scholarly journals Hierarchical two-dimensional molecular assembly through dynamic combination of conformational states at the liquid/solid interface

2020 ◽  
Vol 11 (34) ◽  
pp. 9254-9261
Author(s):  
Matsuhiro Maeda ◽  
Ruri Nakayama ◽  
Steven De Feyter ◽  
Yoshito Tobe ◽  
Kazukuni Tahara
Keyword(s):  
Building Blocks ◽  
Molecular Assembly ◽  
Molecular Network ◽  
Two Dimensional ◽  
Conformational States ◽  
Solid Interface ◽  
Promising Strategy ◽  
Self Assembled

Self-sorting of multiple building blocks for correctly positioning molecules through orthogonal recognition is a promising strategy for construction of a hierarchical self-assembled molecular network (SAMN) on a surface.

scholarly journals Principles of molecular assemblies leading to molecular nanostructures

2013 ◽  
Vol 371 (2000) ◽  
pp. 20120304 ◽  
Author(s):  
Kunal S. Mali ◽  
Steven De Feyter
Keyword(s):  
Self Assembly ◽  
Contemporary Literature ◽  
High Vacuum ◽  
Building Blocks ◽  
Ultra High Vacuum ◽  
Two Dimensional ◽  
Ambient Conditions ◽  
Solid Interface ◽  
Metal Organic ◽  
Molecular Nanostructures

Self-assembled physisorbed monolayers consist of regular two-dimensional arrays of molecules. Two-dimensional self-assembly of organic and metal–organic building blocks is a widely used strategy for nanoscale functionalization of surfaces. These supramolecular nanostructures are typically sustained by weak non-covalent forces such as van der Waals, electrostatic, metal–ligand, dipole–dipole and hydrogen bonding interactions. A wide variety of structurally very diverse monolayers have been fabricated under ambient conditions at the liquid–solid and air–solid interface or under ultra-high-vacuum (UHV) conditions at the UHV–solid interface. The outcome of the molecular self-assembly process depends on a variety of factors such as the nature of functional groups present on assembling molecules, the type of solvent, the temperature at which the molecules assemble and the concentration of the building blocks. The objective of this review is to provide a brief account of the progress in understanding various parameters affecting two-dimensional molecular self-assembly through illustration of some key examples from contemporary literature.

scholarly journals Tailoring the Structure of Two‐Dimensional Self‐Assembled Nanoarchitectures Based on NiII–Salen Building Blocks

2014 ◽  
Vol 20 (42) ◽  
pp. 13566-13575 ◽  
Author(s):  
Marta Viciano‐Chumillas ◽  
Dongzhe Li ◽  
Alexander Smogunov ◽  
Sylvain Latil ◽  
Yannick J. Dappe ◽  
...  
Keyword(s):  
Building Blocks ◽  
Two Dimensional ◽  
Self Assembled

scholarly journals Mapping Conformational Changes in a Self-Assembled Two-Dimensional Molecular Network by Statistical Analysis of Conductance Images

2019 ◽  
Vol 11 (3) ◽  
Author(s):  
Borislav Naydenov ◽  
Samuel Torsney ◽  
Alejandro Santana Bonilla ◽  
Andrea Gualandi ◽  
Luca Mengozzi ◽  
...  
Keyword(s):  
Statistical Analysis ◽  
Conformational Changes ◽  
Molecular Network ◽  
Two Dimensional ◽  
Self Assembled

Frontispiece: Tailoring the Structure of Two‐Dimensional Self‐Assembled Nanoarchitectures Based on Ni II –Salen Building Blocks

2014 ◽  
Vol 20 (42) ◽  
Author(s):  
Marta Viciano‐Chumillas ◽  
Dongzhe Li ◽  
Alexander Smogunov ◽  
Sylvain Latil ◽  
Yannick J. Dappe ◽  
...  
Keyword(s):  
Building Blocks ◽  
Two Dimensional ◽  
Self Assembled

Molecular tuning of amino acids to form two-dimensional molecular networks driven by conformational preorganization

2016 ◽  
Vol 52 (97) ◽  
pp. 14055-14058 ◽  
Author(s):  
Young-Sang Youn ◽  
Aram Jeon ◽  
Do Hwan Kim ◽  
Hee-Seung Lee ◽  
Sehun Kim
Keyword(s):  
Amino Acids ◽  
Dft Calculations ◽  
Self Assembly ◽  
Intramolecular Interaction ◽  
The Self ◽  
Molecular Network ◽  
Molecular Networks ◽  
Two Dimensional ◽  
Self Assembled ◽  
Self Association

We investigated the self-assembly of rationally designed γ-Phe on Au(111) using STM with DFT calculations. In contrast to α-Phe, γ-Phe self-assembled into 2D molecular network. The better self-association was attributed to conformational preorganization through intramolecular interaction.

scholarly journals “Concentration-in-Control” self-assembly concept at the liquid–solid interface challenged

2021 ◽  
Author(s):  
Gangamallaiah Velpula ◽  
Cristina Martin ◽  
Brent Daelemans ◽  
Gunther Hennrich ◽  
Mark Van der Auweraer ◽  
...  
Keyword(s):  
Self Assembly ◽  
Solute Concentration ◽  
High Density ◽  
Molecular Network ◽  
Low Density ◽  
Solid Interface ◽  
Self Assembled

Surprise! against expectations, increasing (decreasing) the solute concentration leads to the formation of a low-density (high-density) self-assembled molecular network at the liquid–solid interface.

SELF-ASSEMBLY OF BISMUTH SELENIDE TWO-DIMENSIONAL SUPERSTRUCTURE FROM HEXAGONAL NANOSHEETS

2011 ◽  
Vol 04 (03) ◽  
pp. 245-248
Author(s):  
JUNJIE SHEN ◽  
QIAN SUN ◽  
TIEJUN ZHU ◽  
XINBING ZHAO
Keyword(s):  
Self Assembly ◽  
Building Blocks ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Facile Hydrothermal Method ◽  
Lattice Match ◽  
X Ray ◽  
Good Lattice ◽  
Self Assembled ◽  
Scanning Electron

A kind of novel superstructure array composed of hexagonal Bi2Se3 nanosheets were fabricated via a facile hydrothermal method. The structure was characterized by X-ray diffraction and field emission scanning electron micrioscopy. It is suggested that the two dimensional superstructure was self-assembled by sheet-like Bi2Se3 building blocks on naturally-formed Bi2SeO2 precusor template. The present result indicates one promising way in design and growth of self-assembled superstructures by controllable crystal growth from deoxided substrates with good lattice match.

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