Asymmetric seven-/eight-step spin-crossover in a three-dimensional Hofmann-type metal–organic framework

2020 ◽  
Vol 7 (8) ◽  
pp. 1685-1690 ◽  
Author(s):  
Yuan-Yuan Peng ◽  
Si-Guo Wu ◽  
Yan-Cong Chen ◽  
Wei Liu ◽  
Guo-Zhang Huang ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crossover Behavior ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

An unprecedented hysteretic seven-/eight-step spin-crossover behavior is revealed. Most importantly, a molecular alloy based on a Hofmann-type framework is used as a strategy to explore multi-step spin-crossover materials for the first time.

The substituent guest effect on four-step spin-crossover behavior

2020 ◽  
Vol 7 (4) ◽  
pp. 911-917 ◽  
Author(s):  
Cui-Juan Zhang ◽  
Kai-Ting Lian ◽  
Si-Guo Wu ◽  
Yang Liu ◽  
Guo-Zhang Huang ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crossover Behavior ◽  
Metal Organic ◽  
Organic Framework

The fluoro substituent strategy on the guest in a three-dimensional Hofmann-type metal–organic framework is explored for four-step spin-crossover properties.

Perturbation of Spin Crossover Behavior by Covalent Post-Synthetic Modification of a Porous Metal-Organic Framework

2014 ◽  
Vol 53 (38) ◽  
pp. 10164-10168 ◽  
Author(s):  
John E. Clements ◽  
Jason R. Price ◽  
Suzanne M. Neville ◽  
Cameron J. Kepert
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Crossover Behavior ◽  
Metal Organic ◽  
Organic Framework

Reversible three equal-step spin crossover in an iron(ii) Hofmann-type metal–organic framework

2018 ◽  
Vol 47 (5) ◽  
pp. 1407-1411 ◽  
Author(s):  
Fu-Ling Liu ◽  
Dong Li ◽  
Li-Jie Su ◽  
Jun Tao
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Crossover Behavior ◽  
Metal Organic ◽  
Organic Framework

A novel bent ligand-pillared 3D Hofmann-type MOF exhibited incomplete three-step spin-crossover behavior with a sequence of HS1.00 ↔ HS0.75LS0.25 ↔ HS0.5LS0.5 ↔ HS0.25LS0.75.

Perturbation of Spin Crossover Behavior by Covalent Post-Synthetic Modification of a Porous Metal-Organic Framework

2014 ◽  
Vol 126 (38) ◽  
pp. 10328-10332 ◽  
Author(s):  
John E. Clements ◽  
Jason R. Price ◽  
Suzanne M. Neville ◽  
Cameron J. Kepert
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Crossover Behavior ◽  
Metal Organic ◽  
Organic Framework

Hysteretic four-step spin-crossover in a 3D Hofmann-type metal–organic framework with aromatic guest

2019 ◽  
Vol 55 (74) ◽  
pp. 11033-11036 ◽  
Author(s):  
Cui-Juan Zhang ◽  
Kai-Ting Lian ◽  
Guo-Zhang Huang ◽  
Sukhen Bala ◽  
Zhao-Ping Ni ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Aromatic Guest ◽  
First Time ◽  
Organic Framework

Hysteretic four-step spin crossover behaviour with the sequence of LS ↔ HS0.25LS0.75 ↔ HS0.5LS0.5 ↔ HS0.67LS0.33 ↔ HS is observed for the first time.

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

Three-dimensional hierarchical C-Co-N/Se derived from metal-organic framework as superior cathode for Li-Se batteries

2017 ◽  
Vol 363 ◽  
pp. 103-109 ◽  
Author(s):  
Jiarui He ◽  
Weiqiang Lv ◽  
Yuanfu Chen ◽  
Jie Xiong ◽  
Kechun Wen ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Metal Organic ◽  
Organic Framework

Electron transitions in a Ce(iii)-catecholate metal–organic framework

2022 ◽  
Author(s):  
Julia G. Knapp ◽  
Debmalya Ray ◽  
Paul B. Calio ◽  
Megan C. Wasson ◽  
Thais R. Scott ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Electron Transitions ◽  
Metal Organic ◽  
Organic Framework

Competitive electron transitions are present in a rare three-dimensional Ce(iii)-catecholate metal–organic framework.

Sign in / Sign up

Export Citation Format

Share Document