Highly efficient near-infrared phosphor LaMgGa11O19:Cr3+

2020 ◽  
Vol 7 (6) ◽  
pp. 1467-1473 ◽  
Author(s):  
Shengqiang Liu ◽  
Zhizhen Wang ◽  
Hao Cai ◽  
Zhen Song ◽  
Quanlin Liu
Keyword(s):  
Near Infrared ◽  
High Efficiency ◽  
Thermal Quenching ◽  
Highly Efficient ◽  
Nir Emission

LaMgGa11O19:Cr3+ phosphor was synthesized successfully, showing broadband NIR emission centered at ∼770 nm, high efficiency and excellent thermal quenching resistance for pc-LEDs.

Efficient near-infrared (NIR) polymer light-emitting diodes (PLEDs) based on heteroleptic iridium(iii) complexes with post-modification effects of intramolecular hydrogen bonding or BF2-chelation

2018 ◽  
Vol 6 (39) ◽  
pp. 10589-10596 ◽  
Author(s):  
Guorui Fu ◽  
Hao Zheng ◽  
Yani He ◽  
Wentao Li ◽  
Xingqiang Lü ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Near Infrared ◽  
High Efficiency ◽  
Light Emitting Diodes ◽  
Intramolecular Hydrogen Bonding ◽  
Light Emitting ◽  
Nir Emission ◽  
Polymer Light Emitting Diodes ◽  
Post Modification ◽  
Intramolecular Hydrogen

Two new heteroleptic iridium(iii)-complexes capable of NIR emission are used to fabricate NIR-PLEDs with high efficiency and almost negligible efficiency-roll-off.

Distorted–octahedral site‒occupation induced high efficiency broadband near infrared emission in LiScGe2O6:Cr3+ phosphor

2021 ◽  
Author(s):  
Xuehua Chen ◽  
Enhai Song ◽  
Yayun Zhou ◽  
Fanquan He ◽  
Jiqiao Yang ◽  
...  
Keyword(s):  
Octahedral Site ◽  
Near Infrared ◽  
High Efficiency ◽  
Light Emitting Diodes ◽  
Optoelectronic Device ◽  
Infrared Emission ◽  
Light Emitting ◽  
Distorted Octahedral ◽  
Nir Emission ◽  
Near Infrared Emission

The discovery of high efficiency broadband Near-infrared (NIR) emission phosphor for phosphor-converted light-emitting diodes (NIR-pc-LEDs) is of importance for optoelectronic device and the emerging applications. Herein, a highly efficient broadband...

Designing of near-infrared sensitive asymmetric small molecular donors for high-efficiency organic solar cells

2020 ◽  
Vol 19 (08) ◽  
pp. 2050034 ◽  
Author(s):  
Muhammad Yasir Mehboob ◽  
Muhammad Usman Khan ◽  
Riaz Hussain ◽  
Rafia Fatima ◽  
Zobia Irshad ◽  
...  
Keyword(s):  
Solar Cells ◽  
Dipole Moment ◽  
Organic Solar Cells ◽  
Near Infrared ◽  
High Efficiency ◽  
Energy Gap ◽  
Transition Density ◽  
Open Circuit ◽  
Excitation Energies ◽  
Highly Efficient

