Plasmon switching of gold nanoparticles through thermo-responsive terminal breathing of surface-grafted DNA in hydrated ionic liquid

The Analyst ◽  
2021 ◽  
Author(s):  
Lu Cheng ◽  
Luyang Wang ◽  
zhiyu He ◽  
Xun Sun ◽  
Yujin Li ◽  
...  

Self-assembly performed in ionic liquids (ILs) as a unique solvent promises distinct functions and applications in sensors, therapeutics, and optoelectronic devices, due to the rich interactions between nanoparticle building blocks...

2019 ◽  
Vol 21 (13) ◽  
pp. 6810-6827 ◽  
Author(s):  
Dilek Yalcin ◽  
Calum J. Drummond ◽  
Tamar L. Greaves

High throughput methods were used to investigate ionic liquid containing solutions to provide systematic data of a broad compositional space. We have principally focused on the surface tension, apparent pH and liquid nanostructure to identify potential self-assembly and protein stabilizing ability of solvent systems.


Soft Matter ◽  
2020 ◽  
Vol 16 (41) ◽  
pp. 9456-9470
Author(s):  
Dilek Yalcin ◽  
Calum J. Drummond ◽  
Tamar L. Greaves

Protic ionic liquids (PILs) are the largest and most tailorable known class of non-aqueous solvents which possess the ability to support amphiphile self-assembly.


RSC Advances ◽  
2015 ◽  
Vol 5 (128) ◽  
pp. 105800-105809 ◽  
Author(s):  
Sampa Sarkar ◽  
Kshudiram Mantri ◽  
Dinesh Kumar ◽  
Suresh K. Bhargava ◽  
Sarvesh K. Soni

Self-assembly of hydrophobic lipase enzyme in hydrophobic and hydrophilic ionic liquids and a correlation in structure–function and activity.


2007 ◽  
Vol 79 (11) ◽  
pp. 1869-1877 ◽  
Author(s):  
Anthony E. Rosamilia ◽  
Christopher R. Strauss ◽  
Janet L. Scott

Adducts of dimethylamine and carbon dioxide form a "distillable ionic liquid" (DIMCARB) that may used as both a reaction medium and catalyst in the direct, atom-economical synthesis of useful synthetic building blocks, such as mono-condensed α,β-unsaturated ketones. The utilization of such building blocks in the synthesis of two new classes of versatile macrocycles, by a sequence of condensation reactions (H2O by-product), is described. Investigation into the mechanism of action of DIMCARB catalysis and observation of an aniline impurity arising from a competing reaction sequence led to development of a new multicomponent reaction for the direct preparation of 2- or 4-substituted anilines. Some of the macrocycles and anilines are, respectively, supramolecular host compounds and ligands for the preparation of metal complexes.


Langmuir ◽  
2008 ◽  
Vol 24 (15) ◽  
pp. 7785-7792 ◽  
Author(s):  
Om P. Khatri ◽  
Kosaku Adachi ◽  
Kuniaki Murase ◽  
Ken-ichi Okazaki ◽  
Tsukasa Torimoto ◽  
...  

2017 ◽  
Vol 41 (21) ◽  
pp. 12989-12995 ◽  
Author(s):  
Sachin Thawarkar ◽  
Balu Thombare ◽  
Nageshwar D. Khupse

In this paper, we have demonstrated the facile synthesis of stable gold nanoparticles (AuNPs) using imidazolium ionic liquids (ImILs) as a stabilizer as well as a surfactant and their surface plasmon resonance (SPR) in different molecular solvents with varying dielectric properties.


RSC Advances ◽  
2015 ◽  
Vol 5 (80) ◽  
pp. 65583-65590 ◽  
Author(s):  
Huiyong Wang ◽  
Bo Tan ◽  
Hucheng Zhang ◽  
Jianji Wang

The pH responsive fluids consisting of single-chain ionic liquid surfactants [Cnmim]Br (n = 12, 14) and hydrotropes can reversibly transform from spherical micelles to vesicles then to spherical micelles again with the change of the solution pH value.


2016 ◽  
Vol 10 (2) ◽  
pp. 178-186 ◽  
Author(s):  
Junbo Li ◽  
Jianlong Zhao ◽  
Wenlan Wu ◽  
Ju Liang ◽  
Jinwu Guo ◽  
...  

2016 ◽  
Vol 7 (9) ◽  
pp. 6232-6237 ◽  
Author(s):  
S. Paterson ◽  
S. A. Thompson ◽  
J. Gracie ◽  
A. W. Wark ◽  
R. de la Rica

A new method is introduced for self-assembling citrate-capped gold nanoparticles into supraparticles with crystallographically aligned building blocks.


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