Simple cuprous iodide complex-based crystals with deep blue emission and high photoluminescence quantum yield up to 100%

2019 ◽  
Vol 33 (3) ◽  
pp. e4731 ◽  
Author(s):  
Liyang Wang ◽  
Yanxue Guo ◽  
Baoyi Yu ◽  
Wei Zhang ◽  
Tengzhou Li ◽  
...  
Molecules ◽  
2021 ◽  
Vol 26 (18) ◽  
pp. 5568
Author(s):  
Jie Li ◽  
Heqi Gong ◽  
Jincheng Zhang ◽  
Hui Liu ◽  
Li Tao ◽  
...  

The realization of a deep-blue-emitting exciplex system is a herculean task in the field of organic light-emitting diodes (OLEDs) on account of a large red-shifted and broadened exciplex emission spectrum in comparison to those of the corresponding single compounds. Herein, 2,5,8-tris(di(4-fluorophenyl)amine)-1,3,4,6,7,9,9b-heptaazaphenalene (HAP-3FDPA) was designed as an electron acceptor by integrating three bis(4-fluorophenyl)amine groups into a heptazine core, while 1,3-di(9H-carbazol-9-yl)benzene (mCP) possessing two electron-donating carbazole moieties was chosen as the electron donor. Excitingly, the exciplex system of 8 wt% HAP-3FDPA:mCP exhibited deep-blue emission and a high photoluminescence quantum yield of 53.2%. More importantly, an OLED containing this exciplex system as an emitting layer showed deep-blue emission with Commission Internationale de l’Eclairage coordinates of (0.16, 0.12), a peak luminance of 15,148 cd m−2, and a rather high maximum external quantum efficiency of 10.2% along with a low roll-off. This study not only reports an efficient exciplex-based deep-blue emitter but also presents a feasible pathway to construct highly efficient deep-blue OLEDs based on exciplex systems.


2020 ◽  
Vol 5 (3) ◽  
pp. 580-585 ◽  
Author(s):  
Yalong Shen ◽  
Jun Yin ◽  
Bo Cai ◽  
Ziming Wang ◽  
Yuhang Dong ◽  
...  

Lead-free Bi-based perovskite FA3Bi2X9 (X = Cl, Br, and I) quantum dots (QDs) are synthesized for the first time at room temperature. The ligand-passivated FA3Bi2Br9 QDs exhibit blue emission at 437 nm with photoluminescence quantum yield (PLQY) up to 52%.


Author(s):  
Sumaiya Parveen ◽  
Ponnappa Kechanda Prasanna ◽  
Sudip Chakraborty ◽  
Pravat K. Giri

Despite recent efforts, achieving stable deep blue emission with near unity quantum yield from lead-free perovskite has remained a great challenge. Herein, we have developed a novel strategy to achieve...


2018 ◽  
Vol 47 (47) ◽  
pp. 17067-17076 ◽  
Author(s):  
Alexander Schinabeck ◽  
Nicholas Rau ◽  
Marius Klein ◽  
Jörg Sundermeyer ◽  
Hartmut Yersin

Triplet and singlet harvesting in combination with enhancing the emitter rigidity leads to a landmark value of the photoluminescence quantum yield for dissolved Cu(i) complexes.


2020 ◽  
Vol 142 (13) ◽  
pp. 6332-6339 ◽  
Author(s):  
Dan Liu ◽  
Jianbo De ◽  
Haikuo Gao ◽  
Suqian Ma ◽  
Qi Ou ◽  
...  

2021 ◽  
Vol 9 (5) ◽  
pp. 1555-1566
Author(s):  
Andrés F. Gualdrón-Reyes ◽  
David F. Macias-Pinilla ◽  
Sofia Masi ◽  
Carlos Echeverría-Arrondo ◽  
Said Agouram ◽  
...  

The Pb substitution in quantum dots (PQDs) with lesser toxic metals has been widely searched to be environmentally friendly, and be of comparable or improved performance compared to the lead-perovskite.


2021 ◽  
Vol 12 (5) ◽  
pp. 1426-1431
Author(s):  
Swarnali Ghosh ◽  
Saptarshi Mandal ◽  
Soumen Mukherjee ◽  
Chayan K. De ◽  
Tridib Samanta ◽  
...  

Author(s):  
Lin Yang ◽  
Bowen Fu ◽  
Xu Li ◽  
Hao Chen ◽  
Lili Li

All inorganic perovskite quantum dots (QDs) have received great attention owing to their excellent performance in optoelectronic applications. However, they often suffer from the defect-related photoluminescence (PL) quenching and phase...


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