Electrochemiluminescence aptasensor for diethylstilbestrol assay based on resonance energy transfer between Ag3PO4-Cu-MOF(Ⅱ) and silver nanoparticles

The Analyst ◽  
2021 ◽  
Author(s):  
Chang Su ◽  
Qingyuan Song ◽  
Ding Jiang ◽  
Chunping Dong ◽  
Xueling Shan ◽  
...  

In this work, a novel electrochemiluminescence (ECL) aptasensor based on resonance energy transfer (RET) effect between Ag3PO4-Cu-MOF (Ⅱ) and silver nanoparticles (Ag NPs) was proposed. The ECL emission spectra of...

2016 ◽  
Vol 16 (4) ◽  
pp. 3646-3652
Author(s):  
Ailing Yang ◽  
Ning Wang ◽  
Yujin Wang ◽  
Shunpin Li ◽  
Lele Wang ◽  
...  

Silver nanoparticles (NPs) with diameters less than 25 nm, and 5, 10, 15, 20-tetrakis(4-carboxy-phenyl) porphyrin potassium salt (K4TCPPS) was synthesized. By adding silver colloids into the K4TCPPS solutions, the fluorescence concentration quenching of the K4TCPPS solutions was improved between 1×10−6–5×10−4 M, depending on the size of the Ag NPs, the concentration of the K4TCPPS and the excitation wavelength. Under excitation wavelengths of 360 and 414 nm, the enhancement was in the range of 0.34–22.8, and 0.71–82.46, respectively. The enhancement increased with decreasing size of the Ag NPs. At the two highest enhancements, the concentrations of the K4TCPPS solutions were 1×10−4 and 1×10−5 M respectively, and the size of the Ag NPs was about 5 nm. The main reasons for the fluorescence enhancing effect are due to fluorescence resonance energy transfer (FRET) between K4TCPPS molecules and Ag NPs, and decreased collision quenching between free K4TCPPS molecules, and free K4TCPPS molecules with Ag NPs. Our results showed that Ag NPs with sizes of about 5 nm can effectively improve the fluorescence concentration quenching of K4TCPPS solutions. This result also suggests that it is possible to use noble metal NPs to improve fluorescence concentration quenching.


RSC Advances ◽  
2014 ◽  
Vol 4 (54) ◽  
pp. 28471-28480 ◽  
Author(s):  
Atiya N. Jordan ◽  
Noureen Siraj ◽  
Susmita Das ◽  
Isiah M. Warner

Mixtures of GUMBOS were used to form binary nanomaterials with tunable emission spectra due to Förster resonance energy transfer (FRET).


2019 ◽  
Vol 43 (3) ◽  
pp. 1424-1430 ◽  
Author(s):  
Jun-Tao Cao ◽  
Wen-Sheng Zhang ◽  
Hui Wang ◽  
Shu-Hui Ma ◽  
Yan-Ming Liu

A fluorescence immunosensor for PSA detection was developed based on the FRET between Si/NS-CDs and Au@Ag NPs.


NANO ◽  
2014 ◽  
Vol 09 (03) ◽  
pp. 1450030
Author(s):  
LIN XU ◽  
HAO CHENG ◽  
CHUANXI WANG ◽  
QUAN LIN

The heterostructure EuSe / Ag nanoparticles (NPs) were prepared through one-step colloid chemical method. Blue fluorescent EuSe NPs were prepared by amine reducing method with oleylamine (OLA) as surface stabilizer. The colloid microemulsion was formed through the mixture of AgNO 3 aqueous solution and the EuSe n-Hexane solution. On the interface, Ag + ions could be reduced to Ag NPs by OLA. Finally heterogeneous EuSe / Ag NPs were obtained. The structure and properties of EuSe NPs and EuSe / Ag NPs were characterized by photoluminescence (PL), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The results showed that the luminescence resonance energy transfer (LRET) occurred on the interface of EuSe NPs and Ag NPs. Also it demonstrated that the linear enhanced LRET effect happened with increasing the concentration of Ag +. All these properties make our heterostructural EuSe / Ag NPs to have interesting potential applications for ions detection and biosensors.


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