AuCl4−-responsive self-assembly of ionic liquid block copolymers for obtaining composite gold nanoparticles and polymeric micelles with controlled morphologies

2014 ◽  
Vol 38 (6) ◽  
pp. 2508 ◽  
Author(s):  
Junbo Li ◽  
Ju Liang ◽  
Wenlan Wu ◽  
Shijie Zhang ◽  
Ke Zhang ◽  
...  
2016 ◽  
Vol 10 (2) ◽  
pp. 178-186 ◽  
Author(s):  
Junbo Li ◽  
Jianlong Zhao ◽  
Wenlan Wu ◽  
Ju Liang ◽  
Jinwu Guo ◽  
...  

Nanoscale ◽  
2017 ◽  
Vol 9 (39) ◽  
pp. 15056-15061 ◽  
Author(s):  
Yun He ◽  
Yan Zhang ◽  
Nan Yan ◽  
Yutian Zhu ◽  
Wei Jiang ◽  
...  

The unique sieve-like particles with lattice arrayed switchable channels were created via the confined self-assembly of P4VP-b-PS-b-P4VP triblock copolymers within the emulsion droplets.


Molecules ◽  
2019 ◽  
Vol 24 (9) ◽  
pp. 1772 ◽  
Author(s):  
Maria de los Angeles Cortes ◽  
Raquel de la Campa ◽  
Maria Luisa Valenzuela ◽  
Carlos Díaz ◽  
Gabino A. Carriedo ◽  
...  

During the last number of years a variety of crystallization-driven self-assembly (CDSA) processes based on semicrystalline block copolymers have been developed to prepare a number of different nanomorphologies in solution (micelles). We herein present a convenient synthetic methodology combining: (i) The anionic polymerization of 2-vinylpyridine initiated by organolithium functionalized phosphane initiators; (ii) the cationic polymerization of iminophosphoranes initiated by –PR2Cl2; and (iii) a macromolecular nucleophilic substitution step, to prepare the novel block copolymers poly(bistrifluoroethoxy phosphazene)-b-poly(2-vinylpyridine) (PTFEP-b-P2VP), having semicrystalline PTFEP core forming blocks. The self-assembly of these materials in mixtures of THF (tetrahydrofuran) and 2-propanol (selective solvent to P2VP), lead to a variety of cylindrical micelles of different lengths depending on the amount of 2-propanol added. We demonstrated that the crystallization of the PTFEP at the core of the micelles is the main factor controlling the self-assembly processes. The presence of pyridinyl moieties at the corona of the micelles was exploited to stabilize gold nanoparticles (AuNPs).


Langmuir ◽  
2008 ◽  
Vol 24 (15) ◽  
pp. 7785-7792 ◽  
Author(s):  
Om P. Khatri ◽  
Kosaku Adachi ◽  
Kuniaki Murase ◽  
Ken-ichi Okazaki ◽  
Tsukasa Torimoto ◽  
...  

2012 ◽  
Vol 44 (6) ◽  
pp. 550-560 ◽  
Author(s):  
Hideharu Mori ◽  
Yuki Ebina ◽  
Riina Kambara ◽  
Kazuhiro Nakabayashi

2016 ◽  
Vol 37 (14) ◽  
pp. 1181-1187 ◽  
Author(s):  
Daniela Cordella ◽  
Antoine Debuigne ◽  
Christine Jérôme ◽  
Zdravko Kochovski ◽  
Daniel Taton ◽  
...  

2019 ◽  
Vol 10 (34) ◽  
pp. 4637-4642 ◽  
Author(s):  
Anna P. Constantinou ◽  
Uriel Marie-Sainte ◽  
Lihui Peng ◽  
Dean R. Carroll ◽  
Catriona M. McGilvery ◽  
...  

Gold nanoparticles (AuNPs) fabricated via the self-assembly of block copolymers of various architectures.


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