Solid-state construction of zig-zag periphery via intramolecular C-H insertion induced by alumina-mediated C-F activation

2021 ◽  
Author(s):  
Mikhail Feofanov ◽  
Andreas Förtsch ◽  
Konstantin Amsharov ◽  
Vladimir Akhmetov
Keyword(s):  
Solid State ◽  
Bond Activation ◽  
State Construction ◽  
Developing Method ◽  
Carbon Based

Caryl-F bond activation has become an important and quickly developing method for construction of carbon-based materials. We report that alumina-mediated C-F bond activation (AmCFA) enables construction of PAHs with zig-zag...

scholarly journals A kinetico-mechanistic study on the C–H bond activation of primary benzylamines; cooperative and solid-state cyclopalladation on dimeric complexes

2014 ◽  
Vol 43 (36) ◽  
pp. 13525 ◽  
Author(s):  
Helena Font ◽  
Mercè Font-Bardia ◽  
Kerman Gómez ◽  
Gabriel González ◽  
Jaume Granell ◽  
...  
Keyword(s):  
Solid State ◽  
Bond Activation ◽  
Mechanistic Study ◽  
Dimeric Complexes

scholarly journals Carbon‐Based Quantum Dots: Carbon‐Based Quantum Dots with Solid‐State Photoluminescent: Mechanism, Implementation, and Application (Small 48/2020)

Small ◽  
2020 ◽  
Vol 16 (48) ◽  
pp. 2070262
Author(s):  
Anli Xu ◽  
Gang Wang ◽  
Yongqiang Li ◽  
Hui Dong ◽  
Siwei Yang ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Solid State ◽  
Carbon Based

scholarly journals Solid-state NMR Reveals the Carbon-based Molecular Architecture ofCryptococcus neoformansFungal Eumelanins in the Cell Wall

2015 ◽  
Vol 290 (22) ◽  
pp. 13779-13790 ◽  
Author(s):  
Subhasish Chatterjee ◽  
Rafael Prados-Rosales ◽  
Boris Itin ◽  
Arturo Casadevall ◽  
Ruth E. Stark
Keyword(s):  
Cell Wall ◽  
Solid State ◽  
Solid State Nmr ◽  
Molecular Architecture ◽  
Carbon Based

scholarly journals Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

2016 ◽  
Vol 52 (88) ◽  
pp. 12960-12963 ◽  
Author(s):  
Andrea Monas ◽  
Krunoslav Užarević ◽  
Ivan Halasz ◽  
Marina Juribašić Kulcsár ◽  
Manda Ćurić
Keyword(s):  
Methyl Orange ◽  
Solid State ◽  
Room Temperature ◽  
Bond Activation ◽  
Aqueous Media ◽  
Accelerated Aging ◽  
Water Soluble ◽  
Clean Synthesis

Room-temperature accelerated aging in the solid state has been applied for quantitative azobenzene C–H bond activation by Pd(OAc)2. Water-soluble dicyclopalladated methyl orange is a selective chromogenic biothiol sensor at physiologically-relevant micromolar concentrations in aqueous media.

Improved Solid-State Dye Solar Cells with Polypyrrole using a Carbon-Based Counter Electrode

2001 ◽  
Vol 30 (10) ◽  
pp. 1054-1055 ◽  
Author(s):  
Takayuki Kitamura ◽  
Masato Maitani ◽  
Mizuho Matsuda ◽  
Yuji Wada ◽  
Shozo Yanagida
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Counter Electrode ◽  
Dye Solar Cells ◽  
Carbon Based

scholarly journals Cyclic C-F-Metal Containig Species. Solid State and Computational Examples

2017 ◽  
Vol 57 (2) ◽  
Author(s):  
Maribel Arroyo Carranza ◽  
Hugo Torrens Miquel
Keyword(s):  
Free Radicals ◽  
Solid State ◽  
Transition Metal ◽  
Experimental Evidence ◽  
Bond Activation ◽  
Theoretical Work ◽  
Activation Process

<p>This article examines the results of research published between 2000 and 2012, which found experimental evidence of cyclic species containing the fragment carbon-fluorine-transition metal. 25 Examples (numbered throughout this paper) with 20 different metals and a wide variety of chemical environments have been gathered. A similar analysis brings together almost 40 transitional states and intermediates resulting from theoretical work studying the transition metal mediated carbon-fluorine bond activation. Among other aspects, this review is useful to recognize the specific characteristics which determine whether the C-F activation process is carried out through a concerted process, a mechanism assisted by auxiliary ligands or by free radicals.</p>

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