Herein, we have designed four small molecular donors (SMDs) with Donor–Acceptor–Acceptor (D–Á–A) backbone having different acceptor units for highly efficient organic solar cells (OSCs). The specific molecular modeling has been made by replacing the additional acceptor unit (A) of recently synthesized TPA-DAA-MDN molecule (R) by employing different highly efficient acceptor units in order to improve the photovoltaic performances of the molecules. A theoretical approach (DFT and TD-DFT) has been applied to investigate the photophysical, opto-electronic and photovoltaic parameters of the designed molecules (DAA1–DAA4) and compared with the reference molecule (R). The red-shifting absorption of SMDs is the most important factor for highly efficient OSCs. Our all formulated molecules showed a red shifted absorption spectrum and also exhibit near IR sensitivity. Acceptor unit modification of R molecule causes reduction in HOMO-LUMO energy gap; therefore, all designed molecules offer better opto-electronic properties as compared to R molecule. A variety of certain critical factors essential for efficient SMDs like frontier molecular orbitals (FMOs), absorption maxima, dipole moment, exciton binding energy along with transition density matrix, excitation energy, open circuit voltages and charge mobilities of (DAA1–DAA4) and R have also been investigated. Generally, low values of reorganizational energy (hole and electron) offer high charge mobility and our all designed molecules are enriched in this aspect. High open circuit voltage values, low excitation energies, large dipole moment values indicate that our designed SMDs are suitable candidates for high-efficiency OSCs. Furthermore, conceptualized molecules are superior and thus are suggested to experimentalist for out-looking future progresses of highly efficient OSCs devices.

Highly Emissive Near-Infrared Solid Organic Fluorophores for Visualization of Latent Fingerprints based on Powder Dusting Method

2021 ◽  
Author(s):  
Hongbing Fu ◽  
Zheng Lv ◽  
Zhongwei Man ◽  
Zhenzhen Xu ◽  
Shuai Li ◽  
...  
Keyword(s):  
Composite Powder ◽  
Near Infrared ◽  
Low Cost ◽  
Latent Fingerprints ◽  
Latent Fingerprint ◽  
Organic Fluorophores ◽  
Highly Efficient ◽  
Fluorescent Materials ◽  
Nir Emission ◽  
Powder Dusting Method

The utilization of highly efficient fluorescent materials for latent fingerprint (LFP) is attractively important for criminal investigations but remains challenging. Herein, we developed low-cost and near-infrared (NIR) emission composite powder...

Highly Fluorescent Au25-xAgx Nanoclusters Protected with Poly(ethylene glycol) - and Zwitterion-Modified Thiolate Ligands

2018 ◽  
Author(s):  
Dinesh Mishra ◽  
Sisi Wang ◽  
Zhicheng Jin ◽  
Eric Lochner ◽  
Hedi Mattoussi
Keyword(s):  
Quantum Yield ◽  
Near Infrared ◽  
Small Diameter ◽  
Binding Energies ◽  
Thiolate Ligands ◽  
Nir Emission ◽  
Thiolate Complexes ◽  
Long Lifetime ◽  
Poly Ethylene

<p>We describe the growth and characterization of highly fluorescing, near-infrared-emitting nanoclusters made of bimetallic Au<sub>25-x</sub>Ag<sub>x</sub> cores, prepared using various monothiol-appended hydrophobic and hydrophilic ligands. The reaction uses well-defined triphenylphosphine-protected Au<sub>11</sub> clusters (as precursors), which are reacted with Ag(I)-thiolate complexes. The prepared nanoclusters are small (diameter < 2nm, as characterized by TEM) with emission peak at 760 nm and long lifetime (~12 µs). The quantum yield measured for these materials was 0.3 - 0.4 depending on the ligand. XPS measurements show the presence of both metal atoms in the core, with measured binding energies that agree with reported values for nanocluster materials. The NIR emission combined with high quantum yield, small size and ease of surface functionalization afforded by the coating, make these materials suitable to implement investigations that address fundamental questions and potentially useful for biological sensing and imaging applications.<br></p>

Ligand Influence Versus Electronic Configuration of d-metal Ion in Determining the Fate of NIR Emission from LnIII Ions: A Case Study with CuII, NiII and ZnII Complexes.

