Perturbation of Spin Crossover Behavior by Covalent Post-Synthetic Modification of a Porous Metal-Organic Framework

2014 ◽  
Vol 53 (38) ◽  
pp. 10164-10168 ◽  
Author(s):  
John E. Clements ◽  
Jason R. Price ◽  
Suzanne M. Neville ◽  
Cameron J. Kepert
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Crossover Behavior ◽  
Metal Organic ◽  
Organic Framework

Perturbation of Spin Crossover Behavior by Covalent Post-Synthetic Modification of a Porous Metal-Organic Framework

2014 ◽  
Vol 126 (38) ◽  
pp. 10328-10332 ◽  
Author(s):  
John E. Clements ◽  
Jason R. Price ◽  
Suzanne M. Neville ◽  
Cameron J. Kepert
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Crossover Behavior ◽  
Metal Organic ◽  
Organic Framework

Asymmetric seven-/eight-step spin-crossover in a three-dimensional Hofmann-type metal–organic framework

2020 ◽  
Vol 7 (8) ◽  
pp. 1685-1690 ◽  
Author(s):  
Yuan-Yuan Peng ◽  
Si-Guo Wu ◽  
Yan-Cong Chen ◽  
Wei Liu ◽  
Guo-Zhang Huang ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crossover Behavior ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

An unprecedented hysteretic seven-/eight-step spin-crossover behavior is revealed. Most importantly, a molecular alloy based on a Hofmann-type framework is used as a strategy to explore multi-step spin-crossover materials for the first time.

Reversible three equal-step spin crossover in an iron(ii) Hofmann-type metal–organic framework

2018 ◽  
Vol 47 (5) ◽  
pp. 1407-1411 ◽  
Author(s):  
Fu-Ling Liu ◽  
Dong Li ◽  
Li-Jie Su ◽  
Jun Tao
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Crossover Behavior ◽  
Metal Organic ◽  
Organic Framework

A novel bent ligand-pillared 3D Hofmann-type MOF exhibited incomplete three-step spin-crossover behavior with a sequence of HS1.00 ↔ HS0.75LS0.25 ↔ HS0.5LS0.5 ↔ HS0.25LS0.75.

The substituent guest effect on four-step spin-crossover behavior

2020 ◽  
Vol 7 (4) ◽  
pp. 911-917 ◽  
Author(s):  
Cui-Juan Zhang ◽  
Kai-Ting Lian ◽  
Si-Guo Wu ◽  
Yang Liu ◽  
Guo-Zhang Huang ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crossover Behavior ◽  
Metal Organic ◽  
Organic Framework

The fluoro substituent strategy on the guest in a three-dimensional Hofmann-type metal–organic framework is explored for four-step spin-crossover properties.

Multifunctionality in an Ion-Exchanged Porous Metal–Organic Framework

2021 ◽  
Vol 143 (3) ◽  
pp. 1365-1376
Author(s):  
Sérgio M. F. Vilela ◽  
Jorge A. R. Navarro ◽  
Paula Barbosa ◽  
Ricardo F. Mendes ◽  
Germán Pérez-Sánchez ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

Unusual pore structure and sorption behaviour in a hexanodal zinc–organic framework material

2014 ◽  
Vol 50 (14) ◽  
pp. 1678-1681 ◽  
Author(s):  
Jinjie Qian ◽  
Feilong Jiang ◽  
Linjie Zhang ◽  
Kongzhao Su ◽  
Jie Pan ◽  
...  
Keyword(s):  
Pore Structure ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Sorption Behaviour ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework structurally consists of three topological kinds of 3-connected 1,3,5-benzenetricarboxylate ligands, Zn2(COO)4, Zn3O(COO)6 and Zn4O(COO)6 SBUs, featuring a new 3,3,3,4,4,6-c hexanodal topology.

High-Throughput Aided Synthesis of the Porous Metal−Organic Framework-Type Aluminum Pyromellitate, MIL-121, with Extra Carboxylic Acid Functionalization

2010 ◽  
Vol 49 (21) ◽  
pp. 9852-9862 ◽  
Author(s):  
Christophe Volkringer ◽  
Thierry Loiseau ◽  
Nathalie Guillou ◽  
Gérard Férey ◽  
Mohamed Haouas ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
High Throughput ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

A Solar Assistant Dehumidifier Based on Porous Metal-Organic Framework

2021 ◽  
Vol 896 ◽  
pp. 13-20
Author(s):  
Xiao Yu Wen
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Modern Architecture ◽  
Activated Alumina ◽  
Additional Energy ◽  
Humidity Control ◽  
Energy Inputs ◽  
Metal Organic ◽  
High Regeneration ◽  
Organic Framework

As an important factor to measure environmental comfort, humidity control is very important. However, previous dehumidification methods have many defects, such as condensation and adsorbents, which often require a lot of energy. The growing requirements of an indoor environment can stem from the development of living levels and technology. Humidity, as an important factor to measure environmental comfort, affects living and production, and indoor humidity control is an indispensable part of modern architecture. However, there are many defects in the previous dehumidification methods, such as condensation dehumidification, which often requires a lot of energy. Traditional adsorbents (such as zeolite silica and activated alumina) have problems with fragile structures or high regeneration temperatures. In this paper, an indoor dehumidification device based on the porous metal-organic framework {MOF-801, Zr6O4(OH)4(Fumarate)6}, can realize the indoor dehumidification process only by using a small amount of solar energy (1 kilowatt per square meter). The device is expected to remove 0.2113 kg/h of moisture per square meter MOF-801, only needs a few additional energy inputs.

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