scholarly journals Highly selective and sensitive simultaneous nanomolar detection of Cs(i) and Al(iii) ions using tripodal organic nanoparticles in aqueous media: the effect of the urea backbone on chemosensing

RSC Advances ◽  
2020 ◽  
Vol 10 (38) ◽  
pp. 22691-22700
Author(s):  
Jayanti Mishra ◽  
Manpreet Kaur ◽  
Navneet Kaur ◽  
Ashok K. Ganguli

Two ligands 1 and 2 are synthesized and their organic nanoparticles (1-ONP and 2-ONP) are generated. 1-ONP has shown the chemosensing of Cs(i) (∼220 nm) and Al(iii) (∼377 nm) in aqueous medium while 2-ONP has not shown any chemosensing behaviour.

The Analyst ◽  
2019 ◽  
Vol 144 (8) ◽  
pp. 2480-2497 ◽  
Author(s):  
Mukhtiar Ahmed ◽  
Muhammad Faisal ◽  
Ayesha Ihsan ◽  
Muhammad Moazzam Naseer

Fluorescent organic nanoparticle (FON)-based chemosensors are emerging as a valuable tool for the fast and accurate detection of metal ions in aqueous media. In this review, we highlight the recent developments in this field.


2014 ◽  
Vol 106 ◽  
pp. 45-50 ◽  
Author(s):  
Shweta Chopra ◽  
Narinder Singh ◽  
Pandiyan Thangarasu ◽  
Vimal K. Bhardwaj ◽  
Navneet Kaur

2020 ◽  
Vol 5 (8) ◽  
pp. 1428-1436
Author(s):  
Anu Saini ◽  
Manpreet Kaur ◽  
Mayank ◽  
Anil Kuwar ◽  
Navneet Kaur ◽  
...  

Hybrid nanoassembly, fluorescent chemosensors, selective response to ketoprofen, and nanomolar detection.


Author(s):  
Divya Singhal ◽  
Neha Gupta ◽  
Ashok Kumar Singh

4-(thiazol-2-yldiazenyl)phenol (L1) and 2-((4-hydroxyphenyl) diazenyl)-5-nitrophenol (L2) based on azo phenol were synthesised and used as selective colorimetric sensor for CN- and AcO− ion in DMSO/H2O-HEPES (v/v; 1:1, pH–7.3 ± 0.2) and showed good sensitivity with large red shifts and nanomolar detection limit for CN- and AcO- ion. The stoichiometry of L1 with CN−/AcO− ion was found to be 1:1 and L2 with CN−/AcO− ion was found to be 1:2. Binding constant for L1+ CN−, L1 + AcO−, L2 + CN− and L2 + AcO− were calculated by B-H plot as 1.6 × 103, 8.0 × 102, 8.4 × 103 and 1.7 × 102 respectively. L2 showed high selectivity towards CN− ion with low detection limit of 81 nM and large binding constant. In addition, 1H NMR titration and DFT studies also supported the deprotonation mechanism of receptors in the presence of selective anions.


ACS Omega ◽  
2020 ◽  
Vol 5 (31) ◽  
pp. 19896-19904
Author(s):  
Sanay Naha ◽  
Natesan Thirumalaivasan ◽  
Somenath Garai ◽  
Shu-Pao Wu ◽  
Sivan Velmathi

SynOpen ◽  
2018 ◽  
Vol 02 (01) ◽  
pp. 0001-0005 ◽  
Author(s):  
Saeed Balalaie ◽  
Hamed Esmaeilabadi ◽  
Saber Mehrparvar ◽  
Frank Rominger ◽  
Fatima Hamdan ◽  
...  

Synthesis of functionalized 2,3-dihydropyrido[2,3-d]pyrimidin-4(1H)-one from a cascade reaction between 3-formylchromone, malononitrile, diammonium hydrogen phosphate, and aromatic aldehydes in aqueous media is described.


2017 ◽  
Vol 72 (1) ◽  
pp. 35-41 ◽  
Author(s):  
Yuling Xu ◽  
Stephen Opeyemi Aderinto ◽  
Huilu Wu ◽  
Hongping Peng ◽  
Han Zhang ◽  
...  

AbstractA new Schiff base, 4-allylamine-N-(N-5-methylsalicylidene)-1,8-naphthalimide (1), has been designed and synthesized by combining a 1,8-naphthalimide moiety as a fluorophore and a Schiff base as a recognition group. Its photophysical properties were investigated by absorption and fluorescence spectroscopy, and this sensor exhibits a high fluorescence quantum yield of 0.75–0.91 inorganic solvents of different polarity. It also shows high selectivity for Cu2+ over other ions with fluorescence quenching in aqueous medium (pH=7.2). The reason for this phenomenon (fluorescence quenching) is attributed to the formation of a 1:1 complex between 1 and Cu2+ according to the Job plot and fluorescence titration. The sensor can be applied to the quantification of Cu2+ in a linear fashion from 0.5 to 5 μM with a detection limit of 0.23 μM. Additionally, the association constant (Ka) between Cu2+ and 1 is 1.328×106 M−1 in aqueous media.


2007 ◽  
Vol 60 (4) ◽  
pp. 305 ◽  
Author(s):  
Sunita B. Bandgar ◽  
Babasaheb P. Bandgar ◽  
Balaji L. Korbad ◽  
Jalinder V. Totre ◽  
Sachin Patil

The synthesis of various tetrahydrobenzo[b]pyran derivatives has been carried out by means of an uncatalyzed, three-component, one-pot clean condensation of aromatic aldehydes, reactive methylene compounds, and dimidone in aqueous medium. Simple workup, and mild and neutral conditions that give quantitative yields of products in pure form, are the attractive features of this method.


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