Long-term stability of dye-sensitized solar cells using a facile gel polymer electrolyte

2018 ◽  
Vol 42 (16) ◽  
pp. 13256-13262 ◽  
Author(s):  
A. Ma’alinia ◽  
H. Asgari Moghaddam ◽  
E. Nouri ◽  
M. R. Mohammadi

Hydroxypropyl cellulose as a polymeric gelator agent was incorporated in the liquid electrolyte of dye-sensitized solar cells, showing long-term stability and efficient performance.

Crystals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1158 ◽  
Author(s):  
Jan Lukas Storck ◽  
Marius Dotter ◽  
Bennet Brockhagen ◽  
Timo Grothe

Alongside efficiency, long-term stability of dye-sensitized solar cells (DSSCs) is a key factor regarding their commercialization. One suitable and cost-effective method to increase the long-term stability is to prevent leakage and evaporation of the electrolyte by gelling it with polymers such as poly(ethylene oxide) (PEO) and gaining a gel polymer electrolyte (GPE). In this study, a GPE based on PEO and glycerol is investigated for the first time as electrolyte for environmentally friendly DSSCs with natural dyes. To evaluate the novel glycerol/PEO GPE, the ionic conductivity and resulting efficiency progressions of DSSCs were measured for 75 days. Different molecular weights (MWs) of PEO and blending with poly(vinylidene fluoride) (PVDF) had negligible impact on efficiencies. 17 wt% PEO was found to be more suitable than lower concentrations and resulted in a relatively high efficiency over 75 days. A glycerol electrolyte without PEO had higher ionic conductivity and achieved higher efficiencies as well but leaked from the unsealed DSSCs. In addition, the reproducibility was examined especially, which appeared to be reduced by considerable differences between identical DSSCs and between measurements of the same DSSC at different times. This emphasizes the relevance of studying multiple DSSC per sample to ensure reliable results.


Author(s):  
N M Nursam ◽  
J Hidayat ◽  
L Muliani ◽  
P N Anggraeni ◽  
L Retnaningsih ◽  
...  

ACS Photonics ◽  
2020 ◽  
Vol 7 (3) ◽  
pp. 653-664 ◽  
Author(s):  
Mahyar Mohammadnezhad ◽  
Gurpreet Singh Selopal ◽  
Zhiming M. Wang ◽  
Barry Stansfield ◽  
Haiguang Zhao ◽  
...  

2009 ◽  
Vol 2 (10) ◽  
pp. 1109 ◽  
Author(s):  
Kohjiro Hara ◽  
Zhong-Sheng Wang ◽  
Yan Cui ◽  
Akihiro Furube ◽  
Nagatoshi Koumura

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