Single-chain crosslinked polymers via the transesterification of folded polymers: from efficient synthesis to crystallinity control

2020 ◽  
Vol 11 (32) ◽  
pp. 5181-5190 ◽  
Author(s):  
Daiki Ito ◽  
Yoshihiko Kimura ◽  
Mikihito Takenaka ◽  
Makoto Ouchi ◽  
Takaya Terashima
Keyword(s):  
Crystallization Behavior ◽  
Random Copolymers ◽  
Organic Media ◽  
Efficient Synthesis ◽  
Single Chain ◽  
Crosslinked Polymers

Herein we report efficient synthetic systems of single-chain crosslinked polymers via the intramolecular transesterification of folded random copolymers in organic media and the unique crystallization behavior of their crosslinked polymers.

Water dynamics and self-assembly of single-chain nanoparticles in concentrated solutions

Soft Matter ◽  
2020 ◽  
Vol 16 (42) ◽  
pp. 9738-9745
Author(s):  
Beatriz Robles-Hernández ◽  
Edurne González ◽  
José A. Pomposo ◽  
Juan Colmenero ◽  
Ángel Alegría
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Water Dynamics ◽  
Nano Particles ◽  
Random Copolymers ◽  
Core Shell ◽  
Dielectric Studies ◽  
Single Chain ◽  
Concentrated Solutions ◽  
Overlap Concentration

Dielectric studies on water dynamics in aqueous solutions of amphiphilic random copolymers confirm the self-assembly into globular like core–shell single-chain nano-particles (SCNPs) at concentrations well above the overlap concentration.

Efficient Synthesis of Optically Pure 1,1,1-Trifluoro-2-alkanols through Lipase-Catalyzed Acylation in Organic Media

1996 ◽  
Vol 61 (26) ◽  
pp. 9635-9635
Author(s):  
Hiroki Hamada ◽  
Mizuho Shiromoto ◽  
Makoto Funahashi ◽  
Toshiyuki Itoh ◽  
Kaoru Nakamura
Keyword(s):  
Organic Media ◽  
Efficient Synthesis ◽  
Optically Pure

scholarly journals Counting loops in sidechain-crosslinked polymers from elastic solids to single-chain nanoparticles

2019 ◽  
Vol 10 (20) ◽  
pp. 5332-5337 ◽  
Author(s):  
Junpeng Wang ◽  
Rui Wang ◽  
Yuwei Gu ◽  
Alexandra Sourakov ◽  
Bradley D. Olsen ◽  
...  
Keyword(s):  
Material Properties ◽  
Functionalized Polymers ◽  
Single Chain ◽  
Elastic Solids ◽  
Crosslinked Polymers

The vast differences in material properties accessible via crosslinking of sidechain-functionalized polymers are driven by topology.

Poly(ethylene glycol-co-1,4-cyclohexanedimethanol terephthalate) random copolymers: effect of copolymer composition and microstructure on the thermal properties and crystallization behavior

RSC Advances ◽  
2015 ◽  
Vol 5 (74) ◽  
pp. 60570-60580 ◽  
Author(s):  
Tingting Chen ◽  
Guodong Jiang ◽  
Guoyu Li ◽  
Zhipeng Wu ◽  
Jun Zhang
Keyword(s):  
Glass Transition ◽  
Thermal Properties ◽  
Crystallization Behavior ◽  
Random Copolymers ◽  
Sequence Length ◽  
Copolymer Composition ◽  
Poly Ethylene Glycol ◽  
Average Sequence Length ◽  
Average Sequence ◽  
Poly Ethylene

The glass transition temperature of the statistically random PETG copolymers increased linearly with the increasing CT content. An increase in the average sequence length resulted in a higher melting temperature.

A user's guide to the thiol-thioester exchange in organic media: scope, limitations, and applications in material science

2018 ◽  
Vol 9 (36) ◽  
pp. 4523-4534 ◽  
Author(s):  
Brady T. Worrell ◽  
Sudheendran Mavila ◽  
Chen Wang ◽  
Taylor M. Kontour ◽  
Chern-Hooi Lim ◽  
...  
Keyword(s):  
Material Science ◽  
Room Temperature ◽  
Organic Media ◽  
Crosslinked Polymers ◽  
Thioester Exchange ◽  
Dynamic Exchange

The dynamic exchange of thiols and thioesters in organic media was explored, leading to room temperature plasticity in crosslinked polymers.

Synthesis and Single-Chain Folding of Amphiphilic Random Copolymers in Water

2014 ◽  
Vol 47 (2) ◽  
pp. 589-600 ◽  
Author(s):  
Takaya Terashima ◽  
Takanori Sugita ◽  
Kaoru Fukae ◽  
Mitsuo Sawamoto
Keyword(s):  
Random Copolymers ◽  
Single Chain ◽  
Chain Folding

scholarly journals Efficient Synthesis of Single-Chain Globules Mimicking the Morphology and Polymerase Activity of Metalloenzymes

2015 ◽  
Vol 36 (17) ◽  
pp. 1592-1597 ◽  
Author(s):  
Ana Sanchez-Sanchez ◽  
Arantxa Arbe ◽  
Joachim Kohlbrecher ◽  
Juan Colmenero ◽  
José A. Pomposo
Keyword(s):  
Polymerase Activity ◽  
Efficient Synthesis ◽  
Single Chain
Sign in / Sign up

Export Citation Format

Share Document