Probing the versatility of metallo-electro hybrid catalysis: enabling access towards facile C–N bond formation

2020 ◽  
Vol 18 (44) ◽  
pp. 8994-9017
Author(s):  
Partha Pratim Sen ◽  
Neha Dagar ◽  
Swati Singh ◽  
Vishal Jyoti Roy ◽  
Vishali Pathania ◽  
...  
Keyword(s):  
Transition Metal ◽  
Bond Formation ◽  
Transition Metal Catalysis ◽  
Metal Catalysis ◽  
Recent Advances ◽  
Electro Catalysis

Metallo-electro catalysis has emerged as sustainable alternate to conventional transition metal methodologies. This review highlights the recent advances for the formation of C–N bonds by merging transition metal catalysis with electrosynthesis.

Quasi-nature catalysis. Rhodium-catalyzed C­C bond formation in air and water

2001 ◽  
Vol 73 (8) ◽  
pp. 1315-1318 ◽  
Author(s):  
Taisheng Huang ◽  
Sripathy Venkatraman ◽  
Yue Meng ◽  
Tien V. Nguyen ◽  
Daniel Kort ◽  
...  
Keyword(s):  
Transition Metal ◽  
Organic Synthesis ◽  
Bond Formation ◽  
Transition Metal Catalysis ◽  
Inert Gas ◽  
Natural Conditions ◽  
Metal Catalysis ◽  
Recent Advances ◽  
Gas Atmosphere

Transition-metal catalysis is out-grown from dry-boxes where the use of inert gas atmosphere and the exclusion of moisture have been essential. Such a restriction undoubtedly imposes limitations in the application of these reactions in organic synthesis and in the recycling of the catalysts. This article discusses some recent advances of rhodium-catalyzed carbon­carbon bond formations under the natural conditions of air and water.

C-N Bond Formation Reactions via Transition Metal Catalysis

Synlett ◽  
1997 ◽  
Vol 1997 (7) ◽  
pp. 749-757 ◽  
Author(s):  
Yoshinao Tamaru ◽  
Masanari Kimura
Keyword(s):  
Transition Metal ◽  
Bond Formation ◽  
Transition Metal Catalysis ◽  
Metal Catalysis ◽  
Bond Formation Reactions

scholarly journals Recent Developments in Transition-Metal Catalyzed Direct C–H Alkenylation, Alkylation, and Alkynylation of Azoles

Molecules ◽  
2020 ◽  
Vol 25 (21) ◽  
pp. 4970
Author(s):  
Su Chen ◽  
Prabhat Ranjan ◽  
Leonid G. Voskressensky ◽  
Erik V. Van der Eycken ◽  
Upendra K. Sharma
Keyword(s):  
Transition Metal ◽  
Transition Metal Catalysis ◽  
Significant Progress ◽  
Metal Catalysis ◽  
Bond Functionalization ◽  
Recent Advances ◽  
Regioselective Alkylation ◽  
Recent Developments ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

The transition metal-catalyzed C–H bond functionalization of azoles has emerged as one of the most important strategies to decorate these biologically important scaffolds. Despite significant progress in the C–H functionalization of various heteroarenes, the regioselective alkylation and alkenylation of azoles are still arduous transformations in many cases. This review covers recent advances in the direct C–H alkenylation, alkylation and alkynylation of azoles utilizing transition metal-catalysis. Moreover, the limitations of different strategies, chemoselectivity and regioselectivity issues will be discussed in this review.

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