Orientation of the α-CD component of [2]rotaxanes affects their specific molecular recognition behaviour

2021 ◽  
Author(s):  
Takuya Iwamoto ◽  
Shinobu Miyagawa ◽  
Masaya Naito ◽  
Yuji Tokunaga
Keyword(s):  
Molecular Recognition ◽  
Anion Recognition ◽  
Oh Groups ◽  
Recognition Ability ◽  
Phenol Moiety

An α-CD component enhanced the anion recognition ability of the urea moiety and the deprotonation of the phenol moiety in the axle component in orientationally isomeric [2]rotaxanes with the OH groups on the wide rim of the α-CD, respectively.

scholarly journals Well-structured bimetallic surface capable of molecular recognition for chemoselective nitroarene hydrogenation

2016 ◽  
Vol 7 (7) ◽  
pp. 4476-4484 ◽  
Author(s):  
Shinya Furukawa ◽  
Katsuya Takahashi ◽  
Takayuki Komatsu
Keyword(s):  
Molecular Recognition ◽  
Bimetallic Surface ◽  
Recognition Ability

Unprecedented molecular recognition ability governed by a simple bimetallic surface was demonstrated.

scholarly journals Role of surface adsorption and porosity features in the molecular recognition ability of imprinted sol–gels

2008 ◽  
Vol 23 (7) ◽  
pp. 1101-1108 ◽  
Author(s):  
Laura Guardia ◽  
Rosana Badía-Laíño ◽  
Marta Elena Díaz-García ◽  
Conchi O. Ania ◽  
José B. Parra
Keyword(s):  
Molecular Recognition ◽  
Surface Adsorption ◽  
Recognition Ability

scholarly journals Synthesis of per(5-N-carboxamide-5-dehydroxylmethyl)-β-cyclodextrins and their selective recognition ability utilizing multiple hydrogen bonds

2019 ◽  
Vol 55 (27) ◽  
pp. 3872-3875 ◽  
Author(s):  
Takashi Nakamura ◽  
Sota Yonemura ◽  
Tatsuya Nabeshima
Keyword(s):  
Hydrogen Bonds ◽  
Functional Groups ◽  
Anion Recognition ◽  
Binding Mode ◽  
Selective Recognition ◽  
Recognition Ability ◽  
Multiple Hydrogen Bonds

An amide cyclodextrin with anion recognition ability exhibits unique binding mode in which unsymmetrically arranged functional groups play distinctive roles.

An Ir3L2 complex with anion binding pockets: photocatalytic E–Z isomerization via molecular recognition

2021 ◽  
Author(s):  
Haruka Sunohara ◽  
Kenta Koyamada ◽  
Hiroki Takezawa ◽  
Makoto Fujita
Keyword(s):  
Molecular Recognition ◽  
Anion Binding ◽  
Recognition Ability ◽  
Binding Pockets ◽  
Self Assembled

A molecular host with photosensitizing centers provides photo-responsive host–guest properties based on its molecular recognition ability. Here, we construct a self-assembled photoactive Ir(III) cage-shaped complex that contains anion binding pockets...

scholarly journals Studies of the Molecular Recognition Abilities of Gallic Acid-Imprinted Polymer Prepared Using a Molecular Imprinting Technique

2012 ◽  
Vol 30 (1) ◽  
pp. 23-34 ◽  
Author(s):  
Sushma Pardeshi ◽  
Rita Dhodapkar ◽  
Anupama Kumar
Keyword(s):  
Molecular Recognition ◽  
Gallic Acid ◽  
Density Functional ◽  
Thermal Polymerization ◽  
Systematic Investigation ◽  
Template Molecule ◽  
Functional Monomers ◽  
Recognition Ability ◽  
Stabilization Energies ◽  
Electronic Stabilization

The present work compares the molecular recognition abilities of two molecularly imprinted polymers (MIPs) synthesized using two different functional monomers, viz. acrylamide (AA) and 4-vinylpyridine (4-Vp), employing gallic acid (GA) as the template using the non-covalent imprinting approach employing ethylene glycol dimethacrylate (EGDMA) as the cross-linker and 2,2-azo-bis-2-isobutyronitrile (AIBN) as an initiator in the porogen acetonitrile by thermal polymerization. The change in the electronic stabilization energies (ΔE) of the template–monomer complexes formed between the template and functional monomers in the presence of the porogen were computed using Density Functional Theory (DFT) to interpret the nature of the interactions between them and to compare their stabilities. A systematic investigation of the molecular recognition abilities of the synthesized MIPs has been carried out by applying the Langmuir–Freundlich (L–F) adsorption isotherm model. The binding parameters obtained from the L–F model demonstrate that MIPAA exhibited a higher specific molecular recognition ability towards the template molecule.

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