scholarly journals Synthesis, modular composition, and electrochemical properties of lamellar iron sulfides

2020 ◽  
Vol 8 (31) ◽  
pp. 15834-15844 ◽  
Author(s):  
Noah E. Horwitz ◽  
Elena V. Shevchenko ◽  
Jehee Park ◽  
Eungje Lee ◽  
Jiaze Xie ◽  
...  

A new class of layered iron sulfide materials offers tunable composition and properties for electrochemical energy storage.

2015 ◽  
Vol 3 (10) ◽  
pp. 5722-5729 ◽  
Author(s):  
Bosi Yin ◽  
Siwen Zhang ◽  
He Jiang ◽  
Fengyu Qu ◽  
Xiang Wu

MnO2 with α-, β- and δ-type structures were controllably synthesized. The electrochemical properties of the supercapacitors based on different types of MnO2 electrodes were investigated in detail.


2020 ◽  
Author(s):  
Noah E. Horwitz ◽  
Elena V. Shevchenko ◽  
Jehee Park ◽  
Eungje Lee ◽  
Jiaze Xie ◽  
...  

Transition metal chalcogenides with layered structures have emerged as promising materials for energy storage, catalysis, and electronics, among other areas. We have identified a new layered phase of iron sulfide containing interlayer solvated cations. We present an optimized synthesis for the Li+-containing material from an Fe(III) xanthate complex. Structure and composition data indicate the material consists of poorly-ordered iron sulfide layers separated by solvated cations. The lamellar spacing in these materials can be tuned by changing the identity of the cation. Furthermore, the lamellar spacing can also be reversibly tuned by the degree of solvation of the material. The material is electrically conductive and can serve as a pseudocapacitor with comparable performance to commercial materials such as MnO<sub>2</sub>. Furthermore, these materials also show promise as lithium or sodium ion battery cathodes with good capacity and reversibility.


2020 ◽  
Vol 44 (11) ◽  
pp. 4353-4362
Author(s):  
Yutao Zhou ◽  
Alan M. Wemyss ◽  
Oliver B. Brown ◽  
Qianye Huang ◽  
Chaoying Wan

Hierarchically porous carbon nanostructures with intrinsically doped heteroatoms and metal elements are attractive for electrochemical energy storage applications.


2020 ◽  
Author(s):  
Noah E. Horwitz ◽  
Elena V. Shevchenko ◽  
Jehee Park ◽  
Eungje Lee ◽  
Jiaze Xie ◽  
...  

Transition metal chalcogenides with layered structures have emerged as promising materials for energy storage, catalysis, and electronics, among other areas. We have identified a new layered phase of iron sulfide containing interlayer solvated cations. We present an optimized synthesis for the Li+-containing material from an Fe(III) xanthate complex. Structure and composition data indicate the material consists of poorly-ordered iron sulfide layers separated by solvated cations. The lamellar spacing in these materials can be tuned by changing the identity of the cation. Furthermore, the lamellar spacing can also be reversibly tuned by the degree of solvation of the material. The material is electrically conductive and can serve as a pseudocapacitor with comparable performance to commercial materials such as MnO<sub>2</sub>. Furthermore, these materials also show promise as lithium or sodium ion battery cathodes with good capacity and reversibility.


Author(s):  
Dhanasekar Kesavan ◽  
Vimal Kumar Mariappan ◽  
Karthikeyan Krishnamoorthy ◽  
Sang-Jae Kim

In this study, we report a facile carbothermal method for the preparation of boron-oxy-carbide (BOC) nanostructures and explore their properties towards electrochemical energy storage devices.


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