AbstractIn biology, organic-inorganic hybrid materials are used for several purposes, in particular, for protection and mechanical support. These materials are generally optimized for their function through precise control over the structure, size, shape, and assembly of the component parts and can be superior to many synthetic materials. The shapes and forms of minerals encountered in nature strongly contrast with those that are generally formed in a synthetic environment. According to current understanding, this is achieved through different modes of control: their shape can be controlled by restricting their growth to a confined space or by influencing their preferred direction of growth; in addition, for crystalline materials, polymorph selection and oriented nucleation are achieved through specific interactions between a template or additive and the developing nucleus. Also, controlled arrangement of nanoparticles into superstructures can lead to a complex structure. The understanding and, ultimately, the mimicking of these processes will provide new synthetic routes to specialized organic-inorganic hybrid materials. On the other hand, transformation of existing complex hierarchical natural structures such as wood or diatom frustules into other materials using shape-preserving chemistry is another approach toward minerals with complex biomimetic structure. The theme topic in this issue will focus on recent biomimetic and bioinspired approaches used to achieve control over the shape and organization of mineral and organic-inorganic hybrid materials. The different contributions will also highlight the advantages of these methods for advanced materials synthesis, and possible applications will be discussed.


2001 ◽  
Vol 76 (1-3) ◽  
pp. 519-526 ◽  
Author(s):  
A. Poghossian ◽  
M.J. Schöning ◽  
P. Schroth ◽  
A. Simonis ◽  
H. Lüth

RSC Advances ◽  
2015 ◽  
Vol 5 (112) ◽  
pp. 92564-92572 ◽  
Author(s):  
Radhakanta Ghosh ◽  
Sandip Das ◽  
Dhruba P. Chatterjee ◽  
Arun K. Nandi

A new fluorometric cyanide sensor using cationic polythiophene exhibits high sensitivity, selectivity with a low detection limit (4.4 ppb) in water.


Sign in / Sign up

Export Citation Format

Share Document