Stable Deep Blue Emission with Unity Quantum Yield in Organic-Inorganic Halide Perovskite 2D Nanosheets Doped with Cerium and Terbium at High Concentrations

Author(s):  
Sumaiya Parveen ◽  
Ponnappa Kechanda Prasanna ◽  
Sudip Chakraborty ◽  
Pravat K. Giri

Despite recent efforts, achieving stable deep blue emission with near unity quantum yield from lead-free perovskite has remained a great challenge. Herein, we have developed a novel strategy to achieve...

ACS Nano ◽  
2017 ◽  
Vol 11 (9) ◽  
pp. 9294-9302 ◽  
Author(s):  
Jian Zhang ◽  
Ying Yang ◽  
Hui Deng ◽  
Umar Farooq ◽  
Xiaokun Yang ◽  
...  

2020 ◽  
Vol 5 (3) ◽  
pp. 580-585 ◽  
Author(s):  
Yalong Shen ◽  
Jun Yin ◽  
Bo Cai ◽  
Ziming Wang ◽  
Yuhang Dong ◽  
...  

Lead-free Bi-based perovskite FA3Bi2X9 (X = Cl, Br, and I) quantum dots (QDs) are synthesized for the first time at room temperature. The ligand-passivated FA3Bi2Br9 QDs exhibit blue emission at 437 nm with photoluminescence quantum yield (PLQY) up to 52%.


2019 ◽  
Vol 33 (3) ◽  
pp. e4731 ◽  
Author(s):  
Liyang Wang ◽  
Yanxue Guo ◽  
Baoyi Yu ◽  
Wei Zhang ◽  
Tengzhou Li ◽  
...  

Author(s):  
Xinzhen Ji ◽  
Zhuangzhuang Ma ◽  
Xu Chen ◽  
Di Wu ◽  
Yongtao Tian ◽  
...  

Abstract Recently, non-toxic alternatives to lead-halide perovskites have been greatly sought after in optoelectronics applications. Deep-blue luminescent material is mainly required for fabricating white light source and expanding the color gamut of full-color displays. However, the synthesis of high-performance lead-free perovskite films with efficient blue emission is still a critical challenge currently, limiting their further practical applications. Here, a novel strategy is reported to prepare non-toxic and deep-blue-emitting K2CuBr3 nanocrystalline films by introducing polymer poly(methyl methacrylate) (PMMA) additives into the anti-solvent. It is found that the PMMA additives could effectively reduce the grain size and improve the crystallinity of K2CuBr3 films, resulting in an enhanced radiative recombination by defect passivation and confinement of excitons in the nanograins. As a result, the PMMA-treated K2CuBr3 films achieve a bright deep-blue light with color coordinates at (0.155, 0.042), and the photoluminescence quantum yield obtained is about 3.3 times that of the pristine sample. Moreover, the treated K2CuBr3 films exhibit a substantially enhanced stability under harsh environmental conditions, maintaining >70% of their initial performances in high humidity environment (50‒70% humidity, 190 h) or under uninterrupted ultraviolet light radiation (254 nm, 3.4 mW/cm2, 150 h). These findings pave a promising strategy for achieving efficient and stable deep-blue metal halide films, showing their potential applications in optoelectronic devices.


2021 ◽  
Vol 143 (37) ◽  
pp. 15176-15184
Author(s):  
Zhiwei Ma ◽  
Qian Li ◽  
Jiajun Luo ◽  
Shunran Li ◽  
Laizhi Sui ◽  
...  

Author(s):  
Xiang Li ◽  
Xinyuan Du ◽  
Peng Zhang ◽  
Yunqiu Hua ◽  
Lin Liu ◽  
...  

CrystEngComm ◽  
2021 ◽  
Author(s):  
Chunlong Li ◽  
Jie Li ◽  
Zhengping Li ◽  
Huayong Zhang ◽  
Yangyang Dang ◽  
...  

Nanostructured halide perovskites have highly yielded record LEDs due to their higher versatility in the local management of charge carriers, which has enabled photoluminescence quantum yields (PLQYs) close to 100%....


2016 ◽  
Vol 55 (48) ◽  
pp. 15012-15016 ◽  
Author(s):  
Meiying Leng ◽  
Zhengwu Chen ◽  
Ying Yang ◽  
Zha Li ◽  
Kai Zeng ◽  
...  

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