Long-term-stability continuous flow CO2 reduction electrolysers with high current efficiency

Author(s):  
Yueyuan Gu ◽  
Jucai Wei ◽  
Jindong Li ◽  
Luyang Wang ◽  
Xu Wu

One of the intrinsic problems relating to electrolysers for the electrochemical carbon dioxide reduction reaction is that the water-based liquid electrolyte induces the hydrogen evolution reaction.

2019 ◽  
Vol 7 (37) ◽  
pp. 11569-11580 ◽  
Author(s):  
Athithan Maheshwaran ◽  
Vijaya Gopalan Sree ◽  
Ho-Yeol Park ◽  
Woosum Cho ◽  
Hyein Kim ◽  
...  

Highly efficient (D–π–A)-type host and green Ir(iii) complexes are introduced for solution-processed PHOLEDs that achieve high CE with considerably high EQE. The devices with symmetrical complex show more stable than those with asymmetrical complex.


Author(s):  
Yingchun Zhang ◽  
Changsheng Cao ◽  
Xintao Wu ◽  
Qi-Long Zhu

Bismuth (Bi)-based nanomaterials are considered as the promising electrocatalysts for electrocatalytic CO2 reduction reaction (CO2RR), but it is challenging to achieve high current density and selectivity in a wide potential...


Author(s):  
Danni Zhou ◽  
Xinyuan Li ◽  
Huishan Shang ◽  
Fengjuan Qin ◽  
Wenxing Chen

Metal-organic framework (MOF) derived single-atom catalysts (SACs), featured unique active sites and adjustable topological structures, exhibit high electrocatalytic performance on carbon dioxide reduction reactions (CO2RR). By modulating elements and atomic...


Author(s):  
Rajasekaran Elakkiya ◽  
Govindhan Maduraiveeran

Design of high-performance and Earth-abundant electrocatalysts for electrochemical carbon dioxide (CO2) reduction reaction (CO2RR) into fuels and value-added chemicals offers an emergent pathway for environment and energy sustainable concerns. Herein,...


2020 ◽  
Vol 8 (31) ◽  
pp. 15936-15941 ◽  
Author(s):  
Pengda An ◽  
Lai Wei ◽  
Huangjingwei Li ◽  
Baopeng Yang ◽  
Kang Liu ◽  
...  

Enhanced carbon dioxide reduction reaction (CO2RR) with suppressed HER was achieved on polytetrafluoroethylene (PTFE) coated Cu nanoneedles (CuNNs).


2019 ◽  
Vol 7 (1) ◽  
pp. 1033-1040 ◽  
Author(s):  
Mihail Kusnezoff ◽  
Nikolai Trofimenko ◽  
Sindy Mosch ◽  
Wieland Beckert ◽  
Andreas Graff ◽  
...  

Science ◽  
2019 ◽  
Vol 365 (6451) ◽  
pp. 367-369 ◽  
Author(s):  
Shaoxuan Ren ◽  
Dorian Joulié ◽  
Danielle Salvatore ◽  
Kristian Torbensen ◽  
Min Wang ◽  
...  

Practical electrochemical carbon dioxide (CO2) conversion requires a catalyst capable of mediating the efficient formation of a single product with high selectivity at high current densities. Solid-state electrocatalysts achieve the CO2 reduction reaction (CO2RR) at current densities ≥ 150 milliamperes per square centimeter (mA/cm2), but maintaining high selectivities at high current densities and efficiencies remains a challenge. Molecular CO2RR catalysts can be designed to achieve high selectivities and low overpotentials but only at current densities irrelevant to commercial operation. We show here that cobalt phthalocyanine, a widely available molecular catalyst, can mediate CO2 to CO formation in a zero-gap membrane flow reactor with selectivities > 95% at 150 mA/cm2. The revelation that molecular catalysts can work efficiently under these operating conditions illuminates a distinct approach for optimizing CO2RR catalysts and electrolyzers.


2018 ◽  
Vol 42 (16) ◽  
pp. 13256-13262 ◽  
Author(s):  
A. Ma’alinia ◽  
H. Asgari Moghaddam ◽  
E. Nouri ◽  
M. R. Mohammadi

Hydroxypropyl cellulose as a polymeric gelator agent was incorporated in the liquid electrolyte of dye-sensitized solar cells, showing long-term stability and efficient performance.


Sign in / Sign up

Export Citation Format

Share Document