scholarly journals Recent advances in the synthesis of bridgehead (or ring-junction) nitrogen heterocycles via transition metal-catalyzed C–H bond activation and functionalization

2020 ◽  
Vol 7 (19) ◽  
pp. 3067-3099
Author(s):  
Biao Nie ◽  
Wanqing Wu ◽  
Yingjun Zhang ◽  
Huanfeng Jiang ◽  
Ji Zhang
Keyword(s):  
Transition Metal ◽  
Bond Activation ◽  
Nitrogen Heterocycles ◽  
Fused Heterocycles ◽  
Recent Advances ◽  
Ring Junction ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Bridgehead Nitrogen

An update on recent advances in the synthesis of bridgehead nitrogen fused heterocycles via transition metal-catalyzed C–H activation and functionalization is reported.

Recent advances in transition-metal-catalyzed C–CN bond activations

RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47806-47826 ◽  
Author(s):  
Qiaodong Wen ◽  
Ping Lu ◽  
Yanguang Wang
Keyword(s):  
Transition Metal ◽  
Bond Activation ◽  
Cross Coupling ◽  
Recent Advances ◽  
Transition Metal Catalyzed ◽  
Bond Activations ◽  
Metal Catalyzed

Recent advances in transition-metal-catalyzed C–CN bond activation, leading to a lot of important approaches such as cyanofunctionalization, cross-coupling and cyanation, are reviewed.

Transition-metal-catalyzed direct β-functionalization of simple carbonyl compounds

2014 ◽  
Vol 1 (7) ◽  
pp. 838-842 ◽  
Author(s):  
Guobing Yan ◽  
Arun Jyoti Borah
Keyword(s):  
Transition Metal ◽  
Carbonyl Compounds ◽  
Bond Activation ◽  
Active Area ◽  
Synthetic Chemistry ◽  
Chemical Transformations ◽  
Recent Advances ◽  
Direct Functionalization ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Chemical transformations via catalytic C–H bond activation have been established as one of the most powerful tools in organic synthetic chemistry. Transition-metal-catalyzed direct functionalization of β-C(sp3)–H bonds of carbonyl compounds has been developed in recent years. This highlight will focus on recent advances in this active area and their mechanisms are also discussed.

Transition metal-catalyzed direct remote C–H functionalization of alkyl groups via C(sp3)–H bond activation

2015 ◽  
Vol 2 (2) ◽  
pp. 169-178 ◽  
Author(s):  
Guanyinsheng Qiu ◽  
Jie Wu
Keyword(s):  
Transition Metal ◽  
Bond Activation ◽  
Recent Advances ◽  
Alkyl Groups ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This review is focused on the recent advances in the transition metal-catalyzed direct remote C–H-functionalization of alkyl groups via C(sp3)–H bond activation. In general, carboxamide/ester-chelated β-functionalization reactions are summarized.

Chelation-assisted transition metal-catalysed C–H chalcogenylations

2020 ◽  
Vol 7 (8) ◽  
pp. 1022-1060 ◽  
Author(s):  
Wenbo Ma ◽  
Nikolaos Kaplaneris ◽  
Xinyue Fang ◽  
Linghui Gu ◽  
Ruhuai Mei ◽  
...  
Keyword(s):  
Transition Metal ◽  
Recent Advances ◽  
Site Selectivity ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This review summarizes recent advances in C–S and C–Se formations via transition metal-catalyzed C–H functionalization utilizing directing groups to control the site-selectivity.

Transition-Metal-Catalyzed Oxidative and Decarboxylative Acylations through sp2 C-H Bond Activation

2015 ◽  
Vol 20 (5) ◽  
pp. 471-511 ◽  
Author(s):  
Satyasheel Sharma ◽  
Neeraj Kumar Mishra ◽  
Youngmi Shin ◽  
In Su Kim
Keyword(s):  
Transition Metal ◽  
Bond Activation ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed
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