Efficient aggregation-induced delayed fluorescent materials based on bipolar carrier transport materials for the fabrication of high-performance nondoped OLEDs with very small efficiency roll-off

2020 ◽  
Vol 8 (28) ◽  
pp. 9549-9557 ◽  
Author(s):  
Yan Fu ◽  
Huijun Liu ◽  
Xiangyu Zhu ◽  
Jiajie Zeng ◽  
Zujin Zhao ◽  
...  

The integration of bipolar carrier transport materials with an aggregation-induced delayed fluorescence unit generates robust luminescent materials, which lead to efficient nondoped OLEDs with high efficiency stability.

2021 ◽  
Vol 12 (11) ◽  
pp. 1692-1699
Author(s):  
Ji Hye Lee ◽  
Jinhyo Hwang ◽  
Chai Won Kim ◽  
Amit Kumar Harit ◽  
Han Young Woo ◽  
...  

New polystyrene-based polymers with high π-extended hole transport pendants were synthesized to obtain a low turn-on voltage and high efficiency in solution-processed green TADF-OLEDs.


2017 ◽  
Vol 5 (28) ◽  
pp. 6989-6996 ◽  
Author(s):  
Junming Li ◽  
Shou-Cheng Dong ◽  
Andreas Opitz ◽  
Liang-Sheng Liao ◽  
Norbert Koch

Host materials for modern high-efficiency organic light-emitting diodes (OLEDs) based on phosphorescence and thermally activated delayed fluorescence were optimized with respect to thermal stability, photophysical properties, energy levels, and charge carrier transport.


2019 ◽  
Vol 55 (86) ◽  
pp. 12952-12955 ◽  
Author(s):  
Mallesham Godumala ◽  
Jiwon Yoon ◽  
Chiho Lee ◽  
Ji-Eun Jeong ◽  
Sungnam Park ◽  
...  

With chromenopyrazole as an electron-acceptor core, two new bipolar host materials (DCzCP and TCzCP) exhibited high performance and low roll-off in solution-processable TADF-OLEDs.


Nanomaterials ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 239 ◽  
Author(s):  
Ionela Andreea Neacsu ◽  
Alexandra Elena Stoica ◽  
Bogdan Stefan Vasile ◽  
Ecaterina Andronescu

One new, promising approach in the medical field is represented by hydroxyapatite doped with luminescent materials for biomedical luminescence imaging. The use of hydroxyapatite-based luminescent materials is an interesting area of research because of the attractive characteristics of such materials, which include biodegradability, bioactivity, biocompatibility, osteoconductivity, non-toxicity, and their non-inflammatory nature, as well their accessibility for surface adaptation. It is well known that hydroxyapatite, the predominant inorganic component of bones, serves a substantial role in tissue engineering, drug and gene delivery, and many other biomedical areas. Hydroxyapatite, to the detriment of other host matrices, has attracted substantial attention for its ability to bind to luminescent materials with high efficiency. Its capacity to integrate a large assortment of substitutions for Ca2+, PO43−, and/or OH− ions is attributed to the versatility of its apatite structure. This paper summarizes the most recently developed fluorescent materials based on hydroxyapatite, which use rare earth elements (REEs) as dopants, such as terbium (Tb3+), erbium (Er3+), europium (Eu3+), lanthanum (La3+), or dysprosium (Dy3+), that have been developed in the biomedical field.


Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1668
Author(s):  
Zong-Liang Tseng ◽  
Wei-Lun Huang ◽  
Tzu-Hung Yeh ◽  
You-Xun Xu ◽  
Chih-Hsun Chiang

Organic light-emitting diodes (OLEDs) have developed rapidly in recent years. Thermally activated delayed fluorescent (TADF) molecules open a path to increase exciton collection efficiency from 25% to 100%, and the solution process provides an alternative technology to achieve lower cost OLEDs more easily. To develop commercial materials as exciplex hosts for high-performance and solution-processed OLEDs, we attempted to use 4,4′-cyclohexylidenebis[N,N-bis(4-methylphenyl)benzenamine (TAPC), poly(9-vinylcarbazole) (PVK), N,N′-Di(1-naphthyl)-N,N′-diphenyl-(1,1′-biphenyl)-4,4′-diamine (NPB), and poly(N,N'-bis-4-butylphenyl-N,N'-bisphenyl)benzidine (Poly-TPD) as the donors and 2,4,6-tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine (POT2T) as the acceptor to obtain the TADF effect. All donors and the acceptor were purchased from chemical suppliers. Our work shows that excellent TADF properties and high-efficiency exciplex OLEDs with low turn-on voltage and high luminance can be achieved with a simple combination of commercial materials.


Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 4870
Author(s):  
Babu Madavali ◽  
Pathan Sharief ◽  
Kyoung-Tae Park ◽  
Gian Song ◽  
Song-Yi Back ◽  
...  

Developing inexpensive and rapid fabrication methods for high efficiency thermoelectric alloys is a crucial challenge for the thermoelectric industry, especially for energy conversion applications. Here, we fabricated large amounts of p-type Cu0.07Bi0.5Sb1.5Te3 alloys, using water atomization to control its microstructure and improve thermoelectric performance by optimizing its initial powder size. All the water atomized powders were sieved with different aperture sizes, of 32–75 μm, 75–125 μm, 125–200 μm, and <200 μm, and subsequently consolidated using hot pressing at 490 °C. The grain sizes were found to increase with increasing powder particle size, which also increased carrier mobility due to improved carrier transport. The maximum electrical conductivity of 1457.33 Ω−1 cm−1 was obtained for the 125–200 μm samples due to their large grain sizes and subsequent high mobility. The Seebeck coefficient slightly increased with decreasing particle size due to scattering of carriers at fine grain boundaries. The higher power factor values of 4.20, 4.22 × 10−3 W/mk2 were, respectively, obtained for large powder specimens, such as 125–200 μm and 75–125 μm, due to their higher electrical conductivity. In addition, thermal conductivity increased with increasing particle size due to the improvement in carriers and phonons transport. The 75–125 μm powder specimen exhibited a relatively high thermoelectric figure of merit, ZT of 1.257 due to this higher electric conductivity.


2016 ◽  
Vol 11 (9) ◽  
pp. 764
Author(s):  
Lella Aicha Ayadi ◽  
Nihel Neji ◽  
Hassen Loukil ◽  
Mouhamed Ali Ben Ayed ◽  
Nouri Masmoudi

Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 1034
Author(s):  
Ching-Chien Huang ◽  
Chin-Chieh Mo ◽  
Guan-Ming Chen ◽  
Hsiao-Hsuan Hsu ◽  
Guo-Jiun Shu

In this work, an experiment was carried out to investigate the preparation condition of anisotropic, Fe-deficient, M-type Sr ferrite with optimum magnetic and physical properties by changing experimental parameters, such as the La substitution amount and little additive modification during fine milling process. The compositions of the calcined ferrites were chosen according to the stoichiometry LaxSr1-xFe12-2xO19, where M-type single-phase calcined powder was synthesized with a composition of x = 0.30. The effect of CaCO3, SiO2, and Co3O4 inter-additives on the Sr ferrite was also discussed in order to obtain low-temperature sintered magnets. The magnetic properties of Br = 4608 Gauss, bHc = 3650 Oe, iHc = 3765 Oe, and (BH)max = 5.23 MGOe were obtained for Sr ferrite hard magnets with low cobalt content at 1.7 wt%, which will eventually be used as high-end permanent magnets for the high-efficiency motor application in automobiles with Br > 4600 ± 50 G and iHc > 3600 ± 50 Oe.


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