2021 ◽  
Author(s):  
Abhineet Verma ◽  
Sk Saddam Hossain ◽  
Sailaja S Sunkari ◽  
Joseph Reibenspies ◽  
Satyen Saha
Keyword(s):  
Metal Ion ◽  
Selection Rule ◽  
Near Infrared ◽  
Electronic Configuration ◽  
Infrared Region ◽  
Direct Excitation ◽  
Characteristic Emission ◽  
Nir Emission ◽  
Near Infrared Region

Lanthanides (LnIII) are well known for their characteristic emission in the Near-Infrared Region (NIR). However, direct excitation of lanthanides is not feasible as described by Laporte’s parity selection rule. Here,...

scholarly journals A self-boosting microwave plasma strategy tuned by air pressure for the highly efficient and controllable surface modification of carbon

RSC Advances ◽  
2021 ◽  
Vol 11 (17) ◽  
pp. 9955-9963
Author(s):  
Yanjing Liu ◽  
Jiawei He ◽  
Bing Zhang ◽  
Huacheng Zhu ◽  
Yang Yang ◽  
...  
Keyword(s):  
Surface Modification ◽  
Carbon Fiber ◽  
High Efficiency ◽  
Microwave Plasma ◽  
Air Pressure ◽  
Air Plasma ◽  
Highly Efficient ◽  
Carbon Fiber Cloth

Microwave enabled air plasma was boosted by a carbon fiber cloth (CFC) and used for the high-efficiency surface modification of the CFC, yielding CFCs with tunable contents of oxygen and each O-containing group.

Highly thermally stable Cr3+ and Yb3+ codoped Gd2GaSbO7 phosphors for broadband near-infrared applications

2021 ◽  
Author(s):  
xiudi wu ◽  
shuang zhao ◽  
Liang Zhang ◽  
Langping Dong ◽  
Yonghui Xu ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Emission Band ◽  
Near Infrared ◽  
Thermally Stable ◽  
Nir Emission

Abstract：Gd2GaSbO7:Cr3+,Yb3+ phosphors with efficient broadband NIR emission were prepared by solid-state reaction. Under the excitation of 448 nm, Gd2GaSbO7:Cr3+ (GGS:Cr3+) phosphor exhibits a broadband NIR emission band centered at approximately...

Multi-Site Cr3+ Occupation Related Broadband NIR Luminescence in Cr3+-doped Li3Mg2NbO6

CrystEngComm ◽  
2021 ◽  
Author(s):  
Fen Xiao ◽  
Chengning Xie ◽  
Shikun Xie ◽  
Rongxi Yi ◽  
Huiling Yuan ◽  
...  
Keyword(s):  
Near Infrared ◽  
Nir Spectroscopy ◽  
Luminescent Materials ◽  
Optical Source ◽  
Nir Emission ◽  
Nir Luminescence

Broadband near infrared (NIR) luminescent materials have attracted great attention recently for the advance smart optical source of NIR spectroscopy. In this work, a broadband NIR emission from 650 nm...

scholarly journals High-Efficiency Responsive Smart Windows Fabricated by Carbon Nanotubes Modified by Liquid Crystalline Polymers

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 440
Author(s):  
Yuan Deng ◽  
Shi-Qin Li ◽  
Qian Yang ◽  
Zhi-Wang Luo ◽  
He-Lou Xie
Keyword(s):  
Carbon Nanotubes ◽  
Liquid Crystalline ◽  
Near Infrared ◽  
High Efficiency ◽  
Polymer Brush ◽  
Light Transmittance ◽  
Smart Window ◽  
Vertical Orientation ◽  
Smart Windows ◽  
Conversion Materials

Smart windows can dynamically and adaptively adjust the light transmittance in non-energy or low-energy ways to maintain a comfortable ambient temperature, which are conducive to efficient use of energy. This work proposes a liquid crystal (LC) smart window with highly efficient near-infrared (NIR) response using carbon nanotubes grafted by biphenyl LC polymer brush (CNT-PDB) as the orientation layer. The resultant CNT-PDB polymer brush can provide the vertical orientation of LC molecules to maintain the initial transparency. At the same time, the smart window shows a rapid response to NIR light, which can quickly adjust the light transmittance to prevent sunlight from entering the room. Different from common doping systems, this method avoids the problem of poor compatibility between the LC host and photothermal conversion materials, which is beneficial for improving the durability of the device.

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