Selective carbon-carbon bond formation via transition metal catalysis. 37. Controlled carbometalation. 16. Novel syntheses of .alpha.,.beta.-unsaturated cyclopentenones via allylzincation of alkynes

Eiichi Negishi; Joseph A. Miller

doi:10.1021/ja00360a060

Selective carbon-carbon bond formation via transition metal catalysis. 37. Controlled carbometalation. 16. Novel syntheses of .alpha.,.beta.-unsaturated cyclopentenones via allylzincation of alkynes

Journal of the American Chemical Society ◽

10.1021/ja00360a060 ◽

1983 ◽

Vol 105 (22) ◽

pp. 6761-6763 ◽

Cited By ~ 104

Author(s):

Eiichi Negishi ◽

Joseph A. Miller

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Alpha Beta

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ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS. PART 18. PALLADIUM-CATALYZED STEREO- AND REGIOSPECIFIC COUPLING OF ALLYLIC DERIVATIVES WITH ALKENYL- AND ARYLMETALS. A HIGHLY SELECTIVE SYNTHESIS AND 1,4-DIENES

Chemischer Informationsdienst ◽

10.1002/chin.198136144 ◽

1981 ◽

Vol 12 (36) ◽

Author(s):

H. MATSUSHITA ◽

E. NEGISHI

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Selective Synthesis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

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ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. PART 20. HIGHLY SELECTIVE SYNTHESIS OF ALLYLATED ARENES AND DIARYLMETHANES VIA PALLADIUM-CATALYZED CROSS COUPLING INVOLVING BENZYLIC DERIVATIVES

Chemischer Informationsdienst ◽

10.1002/chin.198146114 ◽

1981 ◽

Vol 12 (46) ◽

Author(s):

E. NEGISHI ◽

H. MATSUSHITA ◽

N. OKUKADO

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Cross Coupling ◽

Transition Metal Catalysis ◽

Selective Synthesis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

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ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 35. A CONVENIENT SYNTHESIS OF UNSYMMETRICAL BIBENZYLS, HOMOALLYLARENES, AND HOMOPROPARGYLARENES VIA PALLADIUM-CATALYZED CROSS COUPLING

Chemischer Informationsdienst ◽

10.1002/chin.198401180 ◽

1984 ◽

Vol 15 (1) ◽

Author(s):

E. NEGISHI ◽

H. MATSUSHITA ◽

M. KOBAYASHI ◽

C. L. RAND

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Cross Coupling ◽

Transition Metal Catalysis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Convenient Synthesis ◽

Palladium Catalyzed

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ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 23. HIGHLY SELECTIVE AND CONVENIENT METHOD FOR THE SYNTHESIS OF 1,5-ENYNES AND 1,5-DIENES BY THE REACTION OF 1,3-DILITHIOPROPARGYL PHENYL SULFIDE WITH ALLYLIC HALI

Chemischer Informationsdienst ◽

10.1002/chin.198216160 ◽

1982 ◽

Vol 13 (16) ◽

Author(s):

E. NEGISHI ◽

C. L. RAND ◽

K. P. JADHAV

Keyword(s):

Transition Metal ◽

Convenient Method ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Metal Catalysis ◽

Carbon Bond ◽

Phenyl Sulfide ◽

Carbon Carbon Bond

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ChemInform Abstract: CARBOMETALATION. 13. SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS. 28. A SELECTIVE SYNTHESIS OF ALKENYLMERCURIC CHLORIDES VIA ALKENYLALANES

Chemischer Informationsdienst ◽

10.1002/chin.198243285 ◽

1982 ◽

Vol 13 (43) ◽

Author(s):

E. NEGISHI ◽

K. P. JADHAV ◽

N. DAOTIEN

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Selective Synthesis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond

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Selective carbon-carbon bond formation via transition-metal catalysis. Part 18. Palladium-catalyzed stereo- and regiospecific coupling of allylic derivatives with alkenyl- and arylmetals. A highly selective synthesis and 1,4-dienes

Journal of the American Chemical Society ◽

10.1021/ja00400a074 ◽

1981 ◽

Vol 103 (10) ◽

pp. 2882-2884 ◽

Cited By ~ 106

Author(s):

Hajime Matsushita ◽

Eiichi Negishi

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Selective Synthesis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

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ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. PART 30. A SELECTIVE AND CONVENIENT SYNTHESIS OF β,β-DIALKYL-SUBSTITUTED ALKENYLBORANES AND ALKENYLZIRCONIUMS VIA CARBOALUMINATION OF ALKYNES

Chemischer Informationsdienst ◽

10.1002/chin.198301297 ◽

1983 ◽

Vol 14 (1) ◽

Author(s):

E. NEGISHI ◽

L. D. BOARDMAN

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Convenient Synthesis

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ChemInform Abstract: A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling. Selective Carbon-Carbon Bond Formation via Transition Metal Catalysis. Part 26.

Chemischer Informationsdienst ◽

10.1002/chin.198236176 ◽

1982 ◽

Vol 13 (36) ◽

Author(s):

E. NEGISHI ◽

F.-T. LUO ◽

R. FRISBEE ◽

H. MATSUSHITA

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Cross Coupling ◽

Transition Metal Catalysis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond

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Selective carbon-carbon bond formation via transition metal catalysis. 3. A highly selective synthesis of unsymmetrical biaryls and diarylmethanes by the nickel- or palladium-catalyzed reaction of aryl- and benzylzinc derivatives with aryl halides

The Journal of Organic Chemistry ◽

10.1021/jo00430a041 ◽

1977 ◽

Vol 42 (10) ◽

pp. 1821-1823 ◽

Cited By ~ 623

Author(s):

Eiichi Negishi ◽

Anthony O. King ◽

Nobuhisa Okukado

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Transition Metal Catalysis ◽

Aryl Halides ◽

Selective Synthesis ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

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ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 4. A NOVEL APPROACH TO CROSS-COUPLING EXEMPLIFIED BY THE NICKEL-CATALYZED REACTION OF ALKENYLZIRCONIUM DERIVATIVES WITH ARYL HALIDES

Chemischer Informationsdienst ◽

10.1002/chin.197729289 ◽

1977 ◽

Vol 8 (29) ◽

pp. no-no

Author(s):

E. NEGISHI ◽

D. E. VAN HORN

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Cross Coupling ◽

Transition Metal Catalysis ◽

Aryl Halides ◽

Metal Catalysis ◽

Carbon Bond ◽

Novel Approach ◽

Carbon Carbon Bond

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