scholarly journals Oscillatory structural forces between charged interfaces in solutions of oppositely charged polyelectrolytes

Soft Matter ◽  
2020 ◽  
Vol 16 (42) ◽  
pp. 9662-9668
Author(s):  
Katarzyna Kubiak ◽  
Plinio Maroni ◽  
Gregor Trefalt ◽  
Michal Borkovec

Forces between negatively charged micron-sized silica particles were measured in aqueous solutions of cationic polyelectrolytes with the atomic force microscope (AFM).

2015 ◽  
Vol 17 (25) ◽  
pp. 16553-16559 ◽  
Author(s):  
Valentina Valmacco ◽  
Gregor Trefalt ◽  
Plinio Maroni ◽  
Michal Borkovec

Direct force measurements between silica particles were carried out using the colloidal probe technique, which is based on an atomic force microscope (AFM).


Author(s):  
S.A.C. Gould ◽  
B. Drake ◽  
C.B. Prater ◽  
A.L. Weisenhorn ◽  
S.M. Lindsay ◽  
...  

The atomic force microscope (AFM) is an instrument that can be used to image many samples of interest in biology and medicine. Images of polymerized amino acids, polyalanine and polyphenylalanine demonstrate the potential of the AFM for revealing the structure of molecules. Images of the protein fibrinogen which agree with TEM images demonstrate that the AFM can provide topographical data on larger molecules. Finally, images of DNA suggest the AFM may soon provide an easier and faster technique for DNA sequencing.The AFM consists of a microfabricated SiO2 triangular shaped cantilever with a diamond tip affixed at the elbow to act as a probe. The sample is mounted on a electronically driven piezoelectric crystal. It is then placed in contact with the tip and scanned. The topography of the surface causes minute deflections in the 100 μm long cantilever which are detected using an optical lever.


2018 ◽  
Vol 20 (1) ◽  
pp. 158-164 ◽  
Author(s):  
Alexander M. Smith ◽  
Plinio Maroni ◽  
Michal Borkovec

Direct force measurements between negatively charged colloidal particles were carried out using an atomic force microscope (AFM) in aqueous solutions containing monovalent organic cations, namely tetraphenylarsonium (Ph4As+), 1-hexyl-3-methylimidazolium (HMIM+), and 1-octyl-3-methylimidazolium (OMIM+).


1997 ◽  
Vol 5 (10) ◽  
pp. 6-6 ◽  
Author(s):  
Stefan Zauscher

Atomic Force Microscopes (AFM) can measure the force between a surface and the tip of a cantilever as a junction of separation with great precision. For example, van der Waals type forces and electrostatic repulsive forces can easily be measured in aqueous solutions using an AFM. The complex, pyramidal shape of the typical AFM cantilever is, however, not well suited for quantitative measurements. It is thus desirable to attach particles of known geometry (usually spheres) to the tip of a cantilever.


Nanoscale ◽  
2015 ◽  
Vol 7 (41) ◽  
pp. 17289-17298 ◽  
Author(s):  
M. Hernando-Pérez ◽  
A. X. Cartagena-Rivera ◽  
A. Lošdorfer Božič ◽  
P. J. P. Carrillo ◽  
C. San Martín ◽  
...  

The recognition events between viruses and host cells are dominated by both specific and non-specific electrostatic interactions determined by the charge of viral particles. Here we probe the charge of individual viruses in aqueous solutions by measuring the electrostatic force between each viral particle and the Atomic Force Microscope tip.


Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 906
Author(s):  
Jinhong Zhang

An atomic force microscope (AFM) was applied to study of the adsorption of xanthate on bornite surfaces in situ in aqueous solutions. AFM images showed that xanthate, i.e., potassium ethyl xanthate (KEX) and potassium amyl xanthate (PAX), adsorbed strongly on bornite, and the adsorbate bound strongly with the mineral surface without being removed by flushing with ethanol alcohol. The AFM images also showed that the adsorption increased with the increased collector concentration and contact time. Xanthate adsorbed on bornite in a similar manner when the solution pH changed to pH 10. The AFM force measurement results showed that the probe–substrate adhesion increased due to the adsorption of xanthate on bornite. The sharp “jump-in” and “jump-off” points on force curve suggest that the adsorbate is not “soft” in nature, ruling out the existence of dixanthogen, an oily substance. Finally, the ATR-FTIR (attenuated total reflection-Fourier-transform infrared) result confirms that the adsorbate on bornite in xanthate solutions is mainly in the form of insoluble cuprous xanthate (CuX) instead of dixanthogen. This xanthate/bornite adsorption mechanism is very similar to what is obtained with the xanthate/chalcocite system, while it is different from the xanthate/chalcopyrite system, for which oily dixanthogen is the main adsorption product on the chalcopyrite surface. The present study helps clarify the flotation mechanism of bornite in industry practice using xanthate as a collector.


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