Anisotropic nanoporous morphology of ZnO-supported Co that enhances catalytic activity

Nanoscale ◽  
2021 ◽  
Author(s):  
Christopher M. Coaty ◽  
Adam A. Corrao ◽  
Victoria Petrova ◽  
Taewoo Kim ◽  
David P. Fenning ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Catalytic Activity ◽  
Steam Reforming ◽  
Synthesis Methods ◽  
Reaction Synthesis ◽  
Co Catalyst ◽  
Conversion Reaction ◽  
Anisotropic Crystal ◽  
Highly Efficient ◽  
Steam Reforming Of Ethanol

Conversion reaction synthesis methods yield a nanoporous ZnO-supported Co catalyst with an anisotropic crystal structure and an anisotropic, hierarchical, columnar wall morphology that is highly efficient for steam reforming of ethanol to produce H2.

scholarly journals Highly efficient steam reforming of ethanol (SRE) over CeO x grown on the nano Ni x Mg y O matrix: H 2 production under a high GHSV condition

2019 ◽  
Vol 43 (8) ◽  
pp. 3823-3836 ◽  
Author(s):  
Xiang Luo ◽  
Yu Hong ◽  
Honglei Zhang ◽  
Kaiqi Shi ◽  
Gang Yang ◽  
...  
Keyword(s):  
Steam Reforming ◽  
Highly Efficient ◽  
Steam Reforming Of Ethanol

Steam reforming of ethanol–phenol mixture on Ni/Al2O3: Effect of magnesium and boron on catalytic activity in the presence and absence of sulphur

2014 ◽  
Vol 147 ◽  
pp. 813-826 ◽  
Author(s):  
Gabriella Garbarino ◽  
Elisabetta Finocchio ◽  
Alberto Lagazzo ◽  
Ioannis Valsamakis ◽  
Paola Riani ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Steam Reforming ◽  
Steam Reforming Of Ethanol ◽  
Presence And Absence

Steam reforming of ethanol over K promoted Co catalyst

2015 ◽  
Vol 495 ◽  
pp. 30-38 ◽  
Author(s):  
Shuhei Ogo ◽  
Takuya Shimizu ◽  
Yusaku Nakazawa ◽  
Kei Mukawa ◽  
Daiki Mukai ◽  
...  
Keyword(s):  
Steam Reforming ◽  
Co Catalyst ◽  
Steam Reforming Of Ethanol

scholarly journals Comparative Study of Ni-W /CeO2, Ni-W /y-Al2O3 and Ni-W /HT Catalysts for H2 Production by Steam Reforming of Bioethanol

Quimica Hoy ◽  
2011 ◽  
Vol 2 (1) ◽  
pp. 3
Author(s):  
Paz Hernández ◽  
Arturo Fernández ◽  
Sarah Messina
Keyword(s):  
Catalytic Activity ◽  
Fuel Cell ◽  
Hydrogen Production ◽  
Comparative Study ◽  
Steam Reforming ◽  
Carbon Deposition ◽  
Nickel Content ◽  
H2 Production ◽  
Good Stability ◽  
Steam Reforming Of Ethanol

Ni-W catalysts supported on CeO2,Al2O3 and hydrotalcite (HT) were studied in the steam reforming of ethanol at 500-650ºC. The CeO2 and HT were synthesized by impregnation and direct coprecipitation methods, respectively. Commercial Al2O3 was used. Nickel content was varied from 10, 15 and 30% with 1% W. The catalyst that presented the highest catalytic activity and selectivity to hydrogen was 10% Ni-W/HT. Conversion to ethanol was 100% and selectivities to H2, CH4, CO2 and CO were 75, 5.78, 0.37 and 18.85%, respectively, at a temperature of 500 ºC. Moreover, these catalysts showed good stability with respect to carbon deposition and low selectivity towards C2H4 production. These are desirable features for catalysts to be used in hydrogen production for fuel cell applications.

scholarly journals PREPARATION, CHARACTERIZATION AND CATALYTIC ACTIVITY TEST OF CoMo/ZnO CATALYST ON ETHANOL CONVERSION USING STEAM REFORMING METHOD

2010 ◽  
Vol 9 (2) ◽  
pp. 195-200
Author(s):  
Wega Trisunaryanti ◽  
Handirofa Handirofa ◽  
Triyono Triyono ◽  
Suryo Purwono
Keyword(s):  
Catalytic Activity ◽  
Steam Reforming ◽  
Flow Reactor ◽  
Gravimetric Method ◽  
Coke Production ◽  
Ethanol Conversion ◽  
Activity Test ◽  
Steam Reforming Of Ethanol ◽  
Mo Content ◽  
Catalytic Activity Test

Preparation, characterization and catalytic activity test of CoMo/ZnO catalyst for steam reforming of ethanol have been investigated. The catalysts preparation was carried out by impregnation of Co and/or Mo onto ZnO sample. Water excess was used in ethanol feed for steam reforming process under mol ratio of ethanol:water (1:10). Characterizations of catalysts were conducted by analysis of metal content using Atomic Absorption Spectroscopy (AAS). Determination of catalysts acidity was conducted by gravimetric method of adsorption of pyridine base. Catalytic activity test on ethanol conversion using steam reforming method was conducted in a semi-flow reactor system, at a temperature of 400 oC, for 1.5 h under N2 flow rate of 10 mL/min. Gas product was analyzed by gas chromatograph with TCD system. The results of catalysts characterizations showed that the impregnation of Co and/or Mo metals on ZnO sample increased its acidity and specific surface area. The content of Co in Co/ZnO and CoMo/ZnO catalysts was 1.14 and 0.49 wt%. The Mo content in CoMo/ZnO catalyst was 0.36 wt%. The catalytic activity test result on ethanol conversion showed that the ZnO, Co/ZnO, and CoMo/ZnO catalysts produced gas fraction of 16.73, 28.53, and 35.53 wt%, respectively. The coke production of ZnO, Co/ZnO, and CoMo/ZnO catalysts was 0.86, 0.24, and 0.08 wt%, respectively. The gas products consisted mainly of hydrogen.   Keywords: CoMo/ZnO catalyst, steam reforming, ethanol

Influence of the Crystal Structure of Titanium Oxide on the Catalytic Activity of Rh/TiO2 in Steam Reforming of Propane at Low Temperature

2018 ◽  
Vol 24 (35) ◽  
pp. 8742-8746 ◽  
Author(s):  
Lin Yu ◽  
Katsutoshi Sato ◽  
Takaaki Toriyama ◽  
Tomokazu Yamamoto ◽  
Syo Matsumura ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Catalytic Activity ◽  
Low Temperature ◽  
Titanium Oxide ◽  
Steam Reforming
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