Electrochemical Hydrogen Formation Catalysed by a Pd8 String

2021 ◽  
Author(s):  
Tomoaki Tanase ◽  
Kanako Nakamae ◽  
Haruka Miyano ◽  
Yoshimi Fujisawa ◽  
Yasuyuki Ura ◽  
...  
Keyword(s):  

The linear Pd8 complex supported by tetraphosphines reacted with HBF4 to give an unprecedented linear tetrapalladium complex with a terminal hydride, which promoted electrocatalytic hydrogen formation from HBF4 in acetonitrile....

1970 ◽  
Vol 48 (11) ◽  
pp. 1782-1785 ◽  
Author(s):  
P. R. McLean ◽  
D. J. McKenney

Rates of formation of ethylene, hydrogen, and methane have been measured at 630 °C for the thermal decomposition of ethane at pressures between 100 and 620 Torr, with various pressures (approximately 1 to 100 Torr) of added hydrogen sulfide. The effect of the H2S was to increase the rate of methane formation and to decrease the rate of ethylene and hydrogen formation. Rates of formation of all three of these gases decreased with increasing hydrogen sulfide pressures. The quantitative data obtained and the partial product analysis indicate that a complex mechanism is operative. Possible qualitative explanations for the observations are discussed.


2010 ◽  
Vol 726 (1) ◽  
pp. 55 ◽  
Author(s):  
Matthew J. Turk ◽  
Paul Clark ◽  
S. C. O. Glover ◽  
T. H. Greif ◽  
Tom Abel ◽  
...  

2011 ◽  
Vol 100 (3) ◽  
pp. 488a
Author(s):  
Anna Poladyan ◽  
Anna Poghosyan ◽  
Karen Trchounian ◽  
Armen Trchounian

1997 ◽  
Vol 78 (14) ◽  
pp. 2728-2731 ◽  
Author(s):  
J. P. Merrison ◽  
H. Bluhme ◽  
J. Chevallier ◽  
B. I. Deutch ◽  
P. Hvelplund ◽  
...  

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